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We perform a linearization of the Poisson-Boltzmann (PB) density functional for spherical Wigner-Seitz cells that yields Debye-H\"uckel-like equations agreeing asymptotically with the PB results in the weak-coupling (high-temperature)…

Soft Condensed Matter · Physics 2009-11-07 M. N. Tamashiro , H. Schiessel

Motivated by the numerical investigation by Aoki et al. [1], we study a rarefied gas flow between two parallel infinite plates of the same temperature governed by the Boltzmann equation with diffuse reflection boundaries, where one plate is…

Analysis of PDEs · Mathematics 2024-12-02 Renjun Duan , Zhu Zhang

We consider the nonlinear Neumann problem for fully nonlinear elliptic PDEs on a quadrant. We establish a comparison theorem for viscosity sub and supersolutions of the nonlinear Neumann problem. The crucial argument in the proof of the…

Analysis of PDEs · Mathematics 2021-08-31 Hitoshi Ishii , Taiga Kumagai

The electrical double layer for three different topologies of nanopore electrodes is studied, i.e., the interior and exterior electrical double layers of planar, cylindrical and spherical nanopores immersed into a point-ions electrolyte,…

Soft Condensed Matter · Physics 2025-06-10 A. Silva-Caballero , A. Lozada-Hidalgo , M. Lozada-Cassou

We connect two different generalizations of Boltzmann's kinetic theory by requiring the same stationary solution. Non-extensive statistics can be produced by either using corresponding collision rates nonlinear in the one-particle densities…

Statistical Mechanics · Physics 2009-11-11 T. S. Biro , G. Kaniadakis

In this paper, we prove the existence and stability of subsonic flows for steady full Euler-Poisson system in a two dimensional nozzle of finite length when imposing the electric potential difference on non-insulated boundary from a fixed…

Analysis of PDEs · Mathematics 2013-09-16 Myoungjean Bae , Ben Duan , Chunjing Xie

It is widely accepted that the Poisson-Boltzmann (PB) theory provides a valid description for charged surfaces in the so-called weak coupling limit. Here, we show that the image charge repulsion creates a depletion boundary layer that…

Chemical Physics · Physics 2015-06-23 Rui Wang , Zhen-Gang Wang

We have investigated a single charged microgel in aqueous solution with a combined simulational model and Poisson-Boltzmann theory. In the simulations we use a coarse-grained charged bead-spring model in a dielectric continuum, with…

Soft Condensed Matter · Physics 2009-03-12 Gil C. Claudio , Christian Holm , Kurt Kremer

Porous electrodes are widely used in electrochemical systems, where accurately determining electric potentials, particularly overpotentials, is essential for understanding electrode behavior. At the macroscopic scale, porous electrodes are…

Numerical Analysis · Mathematics 2026-03-03 Yuhe Wang , Min Wang , Zhihang Xu

We study the local well-posedness of the solution to a coupled nonlinear elliptic-parabolic system which models electrical discharge in a Micro-Electro-Mechanical System (MEMS). A simple MEMS capacitor device contains two plates acting as…

Analysis of PDEs · Mathematics 2026-02-26 Heiko Gimperlein , Runan He , Andrew A. Lacey

Density functional theory is used to describe electrolyte solutions in contact with electrodes of planar or spherical shape. For the electrolyte solutions we consider the so-called civilized model, in which all species present are treated…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

We revisit the popular notion of effective or renormalized charge, which is a concept of central importance in the field of highly charged colloidal or polyelectrolyte solutions. Working at the level of a linear Debye-H\"uckel like theory…

Soft Condensed Matter · Physics 2009-11-07 Emmanuel Trizac , Lyderic Bocquet , Miguel Aubouy

A model of a finite cylindrical ion channel through a phospholipid membrane of width $L$ separating two electrolyte reservoirs is studied. Analytical solution of the Poisson equation is obtained for an arbitrary distribution of ions inside…

Soft Condensed Matter · Physics 2009-11-11 Yan Levin

We extend the classical Gouy-Chapman model of two planar parallel interacting double-layers, which is used as a first approximation to describe the force between colloidal particles, by considering the finite-thickness of the colloids. The…

Soft Condensed Matter · Physics 2007-05-23 Aldemar Torres , Rene van Roij , Gabriel Tellez

In this paper we propose a nonlinear elasticity model of macromolecular conformational change (deformation) induced by electrostatic forces generated by an implicit solvation model. The Poisson-Boltzmann equation for the electrostatic…

Analysis of PDEs · Mathematics 2010-01-12 Yongcheng Zhou , Michael Holst , James Andrew McCammon

For multispecies ions, we study boundary layer solutions of charge conserving Poisson-Boltzmann (CCPB) equations [50] (with a small parameter \k{o}) over a finite one-dimensional (1D) spatial domain, subjected to Robin type boundary…

Analysis of PDEs · Mathematics 2015-04-28 Chiun-Chang Lee , Hijin Lee , YunKyong Hyon , Tai-Chia Lin , Chun Liu

For the structure of the thin electrical double layer~(EDL) and the property related to the EDL capacitance, we analyze boundary layer solutions (corresponding to the electrostatic potential) of a non-local elliptic equation which is a…

Analysis of PDEs · Mathematics 2018-07-31 Chiun-Chang Lee

Non-local electrostatic interactions associated with the finite solvent size and ion polarizability are investigated within the mean-field linear response theory. To this end, we introduce a field theoretic model of a polar liquid composed…

Soft Condensed Matter · Physics 2015-06-15 Sahin Buyukdagli , Tapio Ala-Nissila

Two overall neutral surfaces with positive and negative charged domains ("patches") have been shown in recent experiments to exhibit long-range attraction when immersed in an ionic solution. Motivated by the experiments, we calculate…

Soft Condensed Matter · Physics 2016-08-31 Ram M. Adar , David Andelman , Haim Diamant

When a Coulombic fluid is confined between two parallel charged plates, an exact relation links the difference of ionic densities at contact with the plates, to the surface charges of these boundaries. It no longer applies when the…

Statistical Mechanics · Physics 2015-10-28 Juan Pablo Mallarino , Gabriel Tellez , Emmanuel Trizac