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By considering general Markov stochastic dynamics and its coarse-graining, we study the framework of stochastic thermodynamics for the original and reduced descriptions corresponding to different scales. We are especially concerned with the…

Statistical Mechanics · Physics 2015-01-29 Yohei Nakayama , Kyogo Kawaguchi

In thermodynamics a macroscopic state of a system results from a number of its microscopic states. This number is given by the exponent of the system's entropy $\exp(S)$. In non-interacting systems with discrete energy spectra, such as…

Mesoscale and Nanoscale Physics · Physics 2015-12-09 Sergey Smirnov

In this study, we advance the understanding of non-equilibrium systems by deriving thermodynamic relations for a heat engine operating under an exponentially decreasing temperature profile. Such thermal configurations closely mimic…

Statistical Mechanics · Physics 2025-04-01 Mesfin Taye

It is discussed how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be defined and classified for finite systems from the topology of the energy surface…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross , E. Votyakov

Traditionally, phase transitions are defined in the thermodynamic limit only. We discuss how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be seen and…

Statistical Mechanics · Physics 2015-06-25 D. H. E. Gross , E. Votyakov

We introduce the concept of stationary metastable states (SMS's) in the presence of another more stable state. The stationary nature allows us to study SMS's by using a restricted partition function formalism as advocated by Penrose and…

Statistical Mechanics · Physics 2007-05-23 P. D. Gujrati

We show that models of opinion formation and dissemination in a community of individuals can be framed within stochastic thermodynamics from which we can build a nonequilibrium thermodynamics of opinion dynamics. This is accomplished by…

Statistical Mechanics · Physics 2023-07-12 Tânia Tomé , Carlos E. Fiore , Mário J. de Oliveira

Bifurcation theory is the usual analytic approach to study the parameter space of a dynamical system. Despite the great power of prediction of these techniques, fundamental limitations appear during the study of a given problem. Nonlinear…

Chaotic Dynamics · Physics 2023-10-02 Alexandre Wagemakers , Alvar Daza , Miguel A. F. Sanjuán

Within the frames of the analytical mechanics the method of the description of dynamics of nonequilibrium systems of potentially interacting elements is develops. The method is based on an opportunity of representation of nonequilibrium…

General Physics · Physics 2012-05-14 V. M. Somsikov

According to the second law of thermodynamics the total entropy of a system is increased during almost any dynamical process. The positivity of the specific heat implies that the entropy increase is associated with heating. This is…

Statistical Mechanics · Physics 2015-06-11 Luca D'Alessio , Anatoli Polkovnikov

Small systems in a thermodynamic medium --- like colloids in a suspension or the molecular machinery in living cells --- are strongly affected by the thermal fluctuations of their environment. Physicists model such systems by means of…

Statistical Mechanics · Physics 2014-10-16 Bernhard Altaner

We examine stochastic processes that are used to model nonequilibrium processes (e.g, pulling RNA or dragging colloids) and so deliberately violate detailed balance. We argue that by combining an information-theoretic measure of…

Statistical Mechanics · Physics 2009-11-13 R. A. Blythe

Two simple spin models are studied to show that the microcanonical entropy can be a non-concave function of the energy, and that the microcanonical and canonical ensembles can give non-equivalent descriptions of the same system in the…

Statistical Mechanics · Physics 2008-01-24 Hugo Touchette

A thermodynamics for systems at a stationary states is formulated. It is based upon the assumption of the existence of local equilibrium in phase space which enables one to interpret the probability density ans its conjugated nonequilibrium…

Statistical Mechanics · Physics 2007-05-23 I. Santamaria-Holek , J. M. Rubi , A. Perez-Madrid

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

Nonequilibrium phase transitions can be typified in a similar way to equilibrium systems, for instance, by the use of the order parameter. However, this characterization hides the irreversible character of the dynamics as well as its…

Statistical Mechanics · Physics 2019-07-10 C. E. Fernández Noa , Pedro E. Harunari , M. J. de Oliveira , C. E. Fiore

Entropy production during the process of thermal phase-separation of multiphase flows is investigated by means of a discrete Boltzmann kinetic model. The entropy production rate is found to increase during the spinodal decomposition stage…

Statistical Mechanics · Physics 2019-03-18 Yudong Zhang , Aiguo Xu , Guangcai Zhang , Yanbiao Gan , Zhihua Chen , Sauro Succi

Thermodynamic phase transitions, a central concept in physics and chemistry, are typically controlled by an interplay of enthalpic and entropic contributions. In most cases, the estimation of the enthalpy in simulations is straightforward…

Soft Condensed Matter · Physics 2025-10-30 Yamin Ben-Shimon , Barak Hirshberg , Yohai Bar-Sinai

A new approach to non-extensive thermodynamical systems with non-additive energy and entropy is proposed. The main idea of the paper is based on the statistical matching of the thermodynamical systems with the additive multi-step Markov…

Data Analysis, Statistics and Probability · Physics 2007-05-23 S. S. Apostolov , Z. A. Mayzelis , O. V. Usatenko , V. A. Yampol'skii

We formulate thermodynamics of economic systems in terms of an arbitrary probability distribution for a conserved economic quantity. As in statistical physics, thermodynamic macroeconomic variables emerge as the mean value of microeconomic…

Statistical Finance · Quantitative Finance 2011-05-26 H. Quevedo , M. N. Quevedo