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Polycyclic Aromatic Hydrocarbons (PAHs) are believed to be the small-size tail of the interstellar carbonaceous dust grain population. Their vibrational emission is the most widely accepted source of the aromatic near-infrared features, and…

Astrophysics of Galaxies · Physics 2015-08-21 Yacine Ali-Haïmoud , Laura Pérez , Ronald Maddalena , Anish Roshi

Context. The recent detection of warm H$_2$O vapor emission from the outflows of carbon-rich asymptotic giant branch (AGB) stars challenges the current understanding of circumstellar chemistry. Two mechanisms have been invoked to explain…

Clusters of polycyclic aromatic hydrocarbon (PAH) molecules are modelled using explicit all-atom potentials using a rigid body approximation. The PAH's considered range from pyrene (C10H8) to circumcoronene (C54H18), and clusters containing…

Chemical Physics · Physics 2016-09-28 M. Rapacioli , F. Calvo , F. Spiegelman , C. Joblin , D. J. Wales

We study the Polycyclic Aromatic Hydrocarbons (PAH) bands, ionic emission lines, and Mid-infrared continuum properties, in a sample of 171 emission line galaxies taken from literature plus 15 new active galactic nuclei (AGN) Spitzer…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 Dinalva A. Sales , M. G. Pastoriza , R. Riffel

The physical and chemical conditions in photodissociation regions (PDRs) are largely determined by the influence of far ultraviolet radiation. Far-UV photons can efficiently dissociate molecular hydrogen, a process that must be balanced at…

Astrophysics of Galaxies · Physics 2018-06-08 P. Castellanos , A. Candian , H. Andrews , A. G. G. M. Tielens

In recent years, many questions have arisen regarding the chemistry of photochemical products in the carbon-rich winds of evolved stars. To address them, it is imperative to constrain the distributions of such species through high angular…

Solar and Stellar Astrophysics · Physics 2022-12-21 Mark A. Siebert , Marie Van de Sande , Thomas J. Millar , Anthony J. Remijan

The infrared (IR) emission of polycyclic aromatic hydrocarbons (PAHs) permeates our universe; astronomers have detected the IR signatures of PAHs around many interstellar objects. The IR emission of interstellar PAHs differs from their…

Astrophysics of Galaxies · Physics 2018-10-05 Cameron J. Mackie , Tao Chen , Alessandra Candian , Timothy J. Lee , Alexander G. G. M. Tielens

In the present contribution, I summarize a systematic study of ISO and Spitzer mid-IR spectra of Galactic regions and star forming galaxies. This study quantifies the relative variations of the main aromatic features inside spatially…

Astrophysics · Physics 2008-02-19 F. Galliano

Polycyclic Aromatic Hydrocarbons are prevalent in the universe and interstellar medium but are primarily attributed to anthropogenic sources on Earth, such as fossil fuel combustion and firewood burning. Drawing upon the idea of PAHs as…

Earth and Planetary Astrophysics · Physics 2025-01-14 Dwaipayan Dubey , Ravi Kopparapu , Barbara Ercolano , Karan Molaverdikhani

Polycyclic aromatic hydrocarbons (PAHs) are believed to be ubiquitous in the interstellar medium. Yet, to date no specific PAH molecule has been identified. In this paper, a new observational avenue is suggested to detect individual PAHs,…

Astrophysics of Galaxies · Physics 2015-08-21 Yacine Ali-Haïmoud

Polycyclic aromatic hydrocarbons (PAHs) are of great astrochemical and astrobiological interest due to their potential to form prebiotic molecules. We analyse the 7.7 and 8.6 ${\mu}$m PAH bands in 126 predominantly starburst-dominated…

Polycyclic aromatic hydrocarbons (PAHs) are fundamental to understanding the interstellar medium (ISM) of several astrophysical objects. Normally present in Starburst (SB) galaxies, they have also been more frequently detected in active…

We have obtained new STIS/HST spectra to search for structure in the ultraviolet interstellar extinction curve, with particular emphasis on a search for absorption features produced by polycyclic aromatic hydrocarbons (PAHs). The presence…

Context. The 3.3 $\mu$m aromatic C-H stretching band of polycyclic aromatic hydrocarbon (PAH) molecules seen in a wide variety of astrophysical regions is often accompanied by a series of weak satellite bands at ~3.4-3.6 $\mu$m. One of…

Instrumentation and Methods for Astrophysics · Physics 2019-12-04 Tao Chen , Yi Luo , Aigen Li

Hydrogen depleted environments are considered an essential requirement for the formation of fullerenes. The recent detection of C60 and C70 fullerenes in what was interpreted as the hydrogen-poor inner region of a post-final helium shell…

Polycyclic Aromatic Hydrocarbons (PAHs) constitute a significant fraction of the Universe's carbon budget, playing a key role in the cosmic carbon cycle and dominating the mid-infrared spectra of astrophysical environments in which they…

Solar and Stellar Astrophysics · Physics 2026-03-18 Charlotte Smith-Perez , Aidan Hembruff , Els Peeters , Alexander G. G. M. Tielens , Alessandra Ricca

Interstellar infrared observation shows featured spectrum due to polycyclic aromatic hydrocarbon (PAH)at wavelength 3.3,6.2,7.6,7.8,8.6,and 11.3 micrometer,which are ubiquitously observed in many astronomical dust clouds and galaxies. Our…

Astrophysics of Galaxies · Physics 2018-08-06 Norio Ota

We present a charge distribution based model that computes the infrared spectrum of polycyclic aromatic hydrocarbon (PAH) molecules using recent measurements or quantum chemical calculations of specific PAHs. The model is applied to a…

Astrophysics of Galaxies · Physics 2022-06-15 Ameek Sidhu , A. G. G. M. Tielens , Els Peeters , Jan Cami

In this Letter we report the results of density functional theory calculations on medium-sized neutral Polycyclic Aromatic Hydrocarbon (PAH) molecules with armchair edges. These PAH molecules possess strong C-H stretching and bending modes…

Astrophysics of Galaxies · Physics 2014-10-09 A. Candian , P. J. Sarre , A. G. G. M. Tielens

The pre-transitional disk around the Herbig Ae star HD 169142 shows a complex structure of possible ongoing planet formation in dust thermal emission from the near infrared (IR) to millimeter wavelength range. Also, a distinct set of broad…

Solar and Stellar Astrophysics · Physics 2016-02-17 Ji Yeon Seok , Aigen Li
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