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The statistical mechanical basis of the fluctuation theory of mixtures is reviewed. An overview of the statistical mechanical relations between the microscopic properties of a system and its macroscopic properties is presented. The…

Statistical Mechanics · Physics 2018-11-20 G. Ali Mansoori , Enrico Matteoli

The second law of thermodynamics imposes an increase of macroscopic entropy with time in an isolated system. Microscopically, however, the entropy production can be negative for a single, microscopic realization of a thermodynamic process.…

Solar and Stellar Astrophysics · Physics 2018-12-07 Andrei Gorobets , Svetlana Berdyugina

The principle of maximum entropy is a broadly applicable technique for computing a distribution with the least amount of information possible constrained to match empirical data, for instance, feature expectations. We seek to generalize…

Information Theory · Computer Science 2022-05-30 Kenneth Bogert

It will be shown, how the Boltzmannian ideas on statistical physics can be naturally applied to nonequilibrium thermodynamics. A similar approach for treating nonequilibrium phenomena has been successfully used by Einstein and Smoluchowski…

Statistical Mechanics · Physics 2007-05-23 W. Pietsch

*First-principles derivation of the entropy production in erectric static conduction. *The second-order (symmetric) density matrix contributes to the entropy production. *New schemes of steady states formulated using a relaxation-type von…

Statistical Mechanics · Physics 2011-03-31 Masuo Suzuki

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

The Boltzmann distribution connects the energetics of an equilibrium system with its statistical properties, and it is desirable to have a similar principle for non-equilibrium systems. Here, we derive a variational principle for the…

Statistical Mechanics · Physics 2025-11-05 Atul Tanaji Mohite , Heiko Rieger

Within the abstract framework of dynamical system theory we describe a general approach to the Transient (or Evans-Searles) and Steady State (or Gallavotti-Cohen) Fluctuation Theorems of non-equilibrium statistical mechanics. Our main…

Mathematical Physics · Physics 2011-06-21 Vojkan Jakšić , Claude-Alain Pillet , Luc Rey-Bellet

The thermodynamic definition of entropy can be extended to nonequilibrium systems based on its relation to information. To apply this definition in practice requires access to the physical system's microstates, which may be prohibitively…

Statistical Mechanics · Physics 2020-08-21 Gil Ariel , Haim Diamant

Entropy production characterizes the thermodynamic irreversibility and reflects the amount of heat dissipated into the environment and free energy lost in nonequilibrium systems. According to the thermodynamic uncertainty relation, we…

Statistical Mechanics · Physics 2020-05-01 Tan Van Vu , Van Tuan Vo , Yoshihiko Hasegawa

We uncover the quantum fluctuation-response inequality, which, in the most general setting, establishes a bound for the mean difference of an observable at two different quantum states, in terms of the quantum relative entropy. When the…

Quantum Physics · Physics 2022-03-22 Yan Wang

One of the major goals of quantum thermodynamics is the characterization of irreversibility and its consequences in quantum processes. Here, we discuss how entropy production provides a quantification of the irreversibility in open quantum…

The emerging field of stochastic thermodynamics extends classical ideas of entropy, heat and work to non-equilibrium systems. One notable finding is that the second law of thermodynamics typically only holds after taking appropriate…

Statistical Mechanics · Physics 2024-02-27 Paul C Bressloff

Given a general scalar balance law, i.e., in several space dimensions and with flux and source both space and time dependent, we focus on the functional properties of the entropy production. We apply this operator to entropy solutions, to…

Analysis of PDEs · Mathematics 2025-04-03 Rinaldo Colombo , Vincent Perrollaz

Fluctuations of the excess heat in an out of equilibrium steady state are experimentally investigated in two stochastic systems : an electric circuit with an imposed mean current and a harmonic oscillator driven out of equilibrium by a…

Statistical Mechanics · Physics 2009-11-13 Sylvain Joubaud , Nicolas Garnier , Sergio Ciliberto

Entropy serves as a central observable in equilibrium thermodynamics. However, many biological and ecological systems operate far from thermal equilibrium. Here we show that entropy production can characterize the behavior of such…

Statistical Mechanics · Physics 2015-03-17 Benjamin Andrae , Jonas Cremer , Tobias Reichenbach , Erwin Frey

Systems with interacting degrees of freedom play a prominent role in stochastic thermodynamics. Our aim is to use the concept of detached path probabilities and detached entropy production for bipartite Markov processes and elaborate on a…

Statistical Mechanics · Physics 2017-10-17 Jannik Ehrich , Andreas Engel

A stopping time $T$ is the first time when a trajectory of a stochastic process satisfies a specific criterion. In this paper, we use martingale theory to derive the integral fluctuation relation $\langle e^{-S_{\rm tot}(T)}\rangle=1$ for…

Statistical Mechanics · Physics 2019-10-22 Izaak Neri , Edgar Roldán , Simone Pigolotti , Frank Jülicher

The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which detailed balance and time-reversal symmetry are broken. Despite…

Statistical Mechanics · Physics 2020-12-02 Luca Cocconi , Rosalba Garcia-Millan , Zigan Zhen , Bianca Buturca , Gunnar Pruessner