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Recent experiments have convincingly demonstrated the existence of surface nanobubbles on submerged hydrophobic surfaces. However, classical theory dictates that small gaseous bubbles quickly dissolve because their large Laplace pressure…

Fluid Dynamics · Physics 2009-11-13 Michael P. Brenner , Detlef Lohse

With the recent important development of microfluidic systems, miniaturization of flow devices has become a real challenge. Microchannels, however, are characterized by a large surface to volume ratio, so that surface properties strongly…

Materials Science · Physics 2009-11-10 Cecile Cottin-Bizonne , Jean-Louis Barrat , Lyderic Bocquet , Elisabeth Charlaix

Experimental investigations of hydrophobic/water interfaces often return controversial results, possibly due to the unknown role of gas accumulation at the interfaces. Here, during advanced atomic force microscopy of the initial evolution…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Ing-Shouh Hwang , Chung-Kai Fang , Hsien-Chen Ko , Chih-Wen Yang , Yi-Hsien Lu

We study surface nanobubbles using molecular dynamics simulation of ternary (gas, liquid, solid) systems of Lennard-Jones fluids. They form for sufficiently low gas solubility in the liquid, i.e., for large relative gas concentration. For…

Fluid Dynamics · Physics 2012-11-19 J. H. Weijs , J. H. Snoeijer , D. Lohse

We investigate the nature of vapor bubble nucleation near a nanoscale-curved convex liquid-solid interface using two models; an equilibrium Gibbs model for homogenous formation, and a nonequilibrium dynamic van der Waals/diffuse interface…

Fluid Dynamics · Physics 2018-03-28 Jarrod Schiffbauer , Tengfei Luo

The influence of the external pressure and surface energy on the wetting transition at nanotextured interfaces is studied using molecular dynamics and continuum simulations. The surface roughness of the composite interface is introduced via…

Soft Condensed Matter · Physics 2018-07-12 Bishal Bhattarai , Nikolai V. Priezjev

We apply specular and off-specular neutron reflection at the hydrophobic silicon/water interface to check for evidence of nanoscopic air bubbles whose presence is claimed after an ad hoc procedure of solvent exchange. Nanobubbles and/or a…

Soft Condensed Matter · Physics 2017-10-13 Philipp Gutfreund , Marco Maccarini , Andrew Dennison , Max Wolff

A model for gas nanobubbles is proposed in which their remarkable stability is explained as due to the presence of a qualitatively different form of water covering the nanobubble surface layer which leads to a reduction of the diffusion…

Mesoscale and Nanoscale Physics · Physics 2014-10-15 Siddhartha Sen , Kumar S. Gupta

A systematically designed study has been conducted to understand and clearly demarcate the degree of contribution by the constituting elements to the surface tension of nanocolloids. The effects of elements such as surfactants, particles…

Soft Condensed Matter · Physics 2016-10-20 A R Harikrishnan , Purbarun Dhar , PK Agnihotri , Sateesh Gedupudi , Sarit K Das

It is shown that when the nanobubble contact line is pinned to a penetrating tip the interface behaves like a Hookean spring with spring constant proportional to the nanobubble surface tension. Atomic force microscope (AFM) data for several…

Soft Condensed Matter · Physics 2015-05-12 Phil Attard

Surface nanobubbles are stable gaseous phases in liquids that form on solid substrates. While their existence has been confirmed, there are many open questions related to their formation and dissolution processes along with their structures…

Fluid Dynamics · Physics 2022-04-20 Zhizhao Che , Panagiotis E. Theodorakis

Measurements of the surface diffusivity of colloidal spheres translating along a vapor/liquid inter- face show an unexpected decrease in diffusivity, or increase in surface drag (from the Stokes-Einstein relation) when the particles situate…

Soft Condensed Matter · Physics 2016-07-08 Joel Koplik , Charles Maldarelli

Stability of lubricating fluid infused slippery surfaces is a concern for scientists and engineers and attempts are being made for its improvement. Lubricating oil coated slippery surface for aqueous drops is one of the important candidates…

Soft Condensed Matter · Physics 2016-08-24 Reeta Pant , Sanjeev Kumar Ujjain , Arun Kumar Nagarajan , Krishnacharya Khare

The stability and growth or dissolution of a single surface nanobubble on a chemically patterned surface are studied by Molecular Dynamics (MD) simulations of binary mixtures consisting of Lennard-Jones (LJ) particles. Our simulations…

Fluid Dynamics · Physics 2017-07-14 Shantanu Maheshwari , Martin van der Hoef , Xuehua Zhang , Detlef Lohse

Cavitation, the formation of vapor bubbles in metastable liquids, is highly sensitive to nanoscale surface defects. Using molecular dynamics simulations and classical nucleation theory, we show that pure water confined within defect-free…

Soft Condensed Matter · Physics 2025-01-22 Marin Šako , Fabio Staniscia , Roland R. Netz , Emanuel Schneck , Matej Kanduč

Shapes of colloids matter at liquid interfaces. We explore the interactions between rough-surfaced nanocolloids at the air--water interface through the compaction of monolayers experimentally and numerically. Sufficiently rough systems…

Soft Condensed Matter · Physics 2023-05-17 Airi N. Kato , Yujie Jiang , Wei Chen , Ryohei Seto , Tao Li

The findings of long-lived surface nanobubbles in various experiments brought a puzzle in theory, as they were supposed to be dissolved in microseconds due to the high Laplace pressure. However, an increasing number of studies suggest that…

Soft Condensed Matter · Physics 2018-01-09 Yawei Liu , Xianren Zhang

An aqueous suspension of silica nanoparticles or nanofluid can alter the wettability of surfaces, specifically by making them hydrophilic and oil-repellent under water. Wettability alteration by nanofluids have important technological…

Applied Physics · Physics 2021-08-13 Shidong Li , Anqi Sng , Dan Daniel , Hon Chung Lau , Ole Torsæter , Ludger P. Stubbs

Surface nanobubbles are nanoscopic spherical-cap shaped gaseous domains on immersed substrates which are stable, even for days. After the stability of a {\it single} surface nanobubble has been theoretically explained, i.e. contact line…

Fluid Dynamics · Physics 2020-02-06 Xiaojue Zhu , Roberto Verzicco , Xuehua Zhang , Detlef Lohse

We present results of Molecular Dynamics (MD) calculations on the behavior of liquid nanodroplets on rough hydrophobic and hydrophilic solid surfaces. On hydrophobic surfaces, the contact angle for nanodroplets depends strongly on the root…

Soft Condensed Matter · Physics 2008-05-07 C. Yang , U. Tartaglino , B. N. J. Persson
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