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By means of electronic transport, we study the transverse magnetic anisotropy of an individual Fe$_4$ single-molecule magnet (SMM) embedded in a three-terminal junction. In particular, we determine in situ the transverse anisotropy of the…

Mesoscale and Nanoscale Physics · Physics 2016-08-10 M. Misiorny , E. Burzurí , R. Gaudenzi , K. Park , M. Leijnse , M. R. Wegewijs , J. Paaske , A. Cornia , H. S. J. van der Zant

Using first-principles methods we study theoretically the properties of an individual $\{Fe_4\}$ single-molecule magnet (SMM) attached to metallic leads in a single-electron transistor geometry. We show that the conductive leads do not…

Mesoscale and Nanoscale Physics · Physics 2014-07-01 J. F. Nossa , M. Fhokrul Islam , C. M. Canali , M. R. Pederson

We review different electron transport methods to probe the magnetic properties, such as the magnetic anisotropy, of an individual Fe4 SMM. The different approaches comprise first and higher order transport through the molecule. Gate…

Mesoscale and Nanoscale Physics · Physics 2016-06-09 E. Burzurí , R. Gaudenzi , H. S. J. van der Zant

Single-molecule transistors provide a unique experimental tool to investigate the coupling between charge transport and the molecular degrees of freedom in individual molecules. One interesting class of molecules for such experiments are…

We reversibly switch the polar environment of an individual magnetic atom with an electric field to control the energy barrier for reversal of magnetization. By applying an electric field in the gap between the tip and sample of a scanning…

Mesoscale and Nanoscale Physics · Physics 2023-03-01 Jose Martinez-Castro , Cyrus F. Hirjibehedin , David Serrate

We study single-electron transport in a three-ion molecule with strong uniaxial anisotropy and in the presence of a transverse magnetic field. Two magnetic ions are connected to each other through a third, nonmagnetic ion. The magnetic ions…

Mesoscale and Nanoscale Physics · Physics 2014-05-12 Javier I. Romero , Eduardo R. Mucciolo

Through systematics density functional calculations, the mechanism of the substrate induced spin reorientation transition in FePc/O-Cu(110) was explained in terms of charge transfer and rearrangement of Fe-d orbitals. Moreover, we found…

Materials Science · Physics 2014-01-14 Jun Hu , Ruqian Wu

Controlling electronic transport through a single-molecule junction is crucial for molecular electronics or spintronics. In magnetic molecular devices, the spin degree-of-freedom can be used to this end since the magnetic properties of the…

We study numerically the low-temperature electronic transport properties of a single-ion magnet with uniaxial and transverse spin anisotropies. We find clear signatures of a Kondo effect caused by the presence of a transverse (zero-field)…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Javier I. Romero , E. Vernek , G. B. Martins , E. R. Mucciolo

Spin-polarized transport through bistable magnetic adatoms or single-molecule magnets (SMMs), which exhibit both uniaxial and transverse magnetic anisotropy, is considered theoretically. The main focus is on the impact of transverse…

Mesoscale and Nanoscale Physics · Physics 2014-07-22 Maciej Misiorny , Józef Barnaś

We analyze the electronic transport through a model spin-1 molecule as a function of temperature, magnetic field and bias voltage. We consider the effect of magnetic anisotropy, which can be generated experimentally by stretching the…

Strongly Correlated Electrons · Physics 2011-06-24 P. S. Cornaglia , P. Roura Bas , A. A. Aligia , C. A. Balseiro

The magnetism of single atoms and molecules is governed by the atomic scale environment. In general, the reduced symmetry of the surrounding splits the $d$ states and aligns the magnetic moment along certain favorable directions. Here, we…

Mesoscale and Nanoscale Physics · Physics 2015-11-30 Benjamin W. Heinrich , Lukas Braun , Jose I. Pascual , Katharina J. Franke

The manipulation of single magnetic molecules may enable new strategies for high-density information storage and quantum-state control. However, progress in these areas depends on developing techniques for addressing individual molecules…

Electric control of magnetism is a vision which drives intense research on magnetic semiconductors and multiferroics. Recently, also ultrathin metallic films were reported to show magnetoelectric effects at room temperature. Here we…

We present a theoretical approach to calculate the molecular magnetic anisotropy parameters, $D_M$ and $E_M$ for single molecule magnets in any eigenstate of the exchange Hamiltonian, treating the anisotropy Hamiltonian as a perturbation.…

Strongly Correlated Electrons · Physics 2009-11-13 Rajamani Raghunathan , S. Ramasesha , Diptiman Sen

To understand the effect of molecular environment on the electronic and magnetic properties of the single-molecule magnet (SMM) Mn$_{12}$, we explore two possible means for adding extra electrons to molecule. We explore both substitution of…

Materials Science · Physics 2009-11-10 Kyungwha Park , Mark R. Pederson

Inspired by cotunneling spectroscopy of spin-states in a single OPE5-based molecule, we investigate the prospects for electric control of magnetism in purely organic molecules contacted in a three-terminal geometry. Using the gate…

Mesoscale and Nanoscale Physics · Physics 2012-12-21 J. Fock , M. Leijnse , K. Jennum , A. S. Zyazin , J. Paaske , P. Hedegård , M. Brøndsted Nielsen , H. S. J. van der Zant

We study the effect of magnetic anisotropy in a single electron transistor with ferromagnetic electrodes and a non-magnetic island. We identify the variation $\delta \mu$ of the chemical potential of the electrodes as a function of the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 J. Fernandez-Rossier , R. Aguado , L. Brey

We report magnetization changes generated by an electric field in ferromagnetic Ga$_{1-x}$Mn$_x$N grown by molecular beam epitaxy. Two classes of phenomena have been revealed. First, over a wide range of magnetic fields, the magnetoelectric…

The ability to make electrical contact to single molecules creates opportunities to examine fundamental processes governing electron flow on the smallest possible length scales. We report experiments in which we controllably stretch…

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