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The behavior of a polyelectrolyte adsorbed on a charged substrate of high-dielectric constant is studied by both Monte-Carlo simulation and analytical methods. It is found that in a low enough ionic strength medium, the adsorption…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

Surface charges play a fundamental role in physics and chemistry, particularly in shaping the catalytic properties of nanomaterials. Tracking nanoscale surface charge dynamics remains challenging due to the involved length and time scales.…

The charge state of dielectric surfaces in aqueous environments is of fundamental and technological importance. Here, we study the influence of dissolved molecular CO$_2$ on the charging of three, chemically different surfaces (SiO$_2$,…

Using self-assembly techniques, x-ray reflectivity measurements, and computer simulations, we study the effective interaction between charged polymer rods and surfaces. Long-time Brownian dynamics simulations are used to measure the…

Soft Condensed Matter · Physics 2009-10-31 R. Jay Mashl , Niels Grønbech-Jensen , M. R. Fitzsimmons , M. Lütt , DeQuan Li

We propose to measure the surface charge accumulating at the interface between a plasma and a dielectric by infrared spectroscopy using the dielectric as a multi-internal reflection element. The surplus charge leads to an attenuation of the…

Plasma Physics · Physics 2021-07-14 K. Rasek , F. X. Bronold , H. Fehske

We suggest to include the density of electron charge explicitly in the electron potential of density functional theory, rather than implicitly via exchange-correlation functionals. The advantages of the approach are conceptual and…

Materials Science · Physics 2007-05-23 Werner A. Hofer , Krisztian Palotas

The problem of the equilibrium state of the charged many-particle system above dielectric surface is formulated.We consider the case of the presence of the external attractive pressing field and the case of its absence. The equilibrium…

Statistical Mechanics · Physics 2009-05-21 Dmytro M. Lytvynenko , Yuriy V. Slyusarenko

A new approach for determining the binding energies of charged particles, such as ions and electrons, on dielectric surfaces in cryogenic liquids is introduced. The experimental technique outlined in this paper is employed to observe the…

Materials Science · Physics 2026-01-21 Ashok Timsina , Wolfgang Korsch

Surface charging is a phenomenon ubiquitously observable in in-situ transmission electron microscopy of non-conducting specimens as a result of electron beam/sample interactions or optical stimuli and often limits the achievable image…

Mesoscale and Nanoscale Physics · Physics 2024-08-27 Jonathan T. Weber , Sascha Schäfer

We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…

Soft Condensed Matter · Physics 2016-11-23 Salim R. Maduar , Olga I. Vinogradova

Electrometry near a dielectric surface is performed using Rydberg electromagnetically induced transparency (EIT). The large polarizability of high n-state Rydberg atoms gives this method extreme sensitivity. We show that adsorbates on the…

Atomic Physics · Physics 2015-05-28 R. P. Abel , C. Carr , U. Krohn , C. S. Adams

The properties of surfaces with charge-regulated patches are studied using non-linear Poisson-Boltzmann theory. Using a mode expansion to solve the non-linear problem efficiently, we reveal the charging behaviour of Debye-length sized…

Soft Condensed Matter · Physics 2015-05-20 Niels Boon , René van Roij

We report an experimental refinement of the local charge density at the Si (111) 7x7 surface utilizing a combination of x-ray and high energy electron diffraction. By perturbing about a bond-centered pseudoatom model, we find experimentally…

Materials Science · Physics 2015-05-13 J. Ciston , A. Subramanian , I. K. Robinson , L. D. Marks

We study the problem of charge regulation and its effects on electrostatic interactions between dissociable charge groups immersed in a univalent electrolyte, within a family of one dimensional exactly solvable models. We consider the case…

Soft Condensed Matter · Physics 2015-06-23 A. C. Maggs , R. Podgornik

Scanning Probe Microscopy is used to study and quantify the nanoscale electric phenomena in the two classes of oxide systems, namely transport at electroactive grain boundaries and surface behavior of ferroelectric materials. Scanning…

Materials Science · Physics 2007-05-23 Sergei V. Kalinin

The Poisson-Boltzmann equation for a strongly charged plate inside a generic charge-asymmetric electrolyte is solved using the method of asymptotic matching. Both near field and far field asymptotic behaviors of the potential are…

Soft Condensed Matter · Physics 2015-06-05 Ming Han , Xiangjun Xing

The structure of dilute electrolyte solutions close to a surface carrying a spatially inhomogeneous surface charge distribution is investigated by means of classical density functional theory (DFT) within the approach of fundamental measure…

Soft Condensed Matter · Physics 2020-06-23 Maximilian Mußotter , Markus Bier , S. Dietrich

The ion distribution of electrolytes near interfaces with dielectric contrast has important consequences for electrochemical processes and many other applications. To date, most studies of such systems have focused on geometrically simple…

Soft Condensed Matter · Physics 2018-11-14 Huanxin Wu , Honghao Li , Francisco J. Solis , Monica Olvera de la Cruz , Erik Luijten

Kelvin probe force microscopy (KPFM) is a powerful tool for studying contact electrification at the nanoscale, but converting KPFM voltage maps to charge density maps is non-trivial due to long-range forces and complex system geometry. Here…

Soft Condensed Matter · Physics 2022-11-30 Felix Pertl , Juan Carlos Sobarzo , Lubuna Shafeek , Tobias Cramer , Scott Waitukaitis

Lithium niobate has emerged as a promising platform for integrated quantum optics, enabling efficient generation, manipulation, and detection of quantum states of light. However, integrating single-photon detectors requires cryogenic…