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The Kelvin-Planck statement of the Second Law of Thermodynamics is a stricture on the nature of heat receipt by any body suffering a cyclic process. It makes no mention of temperature or of entropy. Beginning with a Kelvin-Planck statement…

Mathematical Physics · Physics 2023-08-28 Martin Feinberg , Richard B. Lavine

The dynamics of a central spin-1/2 in presence of a local magnetic field and a bath of N spin-1/2 particles is studied in the thermodynamic limit. The interaction between the spins is Heisenberg XY type and the bath is considered to be a…

Quantum Physics · Physics 2008-11-26 J. Rodríguez Garzón , R. M. Gutiérrez

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

We improve on our version of the second law of thermodynamics as a deterministic theorem for quantum spin systems in two basic aspects. The first concerns the general statement of the second law: spontaneous changes in an adiabatically…

Quantum Physics · Physics 2026-04-14 Walter F. Wreszinski

Small spin systems at the interface between analytical studies and experimental application have been intensively studied in recent decades. The spin ring consisting of four spins with uniform antiferromagnetic Heisenberg interaction is an…

Statistical Mechanics · Physics 2023-04-19 Heinz-Jürgen Schmidt , Christian Schröder

In a recent companion paper, we observed that the rules of ordinary thermodynamics generally fail to respect thermal duality, a symmetry of string theory under which the physics at temperature T is related to the physics at the inverse…

High Energy Physics - Theory · Physics 2009-11-10 Keith R. Dienes , Michael Lennek

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

The concept of entropy has been pivotal in the formulation of thermodynamics. For systems driven away from thermal equilibrium, a comparable role is played by entropy production and dissipation. Here we provide a comprehensive picture how…

Soft Condensed Matter · Physics 2025-05-15 Robin Bebon , Joshua F. Robinson , Thomas Speck

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

Statistical Mechanics · Physics 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

In the context of non-relativistic quantum mechanics, we investigated Shannon's entropy of a non-Hermitian system to understand how this quantity is modified with the cyclotron frequency. Subsequently, we turn our attention to the…

Quantum Physics · Physics 2021-05-07 F. C. E. Lima , A. R. P. Moreira , C. A. S. Almeida

Thermodynamics of a pseudospin-electron model without correlations is investigated. The correlation functions, the mean values of pseudospin and particle number, as well as the thermodynamic potential are calculated. The calculation is…

Superconductivity · Physics 2014-02-17 I. V. Stasyuk , A. M. Shvaika , K. V. Tabunshchyk

It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

System consisting of a number of trapped atoms evolving under the influence of external inhomogenous magnetic field undergoes spin dephasing: classically, since each atom feels different field along its trajectory, the spin rotation rates…

Quantum Physics · Physics 2020-02-05 Konrad Szymański , Krzysztof Pawłowski

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

The eigenstate thermalisation hypothesis (ETH) is a statistical characterisation of eigen-energies, eigenstates and matrix elements of local operators in thermalising quantum systems. We develop an ETH-like ansatz of a partially…

Quantum Physics · Physics 2022-08-01 Philip JD Crowley , Anushya Chandran

Here we investigate how local properties of particles in a thermal bath influence the thermodynamics of the bath. We utilize nanothermodynamics, based on two postulates: that small systems can be treated self-consistently by coupling to an…

Statistical Mechanics · Physics 2022-10-26 Ralph V. Chamberlin , Michael R. Clark , Vladimiro Mujica , George H. Wolf

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…

Quantum Physics · Physics 2019-05-01 Mirjam Weilenmann , Lea Krämer Gabriel , Philippe Faist , Renato Renner

We provide a versatile analytical framework for calculating the dynamics of a spin system in contact with a fermionic bath beyond the Markov approximation. The approach is based on a second order expansion of the Nakajima-Zwanzig master…

Mesoscale and Nanoscale Physics · Physics 2019-10-18 Stephanie Matern , Daniel Loss , Jelena Klinovaja , Bernd Braunecker