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Oxygen molecules are found to exhibit non-negligible reactivity with graphene under strong light irradiation in the presence of water. The reaction is triggered by the laser Raman spectroscopy measurement itself, and the D band (ca. 1340…

Materials Science · Physics 2013-11-15 Nobuhiko Mitoma , Ryo Nouchi , Katsumi Tanigaki

The electronic structure of few-layer graphene (FLG) samples with crystalline order was investigated experimentally by infrared absorption spectroscopy for photon energies ranging from 0.2 - 1 eV. Distinct optical conductivity spectra were…

Materials Science · Physics 2015-05-18 Kin Fai Mak , Jie Shan , Tony F. Heinz

The electronic structure in the vicinity of the 1-heptagonal and 1-pentagonal defects in the carbon graphene plane is investigated. Using a continuum gauge field-theory model the local density of states around the Fermi energy is calculated…

Mesoscale and Nanoscale Physics · Physics 2011-12-06 J. Smotlacha , R. Pincak , M. Pudlak

Raman spectroscopy, a fast and nondestructive imaging method, can be used to monitor the doping level in graphene devices. We fabricated chemical vapor deposition (CVD) grown graphene on atomically flat hexagonal boron nitride (hBN) flakes…

Materials Science · Physics 2013-12-09 Kanokporn Chattrakun , Shengqiang Huang , K. Watanabe , T. Taniguchi , A. Sandhu , B. J. LeRoy

An analytical study is presented of the double resonant Raman scattering process in graphene, responsible for the D and D$^{\prime}$ features in the Raman spectra. This work yields analytical expressions for the D and D$^{\prime}$…

Mesoscale and Nanoscale Physics · Physics 2015-01-29 J. F. Rodriguez-Nieva , E. B. Barros , R. Saito , M. S. Dresselhaus

We report about investigations of time-dependent structural modifications in single crystal graphene due to laser irradiation even at moderate power levels of 1mW in a diffraction limited spot. The structural modifications have been…

The doping of graphene to tune its electronic structure is essential for its further use in carbon based electronics. Adapting strategies from classical silicon based semiconductor technology, we use the incorporation of heteroatoms in the…

In this work, the effect of the ion fluence-dependent defect formation on the modification of surface electronic and optical properties of graphene has been investigated. The chemical vapor deposited (CVD) graphene was irradiated with swift…

Materials Science · Physics 2022-06-14 Tanmay Mahanta , Sanjeev Kumar , D. Kanjilal , Tanuja Mohanty

Electronic band structures in hydrogenated graphene are theoretically investigated by means of first-principle calculations and an effective tight-binding model. It is shown that regularly designed hydrogenation to graphene gives rise to a…

Mesoscale and Nanoscale Physics · Physics 2024-08-05 Yong-Cheng Jiang , Toshikaze Kariyado , Xiao Hu

Using the GW approximation, we study the electronic structure of the recently synthesized hydrogenated graphene, named graphane. For both conformations, the minimum band gap is found to be direct at the $\Gamma$ point, and it has a value of…

Materials Science · Physics 2015-05-13 S. Lebegue , M. Klintenberg , O. Eriksson , M. I. Katsnelson

The dependence of the Raman spectrum on the excitation energy has been investigated for ABA-and ABC- stacked few-layer graphene in order to establish the fingerprint of the stacking order and the number of layers, which affect the transport…

Mesoscale and Nanoscale Physics · Physics 2014-04-23 The An Nguyen , Jae-Ung Lee , Duhee Yoon , Hyeonsik Cheong

The electronic structure of two-dimensional (2D) semiconductors can be significantly altered by screening effects, either from free charge carriers in the material itself, or by environmental screening from the surrounding medium. The…

Understanding the phenomenon of intense photoluminescence in carbon materials such as hydrogenated graphene, graphene nanoribbons, etc. is at the forefront of investigations. In this study, six different types of hydrogenated graphene (phG)…

Chemical Physics · Physics 2018-05-31 Volker Strauss , Ricarda A. Schäfer , Frank Hauke , Andreas Hirsch , Dirk M. Guldi

Few-layer graphene deposited on semiconductor nanorods separated by undoped spacers has been studied in perspective for the fabrication of stable nanoresonators. We show that an applied bias between the graphene layer and the nanorod…

We study the structural and electronic properties of phase III of solid hydrogen using accurate many-electron theories and compare to state-of-the-art experimental findings. The atomic structures of phase III modelled by C2/c-24 crystals…

Materials Science · Physics 2021-02-24 Ke Liao , Tong Shen , Xin-Zheng Li , Ali Alavi , Andreas Grüneis

This work presents a systematic review of the feature-rich essential properties in graphene-related systems using the first-principles method. The geometric and electronic properties are greatly diversified by the number of layers, the…

Chemical Physics · Physics 2017-02-14 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Chiun-Yan Lin , Ming-Fa Lin

We investigate the signature of the low-energy electronic excitations in the Raman spectrum of monolayer and bilayer graphenes. The dominant contribution to the Raman spectra is due to the interband electron-hole pairs, which belong to the…

Mesoscale and Nanoscale Physics · Physics 2012-12-12 Oleksiy Kashuba , Vladimir I. Fal'ko

The Raman shift, broadening, and relative Raman intensities of bilayer graphene are computed as functions of the electron concentration. We include dynamic effects for the phonon frequencies and we consider the gap induced in the band…

Materials Science · Physics 2009-09-11 Paola Gava , Michele Lazzeri , A. Marco Saitta , Francesco Mauri

The electronic properties and optical excitations are investigated in the geometry- and field-modulated bilayer graphene systems, respectively, by using the tight-binding model and Kubo formula. The stacking symmetry of bilayer graphene can…

Mesoscale and Nanoscale Physics · Physics 2019-07-23 Chiun-Yan Lin , Ming-Fa Lin

Adsorption of hydrogen atoms to a carbon atom vacancy in graphene is investigated by means of periodic \emph{first principles} calculations, up to the fully hydrogenated state where six H atoms chemically bind to the vacancy. Addition of a…

Materials Science · Physics 2013-12-30 M. Casartelli , S. Casolo , G. F. Tantardini , R. Martinazzo