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An efficient route to synthesize macroscopic amounts of graphene is highly desired and a bulk characterization of such samples, in terms of the number of layers, is equally important. We present a Raman spectroscopy-based method to…

Graphene and few-layer graphene at high bias expose a wealth of phenomena due to the high temperatures reached. With in-situ transmission electron microscopy (TEM) we observe directly how the current modifies the structure, and vice versa.…

Mesoscale and Nanoscale Physics · Physics 2013-01-30 Amelia Barreiro , Felix Boerrnert , Mark H. Ruemmeli , Bernd Buechner , Lieven M. K. Vandersypen

Using a scanning electron microscope, we observed a reproducible, discrete distribution of secondary electron intensity stemming from an atomically thick graphene film on a thick insulating substrate. The discrete distribution made it…

Materials Science · Physics 2010-09-29 Hidefumi Hiura , Hisao Miyazaki , Kazuhito Tsukagoshi

Synthesis of graphene with reduced use of chemical reagents is essential for manufacturing scale-up and to control its structure and properties. In this paper, we report on a novel chemical-free mechanism of graphene exfoliation from…

We have developed a method for depositing graphene monolayers and bilayers with minimum lateral dimensions of 2-10 nm by the mechanical exfoliation of graphite onto the Si(100)-2x1:H surface. Room temperature, ultra-high vacuum (UHV)…

Materials Science · Physics 2009-11-13 Kyle A. Ritter , Joseph W. Lyding

Graphite is a well-studied material with known electronic and optical properties. Graphene, on the other hand, which is just one layer of carbon atoms arranged in a hexagonal lattice, has been studied theoretically for quite some time but…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 F. Molitor , D. Graf , C. Stampfer , T. Ihn , K. Ensslin

We demonstrate using graphene sheets as a novel mass standard in the scanning transmission electron microscopy (STEM) based mass spectrometry. Here, free-standing graphene sheets are investigated by STEM. The discrete number of graphene…

Mesoscale and Nanoscale Physics · Physics 2011-04-11 Fengqi Song , Ziyou Li , Zhiwei Wang , Longbing He , Min Han , Guanghou Wang

The removal of single atomic layers from multi-layer graphene using a He plasma is reported. By applying sample biases of -60 and +60 V during He plasma exposure, layer removal is found to be due to electrons instead of He ions or neutrals…

Materials Science · Physics 2012-02-17 Jason D. Jones , Rakesh K. Shah , Guido F. Verbeck , Jose M. Perez

Few layer graphene (FLG) was synthesized by $\mu$-wave assisted exfoliation of expanded graphite in toluene with an overall yield from c.a. 7% to 20%. A significant difference in the absorption of $\mu$-waves by the expanded graphite and…

The electronic properties of a graphene sheet with attached hydrogen atoms is studied using a modified Falicov-Kimball model on the honeycomb lattice. It is shown that in the ground state this system separates into two phases: fully…

Mesoscale and Nanoscale Physics · Physics 2012-11-30 A. L. Rakhmanov , A. V. Rozhkov , A. O. Sboychakov , Franco Nori

Interfacing graphene with solid-state devices and maintaining it free of contamination is a crucial step towards a functioning device, be it a semiconductor structure or any other device for technological applications. We take advantage of…

Mesoscale and Nanoscale Physics · Physics 2014-08-27 Jean-Nicolas Longchamp , Conrad Escher , Hans-Werner Fink

A fluid-based method is demonstrated for preparing graphene nanomeshes (GNMs) directly from pristine graphite flakes by a one-step process. The high efficiency is attributed to the combination of fluid-assisted exfoliation and perforation…

Other Condensed Matter · Physics 2016-11-02 Shuaishuai Liang , Min Yi , Zhigang Shen , Lei Liu , Xiaojing Zhanga , Shulin Ma

Owing to wide variety of applications of graphene, high-quality and economical way of synthesizing graphene is highly desirable. In this study, we report a cost effective and simple approach to production of high-quality graphene. Here the…

Materials Science · Physics 2013-10-29 Prashant Tripathi , Ch. Ravi Prakash Patel , M. A. Shaz , O. N. Srivastava

Microstructure characterization is of great value to understanding nuclear graphite's properties and irradiation behavior. However, graphite is soft and could be easily damaged during sample preparation. A three-step polishing method…

Materials Science · Physics 2021-06-07 Qing Huang , Hui Tang

Following the discovery of graphene, keen attentions have been paid in comprehending the noticeably superior electromagnetic, optical and absorptive properties of few layer graphene (FLG) with rotational-stacking-faults. With achieving…

Raman spectroscopy is one of the widely used methods in the analysis of various samples including carbon-based materials. This study aimed to identify the number of layers and defects in graphene using micro-Raman spectroscopy. More…

Optics · Physics 2024-03-21 Somayeh Gholipour , Maryam Bahreini , Mohamad Reza Jafarfard

This study reports the successful synthesis of multilayered graphene sheets via microwave atmospheric pressure plasma. This innovative approach streamlines and expedites graphene production and other carbon nanostructures, eliminating the…

Plasma Physics · Physics 2024-03-07 Waqas Iqbal , Najeeb-ur-Rehman , Niaz Wali

We present Raman spectroscopy measurements on single- and few-layer graphene flakes. Using a scanning confocal approach we collect spectral data with spatial resolution, which allows us to directly compare Raman images with scanning force…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 D. Graf , F. Molitor , K. Ensslin , C. Stampfer , A. Jungen , C. Hierold , L. Wirtz

We demonstrate how self-assembled monolayers of aromatic molecules on copper substrates can be converted into high-quality single-layer graphene using low-energy electron irradiation and subsequent annealing. We characterize this…

It is shown, by DFT calculations, that the uniform functionalization of upper layer of graphite by hydrogen or fluorine does not change essentially its bonding energy with the underlying layers, whereas the functionalization by phenyl…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 D. W. Boukhvalov , M. I. Katsnelson
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