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We present a simple, robust and black-box approach to the implementation and use of local, periodic, atom-centered Gaussian basis functions within a plane wave code, in a computationally efficient manner. The procedure outlined is based on…

Strongly Correlated Electrons · Physics 2016-09-21 George H. Booth , Theodoros Tsatsoulis , Garnet Kin-Lic Chan , Andreas Grüneis

Tensor network states and parton wave functions are two pivotal methods for studying quantum many-body systems. This work connects these two subjects as we demonstrate that a variety of parton wave functions, such as projected Fermi sea and…

Strongly Correlated Electrons · Physics 2020-06-22 Ying-Hai Wu , Lei Wang , Hong-Hao Tu

An approximation to the many-body London dispersion energy in molecular systems is expressed as a functional of the occupied orbitals only. The method is based on the local-RPA theory. The occupied orbitals are localized molecular orbitals…

Chemical Physics · Physics 2015-12-25 Bastien Mussard , Janos Angyan

General formulas of the two-electron operator representing either atomic or effective interactions are given in a coupled tensorial form in relativistic approximation. The alternatives of using uncoupled, coupled and antisymmetric…

Atomic Physics · Physics 2010-04-30 Rytis Jursenas , Gintaras Merkelis

Choosing a basis set is the first step of a quantum chemistry calculation and it sets its maximum accuracy. This choice of orbitals is limited by strong technical constraints as one must be able to compute a large number of six dimensional…

Strongly Correlated Electrons · Physics 2026-02-04 Nicolas Jolly , Yuriel Núñez Fernández , Xavier Waintal

We present a low-complexity algorithm to calculate the correlation energy of periodic systems in second-order M\o ller-Plesset perturbation theory (MP2). In contrast to previous approximation-free MP2 codes, our implementation possesses a…

Chemical Physics · Physics 2017-03-16 Tobias Schäfer , Benjamin Ramberger , Georg Kresse

In this paper, we introduce a method for multivariate function approximation using function evaluations, Chebyshev polynomials, and tensor-based compression techniques via the Tucker format. We develop novel randomized techniques to…

Numerical Analysis · Mathematics 2021-07-29 Arvind K. Saibaba , Rachel Minster , Misha E. Kilmer

Tensor-network techniques have enjoyed outstanding success in physics, and have recently attracted attention in machine learning, both as a tool for the formulation of new learning algorithms and for enhancing the mathematical understanding…

Machine Learning · Computer Science 2019-12-02 Ivan Glasser , Ryan Sweke , Nicola Pancotti , Jens Eisert , J. Ignacio Cirac

The tensorial form of the spin-other-orbit interaction operator in the formalism of second quantization is presented. Such an expression is needed to calculate both diagonal and off-diagonal matrix elements according to an approach, based…

Atomic Physics · Physics 2009-11-10 G. Gaigalas , A. Bernotas , Z. Rudzikas , C. Froese Fischer

The paper is concerned with the sparse approximation of functions having hybrid regularity borrowed from the theory of solutions to electronic Schr\"odinger equations due to Yserentant [43]. We use hyperbolic wavelets to introduce…

Numerical Analysis · Mathematics 2022-03-21 Glenn Byrenheid , Janina Hübner , Markus Weimar

The paper is devoted to the efficient computation of high-order cubature formulas for volume potentials obtained within the framework of approximate approximations. We combine this approach with modern methods of structured tensor product…

Numerical Analysis · Mathematics 2009-02-13 Flavia Lanzara , Vladimir Maz'ya , Gunther Schmidt

In this paper we consider the problem of recovering a low-rank Tucker approximation to a massive tensor based solely on structured random compressive measurements. Crucially, the proposed random measurement ensembles are both designed to be…

Information Theory · Computer Science 2023-08-29 Cullen Haselby , Mark A. Iwen , Deanna Needell , Elizaveta Rebrova , William Swartworth

We study the decomposition of the Coulomb integrals of periodic systems into a tensor contraction of six matrices of which only two are distinct. We find that the Coulomb integrals can be well approximated in this form already with small…

Chemical Physics · Physics 2017-04-05 Felix Hummel , Theodoros Tsatsoulis , Andreas Grüneis

We measure electron localization in different materials by means of a ``localization tensor'', based on Berry phases and related quantities. We analyze its properties, and we actually compute such tensor from first principles for several…

Materials Science · Physics 2009-11-07 Claudia Sgiarovello , Maria Peressi , Raffaele Resta

In the nonequilibrium Green's function approach, the approximation of the correlation self-energy at the second-Born level is of particular interest, since it allows for a maximal speed-up in computational scaling when used together with…

Computational Physics · Physics 2019-11-11 Riku Tuovinen , Fabio Covito , Michael A. Sentef

We explore a new class of computationally feasible approximations of the two-body density matrix as a finite sum of tensor products of single-particle operators. Physical symmetries then uniquely determine the two-body matrix in terms of…

Materials Science · Physics 2009-09-25 Gabor Csanyi , T. A. Arias

This paper establishes a rigorous connection between circuit representations and tensor factorizations, two seemingly distinct yet fundamentally related areas. By connecting these fields, we highlight a series of opportunities that can…

What learning algorithms can be run directly on compressively-sensed data? In this work, we consider the question of accurately and efficiently computing low-rank matrix or tensor factorizations given data compressed via random projections.…

Machine Learning · Computer Science 2019-05-28 Vatsal Sharan , Kai Sheng Tai , Peter Bailis , Gregory Valiant

Approximation of a tensor network by approximating (e.g., factorizing) one or more of its constituent tensors can be improved by canceling the leading-order error due to the constituents' approximation. The utility of such robust…

Chemical Physics · Physics 2024-07-30 Karl Pierce , Varun Rishi , Edward F. Valeev

We consider functions $f$ of two real variables, given as trigonometric functions over a finite set $F$ of frequencies. This set is assumed to be closed under rotations in the frequency plane of angle $\frac{2k\pi}{M}$ for some integer $M$.…

Numerical Analysis · Mathematics 2016-12-02 Jean-Paul Gauthier , Dario Prandi
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