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A fresh approach to the data from experiments with hard sphere colloids yields seminal insights into the glass transition. The precise determination of the fraction of particles caged by their neighbours is unprecedented and provides…

Soft Condensed Matter · Physics 2021-10-01 W. van Megen , H. J. Schöpe

Recent ideas based on the properties of assemblies of frictionless particles in mechanical equilibrium provide a perspective of amorphous systems different from that offered by the traditional approach originating in liquid theory. The…

Statistical Mechanics · Physics 2009-07-09 R. Mari , F. Krzakala , J. Kurchan

We use confocal microscopy to study the motion of a magnetic bead in a dense colloidal suspension, near the colloidal glass transition volume fraction $\phi_g$. For dense liquid-like samples near $\phi_g$, below a threshold force the…

Soft Condensed Matter · Physics 2009-11-10 P. Habdas , D. Schaar , Andrew C. Levitt , Eric R. Weeks

The shear rheology of soft particles systems becomes complex at large density because crowding effects may induce a glass transition for Brownian particles, or a jamming transition for non-Brownian systems. Here we successfully explore the…

Soft Condensed Matter · Physics 2013-07-30 Atsushi Ikeda , Ludovic Berthier , Peter Sollich

We present a mode-coupling theory for the dynamics of a tagged particle in a driven granular fluid close to the glass transition. The mean-squared displacement is shown to exhibit a plateau indicating structural arrest. In contrast to…

Statistical Mechanics · Physics 2012-11-20 Matthias Sperl , Wolf Till Kranz , Annette Zippelius

In a recent publication we established an analogy between the free energy of a hard sphere system and the energy of an elastic network [1]. This result enables one to study the free energy landscape of hard spheres, in particular to define…

Disordered Systems and Neural Networks · Physics 2007-08-08 Carolina Brito , Matthieu Wyart

We study concentrated binary colloidal suspensions, a model system which has a glass transition as the volume fraction $\phi$ of particles is increased. We use confocal microscopy to directly observe particle motion within dense samples…

Soft Condensed Matter · Physics 2011-05-20 Takayuki Narumi , Scott V. Franklin , Kenneth W. Desmond , Michio Tokuyama , Eric R. Weeks

Hard-sphere colloids are popular as models for testing fundamental theories in condensed matter and statistical physics, from crystal nucleation to the glass transition. A single parameter, the volume fraction (phi), characterizes an ideal,…

Soft Condensed Matter · Physics 2017-12-27 Wilson C. K. Poon , Eric R. Weeks , C. Patrick Royall

We present simulation results addressing the dynamics of a colloidal system with attractive interactions close to gelation. Our interaction also has a soft, long range repulsive barrier which suppresses liquid-gas type phase separation at…

Soft Condensed Matter · Physics 2007-05-23 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

We consider the stationary state of a fluid comprised of inelastic hard spheres or disks under the influence of a random, momentum-conserving external force. Starting from the microscopic description of the dynamics, we derive a nonlinear…

Statistical Mechanics · Physics 2013-02-25 W. T. Kranz , M. Sperl , A. Zippelius

We develop a mode coupling theory(MCT) to study the nonequilibrium glass transition behavior of a mono-disperse mixture of active-passive hard-sphere particles. The MCT equations clearly demonstrate that the glass transition is shifted to…

Soft Condensed Matter · Physics 2015-06-10 Huai Ding , Mengkai Feng , Huijun Jiang , Zhonghuai Hou

Colloidal glasses form from hard spheres, nearly hard spheres, ellipsoids and platelets or their attractive variants have been studied in detail. Complementing and checking theoretical approaches and simulations, the many different types of…

Soft Condensed Matter · Physics 2017-11-15 Ran Niu , Sabrina Heidt , Ramsia Sreij , Riande I. Dekker , Maximilian Hofmann , Thomas Palberg

The liquid-liquid phase transition in high-pressure Hydrogen is a problem of longstanding and controversy. The recent Nature paper by Cheng et al. [vol. 585, p. 217] makes a set of strong claims to the effect that all the previous density…

Other Condensed Matter · Physics 2020-12-29 Valentin V. Karasiev , Joshua Hinz , S. X. Hu , S. B. Trickey

Comprehensive calculations were performed to predict the phase behaviour of large spherical colloids mixed with small spherical colloids that act as depletant. To this end, the free volume theory (FVT) of Lekkerkerker et al. [Europhys.…

Soft Condensed Matter · Physics 2021-01-29 J. Opdam , M. P. M. Schelling , R. Tuinier

We propose a method to study quantitatively the glass transition in a system of interacting particles. In spite of the absence of any quenched disorder, we introduce a replicated version of the hypernetted chain equations. The solution of…

Condensed Matter · Physics 2009-10-28 Marc Mezard , Giorgio Parisi

Among the key insights into the glass transition has been the identification of a non-equilibrium phase transition in trajectory space which reveals phase coexistence between the normal supercooled liquid (active phase) and a glassy state…

Soft Condensed Matter · Physics 2017-07-19 Rattachai Pinchaipat , Matteo Campo , Francesco Turci , James Hallett , Thomas Speck , C. Patrick Royall

Using molecular dynamics simulations we study the slow dynamics of a hard sphere fluid confined in a disordered porous matrix. The presence of both discontinuous and continuous glass transitions as well as the complex interplay between…

Soft Condensed Matter · Physics 2009-09-29 Jan Kurzidim , Daniele Coslovich , Gerhard Kahl

This paper has been withdrawn by the authors. It has been superceded by an improved investigation: ``Thermodynamic Generalized Compressibility in a Glass Forming Liquid,'' H. M. Carruzzo and C. C. Yu, cond-mat/0004320.

Disordered Systems and Neural Networks · Physics 2007-05-23 Herve M. Carruzzo , Clare C. Yu

We investigate the structure and dynamics of a hard colloid-star polymer mixture in the range of its arrested phase separation, where an incipient demixing transition is interfering with a nearby vitrification line, focusing on the protein…

Soft Condensed Matter · Physics 2026-01-13 Konstantin N. Moser , Christos N. Likos , Vittoria Sposini

We analyze the slow, glassy structural relaxation as measured through collective and tagged-particle density correlation functions obtained from Brownian dynamics simulations for a polydisperse system of quasi-hard spheres in the framework…

Soft Condensed Matter · Physics 2010-10-18 F. Weysser , A. M. Puertas , M. Fuchs , Th. Voigtmann