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Variational algorithms for strongly correlated chemical and materials systems are one of the most promising applications of near-term quantum computers. We present an extension to the variational quantum eigensolver that approximates the…

Quantum Physics · Physics 2020-08-26 William J. Huggins , Joonho Lee , Unpil Baek , Bryan O'Gorman , K. Birgitta Whaley

The solution of one--dimensional asymmetric quantum harmonic oscillator is presented. The asymmetry can be realized, for example, by using two springs, one spring is glued with the mass, and the second spring is freely connected with the…

Quantum Physics · Physics 2022-04-14 Goce Chadzitaskos , Jiri Patera

We consider three different approaches to analyze the quantum mechanical problems in multi-well potentials: i) the standard matrix diagonalization technique in the basis sets of harmonic oscillator eigenfunctions or plain waves; ii) the…

Quantum Physics · Physics 2020-12-11 V. P. Berezovoj , Yu. L. Bolotin , V. A. Cherkaskiy , M. I. Konchantnyi

In this paper we show how the quantum mechanics of the inverted harmonic oscillator can be mapped to the quantum mechanics of a particle in a super-critical inverse square potential. We demonstrate this by relating both of these systems to…

Quantum Physics · Physics 2024-05-20 Sriram Sundaram , C. P. Burgess , D. H. J. O'Dell

The random matrix ensembles (RME) of Hamiltonian matrices, e.g. Gaussian random matrix ensembles (GRME) and Ginibre random matrix ensembles (Ginibre RME), are applicable to following quantum statistical systems: nuclear systems, molecular…

Statistical Mechanics · Physics 2007-05-23 Maciej M. Duras

We establish a simple method to assess the quantum Fisher information required for resolving two incoherent point sources with an imaging system. The resulting Cram\'er-Rao bound shows that the standard Rayleigh limit can be surpassed by…

Quantum Physics · Physics 2016-06-28 Martin Paur , Bohumil Stoklasa , Zdenek Hradil , Luis L. Sanchez-Soto , Jaroslav Rehacek

A quantum anharmonic oscillator is defined by the Hamiltonian ${\cal H}= -\frac{ {\rm d^{2}}}{{\rm d}x^{2}} + V(x)$, where the potential is given by $V(x) = \sum_{i=1}^{m} c_{i} x^{2i}$ with $c_{m}>0$. Using the Sinc collocation method…

Numerical Analysis · Mathematics 2014-11-19 Philippe Gaudreau , Richard Slevinsky , Hassan Safouhi

A nonlinear model of the quantum harmonic oscillator on two-dimensional spaces of constant curvature is exactly solved. This model depends of a parameter $\la$ that is related with the curvature of the space. Firstly the relation with other…

Mathematical Physics · Physics 2010-11-11 José F. Cariñena , Manuel F. Rañada , Mariano Santander

We investigate symmetric oscillators, and in particular their quantization, by employing semiclassical and quantum phase functions introduced in the context of Liouville-Green transformations of the Schr\"{o}dinger equation. For anharmonic…

Quantum Physics · Physics 2011-11-10 A. Matzkin , M. Lombardi

The quantum quartic anharmonic oscillator with the Hamiltonian $H=\frac{1}{2}\left( p^{2}+x^{2}\right) +\lambda x^{4}$ is a classical and fundamental model that plays a key role in various branches of physics, including quantum mechanics,…

Quantum Physics · Physics 2025-05-13 V. A. Babenko , A. V. Nesterov

The hyperspherical harmonic basis is used to describe bound states in an $A$--body system. The approach presented here is based on the representation of the potential energy in terms of hyperspherical harmonic functions. Using this…

Computational Physics · Physics 2009-05-13 M. Gattobigio , A. Kievsky , M. Viviani , P. Barletta

For a system of coupled anharmonic oscillators we compare the convergence rate of the variational collocation approach presented recently by Amore and Fernandez (2010 Phys.Scr.81 045011) with the one obtained using the optimized…

Quantum Physics · Physics 2020-09-22 Arkadiusz Kuros , Anna Okopinska

We study a class of quantum two-dimensional models with complex potentials of specific form. They can be considered as the generalization of a recently studied model with quadratic interaction not amenable to conventional separation of…

Mathematical Physics · Physics 2015-06-05 F. Cannata , M. V. Ioffe , D. N. Nishnianidze

We present a variational study of employing the trigonometric basis functions satisfying periodic boundary condition for the accurate calculation of eigenvalues and eigenfunctions of quartic double-well oscillators. Contrary to usual…

Mathematical Physics · Physics 2013-08-06 P. Pedram , M. Mirzaei , S. S. Gousheh

The Variational Quantum Eigensolver (VQE) is a promising candidate for quantum applications on near-term Noisy Intermediate-Scale Quantum (NISQ) computers. Despite a lot of empirical studies and recent progress in theoretical understanding…

Quantum Physics · Physics 2022-05-26 Xuchen You , Shouvanik Chakrabarti , Xiaodi Wu

Besides perturbation theory, which requires, of course, the knowledge of the exact unperturbed solution, variational techniques represent the main tool for any investigation of the eigenvalue problem of some semibounded operator H in…

High Energy Physics - Phenomenology · Physics 2016-12-28 Wolfgang Lucha , F. F. Schoberl

In the present article a family of quantum anharmonic oscillators is studied using Hermite's function basis (Fock's basis) in the Hilbert space. The numerical investigation of the eigenenergies of that family is presented. The statistical…

Statistical Mechanics · Physics 2011-11-10 Maciej M. Duras

Exact solvability (typically, of harmonic oscillators) in quantum mechanics usually implies an elementary form of the spectrum while in all the "next-to-solvable" models, the energies E are only available in an implicit form (typically, as…

Computational Physics · Physics 2007-05-23 Miloslav Znojil

Subspace methods are commonly used for finding approximate eigenvalues and singular values of large-scale matrices. Once a subspace is found, the Rayleigh-Ritz method (for symmetric eigenvalue problems) and Petrov-Galerkin projection (for…

Numerical Analysis · Mathematics 2025-10-07 Irina-Beatrice Haas , Yuji Nakatsukasa

We propose a new analytical method to solve for the nonexactly solvable Schrodinger equation. Successfully, it is applied to a class of spiked harmonic oscillators and truncated Coulomb potentials. The utility of this method could be…

Mathematical Physics · Physics 2009-10-31 Omar Mustafa , Maen Odeh