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We determine trapping conditions for ultracold polar molecules, where pairs of internal states experience identical trapping potentials. Such conditions could ensure that detrimental effects of inevitable inhomogeneities across an ultracold…

Atomic Physics · Physics 2015-06-12 Alexander Petrov , Constantinos Makrides , Svetlana Kotochigova

Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

We theoretically investigate trapping conditions for ultracold polar molecules in optical lattices, when external magnetic and electric fields are simultaneously applied. Our results are based on an accurate electronic-structure calculation…

Quantum Physics · Physics 2017-08-29 Ming Li , Alexander Petrov , Constantinos Makrides , Eite Tiesinga , Svetlana Kotochigova

We investigate the effects of static electric and magnetic fields on the differential ac Stark shifts for microwave transitions in ultracold bosonic $^{87}$Rb$^{133}$Cs molecules, for light of wavelength $\lambda = 1064~\mathrm{nm}$. Near…

We demonstrate that the differential ac-Stark shift of a ground-state hyperfine transition in an optical trap can be eliminated by using properly polarized trapping light. We use the vector polarizability of an alkali-metal atom to produce…

Atomic Physics · Physics 2015-06-17 Huidong Kim , Hyok Sang Han , D. Cho

We investigate the effect of far-off-resonant trapping light on ultracold bosonic RbCs molecules. We use kHz-precision microwave spectroscopy to measure the differential AC Stark shifts between the ground and first excited rotational levels…

Sideband cooling is a popular method for cooling atoms to the ground state of an optical trap. Applying the same method to molecules requires a number of challenges to be overcome. Strong tensor Stark shifts in molecules cause the optical…

Atomic Physics · Physics 2020-03-11 L. Caldwell , M. R. Tarbutt

A detailed treatment of an electro-optical trap for polar molecules, realized by embedding an optical trap within a uniform electrostatic field, is presented and the trap's properties analyzed and discussed. The electro-optical trap offers…

Atomic Physics · Physics 2022-06-15 Bretislav Friedrich

We report the measurement of the anisotropic AC polarizability of ultracold polar $^{40}$K$^{87}$Rb molecules in the ground and first rotationally excited states. Theoretical analysis of the polarizability agrees well with experimental…

Atomic Physics · Physics 2012-12-11 B. Neyenhuis , B. Yan , S. A. Moses , J. P. Covey , A. Chotia , A. Petrov , S. Kotochigova , J. Ye , D. S. Jin

We investigate magic-wavelength trapping of ultracold bialkali molecules in the vicinity of weak optical transitions from the vibrational ground state of the X$^1\Sigma^+$ potential to low-lying rovibrational states of the b$^3\Pi_0$…

Quantum Physics · Physics 2021-04-14 Q. Guan , S. L. Cornish , S. Kotochigova

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

Laser cooling and magneto-optical trapping of molecules typically involves multiple transitions driven by several laser frequencies. We analyze how magneto-optical trapping forces depend on the angular momenta, $F_l$ and $F_u$, and the…

Atomic Physics · Physics 2015-06-22 M. R. Tarbutt

In optical dipole traps, the excited rotational states of a molecule may experience a very different light shift than the ground state. For particles with two polarizability components (parallel and perpendicular), such as linear $^1\Sigma$…

Atomic Physics · Physics 2018-07-26 Till Rosenband , David D. Grimes , Kang-Kuen Ni

Polar molecules are desirable systems for quantum simulations and cold chemistry. Molecular ions are easily trapped, but a bias electric field applied to polarize them tends to accelerate them out of the trap. We present a general solution…

Optical microtraps provide a strong spatial confinement for laser-cooled atoms. They can, e.g., be realized with strongly focused trapping light beams or the optical near fields of nano-scale waveguides and photonic nanostructures. Atoms in…

We report on the optical polarizability of microwave-shielded ultracold NaCs molecules in an optical dipole trap. While dressing a pair of rotational states with a microwave field, we observe a marked dependence of the optical…

Quantum Gases · Physics 2025-01-16 Siwei Zhang , Weijun Yuan , Niccolò Bigagli , Claire Warner , Ian Stevenson , Sebastian Will

We analyze the ac Stark shift of a cesium atom interacting with far-off-resonance guided light fields in the nanofiber-based two-color optical dipole trap realized by Vetsch \textit{et al.} [Phys. Rev. Lett. \textbf{104}, 203603, (2010)].…

Atomic Physics · Physics 2013-09-25 Fam Le Kien , Philipp Schneeweiss , Arno Rauschenbeutel

Proposals for quantum computing using rotational states of polar molecules as qubits have previously considered only diatomic molecules. For these the Stark effect is second-order, so a sizable external electric field is required to produce…

Quantum Physics · Physics 2015-05-30 Qi Wei , Sabre Kais , Bretislav Friedrich , Dudley Herschbach

Highly excited Rydberg states are usually extremely polarizable and exceedingly sensitive to electric fields. Because of this Rydberg ions confined in electric fields have state-dependent trapping potentials. We engineer a Rydberg state…

Atomic Physics · Physics 2020-05-27 Fabian Pokorny , Chi Zhang , Gerard Higgins , Markus Hennrich

Ultracold molecules trapped in optical tweezers show great promise for the implementation of quantum technologies and precision measurements. We study a prototypical scenario where two interacting polar molecules placed in separate traps…

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