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Related papers: The Michaelis-Menten-Stueckelberg Theorem

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The prevalent scheme of a diffusion-mediated bimolecular reaction $A+B\rightarrow P$ is an adaptation of that proposed by Briggs and Haldane for enzyme action [{\em Biochem J.\/}, 19:338--339, 1925]. The purpose of this Note is to explain,…

Chemical Physics · Physics 2014-11-11 K. Razi Naqvi

The evolution of the joint system (JS) - ``quantum system (QS)+thermal bath (TB)" is considered in the framework of a complex probabilistic processes that satisfies the stochastic differential equation of the Langevin-Schr\"{o}dinger type.…

Quantum Physics · Physics 2020-08-04 Ashot Gevorkyan

In integrable many-particle systems, it is widely believed that the stationary state reached at late times after a quantum quench can be described by a generalized Gibbs ensemble (GGE) constructed from their extensive number of conserved…

The chemical fueling of transient states (CFTS) is a powerful process to control the nonequilibrium structuring and the homeostatic function of adaptive soft matter systems. Here, we introduce a mean-field model of CFTS based on the…

Soft Condensed Matter · Physics 2023-06-12 Sven Pattloch , Joachim Dzubiella

Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail)…

Statistical Mechanics · Physics 2013-11-13 Peter Reimann , Mykhaylo Evstigneev

A century ago, the foundations of equilibrium statistical mechanics were laid. For a system in equilibrium with a thermal bath, much is understood through the Boltzmann factor, exp{-H[C]/kT}, for the probability of finding the system in any…

Statistical Mechanics · Physics 2009-10-31 R. K. P. Zia , L. B. Shaw , B. Schmittmann , R. J. Astalos

In biochemical networks, reactions often occur on disparate timescales and can be characterized as either "fast" or "slow." The quasi-steady state approximation (QSSA) utilizes timescale separation to project models of biochemical networks…

Molecular Networks · Quantitative Biology 2015-06-19 Jae Kyoung Kim , Krešimir Josić , Matthew R. Bennett

We investigate a kinetic model of a system in contact with several thermal reservoirs at different temperatures $T_\alpha$. Our system is a spatially uniform dilute gas whose internal dynamics is described by the nonlinear Boltzmann…

Mathematical Physics · Physics 2014-06-17 Eric A. Carlen , Joel L. Lebowitz , Clement Mouhot

We review the non-relativistic Green's-function approach to the kinetic equations for Fermi liquids far from equilibrium. The emphasis is on the consistent treatment of the off-shell motion between collisions and on the non-instant and…

Nuclear Theory · Physics 2017-03-08 P. Lipavsky , K. Morawetz , V. Spicka

The atmospheric reaction of H$_2$S with Cl has been reinvestigated to check if, as previously suggested, only explicit dynamical computations can lead to an accurate evaluation of the reaction rate because of strong recrossing effects and…

Chemical Physics · Physics 2020-07-21 Jacopo Lupi , Cristina Puzzarini , Carlo Cavallotti , Vincenzo Barone

We consider quantum quenches in the integrable $SU(3)$-invariant spin chain (Lai-Sutherland model) which admits a Bethe ansatz description in terms of two different quasiparticle species, providing a prototypical example of a model solvable…

Statistical Mechanics · Physics 2019-06-20 Lorenzo Piroli , Eric Vernier , Pasquale Calabrese , Balázs Pozsgay

Complex systems can be advantageously modeled by formal reaction systems (RS), a.k.a. chemical reaction networks in chemistry. Reaction-based models can indeed be interpreted in a hierarchy of semantics, depending on the question at hand,…

Molecular Networks · Quantitative Biology 2024-06-27 Hugo Buscemi , François Fages

After a brief review of the present status of nonextensive statistical mechanics, we present a conjectural scenario where mixing (characterized by the entropic index $q_{mix} \le 1$) and equilibration (characterized by the entropic index…

Statistical Mechanics · Physics 2015-06-24 Constantino Tsallis , Ernesto P. Borges , Fulvio Baldovin

The semiclassical Boltzmann equation is widely used to study transport effects. However, being semiclassical and borrowing heavily from classical mechanics, the formalism calls for verification from the perspective of quantum mechanics.…

Mesoscale and Nanoscale Physics · Physics 2025-08-05 Da Ma , Zhi-Fan Zhang , Hua Jiang , X. C. Xie

A relation giving a minimum for the irreversible work in quasi-equilibrium processes was derived by Sekimoto et al. (K. Sekimoto and S. Sasa, J. Phys. Soc. Jpn. {\bf 66} (1997), 3326) in the framework of stochastic energetics. This relation…

Statistical Mechanics · Physics 2015-03-13 E. Sergio Santini , M. Florencia Carusela , Eduardo D. Izquierdo

Classical theories of chemical kinetics assume independent reactions in dilute solutions, whose rates are determined by mean concentrations. In condensed matter, strong interactions alter chemical activities and create inhomogeneities that…

Materials Science · Physics 2013-04-17 Martin Z. Bazant

Relaxation dynamics of complex quantum systems with strong interactions towards the steady state is a fundamental problem in statistical mechanics. The steady state of subsystems weakly interacting with their environment is described by the…

Statistical Mechanics · Physics 2016-06-22 Alexey M. Shakirov , Yulia E. Shchadilova , Alexey N. Rubtsov

We construct a model for a particle in the framework of the theory of Stueckelberg, Horwitz and Piron (SHP) as an ensemble of events subject to the laws of covariant classical equilibrium statistical mechanics. The canonical and grand…

Classical Physics · Physics 2017-06-28 Lawrence Horwitz

After a sudden disruption, weakly interacting quantum systems first relax to a prethermalized state that can be described by perturbation theory and a generalized Gibbs ensemble. Using these properties of the prethermalized state we…

Strongly Correlated Electrons · Physics 2013-08-27 Michael Stark , Marcus Kollar

Quasiparticle dynamics in relativistic plasmas associated with hot, weakly-coupled gauge theories (such as QCD at asymptotically high temperature $T$) can be described by an effective kinetic theory, valid on sufficiently large time and…

High Energy Physics - Phenomenology · Physics 2010-02-16 Peter Arnold , Guy D. Moore , Laurence G. Yaffe