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The magnetic, dielectric and structural properties of type-I multiferroic KNiPO$_4$ have been investigated by neutron powder diffraction, magnetization, dielectric and high temperature synchrotron-XRD measurements. Below the N\'{e}el…

Strongly Correlated Electrons · Physics 2022-07-15 Alexandre Pages , Jian-Rui Soh , Marjaneh Jafari Fesharaki , Henrik M. Ronnow , Hossein Ahmadvand

The octahedral tilting and ferroelectric-like structural transition of LiOsO3 metallic perovskite [Nature Materials 12, 1024 (2013)] was examined using first-principles density-functional theory. In LiOsO3, a-a-a- octahedral titling mode is…

Materials Science · Physics 2015-06-17 Hyunsu Sim , Bog G. Kim

Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition…

We report a temperature-dependent neutron diffraction (ND) study on polycrystalline monoclinic BaIrO$_3$ which is famous for charge density wave (CDW) and weak ferromagnetic phase transitions at T$_C$$\sim$180 K simultaneously. A Rietveld…

Strongly Correlated Electrons · Physics 2023-08-17 Bin Chang , Jinwon Jeong , Han-Jin Noh , Seongsu Lee

The normal ferroelectric to paraelectric phase transition in model ferroelectric materials such as BaTiO3 is typically characterized by a sharp, well-defined dielectric constant peak at a specific transition temperature. However, under…

Materials Science · Physics 2025-10-17 Prithwiraj Ganguly , Prashant Joshi , Maneesha Puthiyoth , Dilip Sasmal , Somaditya Sen

Identification of novel multiferroic materials with high-ordering temperatures remains at the forefront of condensed matter physics research. In this regard, the antiferromagnetic RCrO$_3$ compounds (like GdCrO$_3$) constitute a promising…

We report the results of our investigations on a polycrystalline sample of Lu$_2$Ir$_3$Si$_5$ which crystallizes in the U$_2$Co$_3$Si$_5$ type structure (Ibam). These investigations comprise powder X-ray diffraction, magnetic…

Strongly Correlated Electrons · Physics 2017-07-26 Yogesh Singh , Dilip Pal , S. Ramakrishnan , A. M. Awasthi , S. K. Malik

Dielectric spectroscopy of $SrTiO_3$ single crystal over a broad range of microwave frequency using quasi $TE_{m,1,1}$ and quasi $TM_{m,1,1}$ modes reveals crystal asymmetry from typical measurement of $Q$-factor, transmission or frequency…

Materials Science · Physics 2025-05-22 M. A. Hosain , J-M. Le Floch , J. F. Bourhill , J. Krupka , M. E. Tobar

Ferroelectricity is observed in orthorhombic $HoMnO_3$ and $YMnO_3$ at the magnetic lock-in transitions into an E-type structure or an incommensurate phase with a temperature independent wave vector, respectively. In $HoMnO_3$ the…

Strongly Correlated Electrons · Physics 2011-11-09 B. Lorenz , Y. Q. Wang , C. W. Chu

A new-type structural transition has been found in Li2RuO3 with honeycomb lattice of edge-sharing RuO6-octahedra. With decreasing temperature T, the electrical resistivity exhibits an anomalous increase at T=Tc~540 K, suggesting the (metal…

Strongly Correlated Electrons · Physics 2015-06-25 Yoko Miura , Yukio Yasui , Masatoshi Sato , Naoki Igawa , Kazuhisa Kakurai

We report the observation of a phase transition in a KTaO$_3$ crystal, corresponding to a paraelectric-to-ferroelectric transition. The crystal was placed inside a copper cavity to form a dielectric-loaded microwave cavity, and the…

Materials Science · Physics 2025-07-23 Zijun C. Zhao , Jeremy F. Bourhill , Maxim Goryachev , Aleksey Sadekov , Michael E. Tobar

Multiferroic materials open up the possibility to design novel functionality in electronic devices, with low energy consumption. However, there are very few materials that show multiferroicity at room temperature, which is essential to be…

Using first-principles calculations we examine the band structures of ferromagnetic hexagonal manganites $\mathrm{YXO_3}$ (X=V, Cr, Mn, Fe and Co) in the nonpolar nonsymmorphic $P6_3/mmc$ space group. For $\mathrm{YVO_3}$ and…

Materials Science · Physics 2019-07-03 Sophie F. Weber , Sinéad M. Griffin , Jeffrey B. Neaton

Infrared reflectance spectra of an epitaxial Bi2FeCrO6 thin film prepared by pulsed laser deposition on LaAlO3 substrate were recorded between 10 and 900 K. No evidence for a phase transition to the paraelectric phase was observed, but some…

Materials Science · Physics 2009-01-06 S. Kamba , D. Nuzhnyy , R. Nechache , K. Zaveta , D. Niznansky , E. Santava , C. Harnagea , A. Pignolet

The large electrocaloric coupling in PbZrO3 allows using high-speed infrared imaging to visualize antiferroelectric switching dynamics via the associated temperature change. We find that in ceramic samples of homogeneous temperature and…

We present here the results of frequency dependent dielectric, polarization and powder X-ray powder diffraction studies in the 300 to 100K temperature range for Ba_0.55Sr_0.45TiO_3. The dielectric results indicate a succession of three…

Materials Science · Physics 2007-09-24 Satyendra Singh , Satendra Pal Singh , Dhananjai Pandey

The structural phase transformations of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-30%PT) have been studied using x-ray diffraction (XRD) and neutron scattering as a function of temperature and electric field. We observe the phase transformational…

Materials Science · Physics 2009-11-10 Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , P. M. Gehring , Guangyong Xu , G. Shirane

Perovskite solid solutions PbHfO3-PbSnO3 offer valuable opportunities for studying the formation mechsnisms of incommensurate phases, owing to the presence of an intermediate (between cubic and incommensurate) phase, which is stabilized in…

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

We have investigated the temperature-dependent changes in the near-$E$$_F$ occupied and unoccupied states of Pr$_{0.67}$Ca$_{0.33}$MnO$_3$ which shows the presence of ferromagnetic and antiferromagnetic phases. The temperature-dependent…

Strongly Correlated Electrons · Physics 2009-11-11 M. K. Dalai , P. Pal , B. R. Sekhar , N. L. Saini , R. K. Singhal , K. B. Garg , B. Doyle , S. Nannarone , C. Martin , F. Studer