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This article examines systematic oxygen (O)-incorporation to reduce total leakage currents in sputtered wurtzite-type ferroelectric Al0.73Sc0.27N thin films, along with its impact on the material structure and the polarity of the as-grown…

In complex transition metal oxide heterostructures of physically dissimilar perovskite compounds, interface phenomena can lead to novel physical properties not observed in either of their constituents. This remarkable feature opens new…

Strongly Correlated Electrons · Physics 2011-12-30 Natalia Pavlenko , Thilo Kopp

Transition metal oxides exhibit a wide range of tunable electronic properties arising from the complex interplay of charge, spin, and lattice degrees of freedom, governed by their $d$ orbital configurations, making them particularly…

Unlike widely explored complex oxide heterostructures grown along [001], the study of [111]-oriented heterointerfaces are very limited thus far. One of the main challenges is to overcome the polar discontinuity that hinders the epitaxy of…

Materials Science · Physics 2018-02-14 Minhui Hu , Qinghua Zhang , Lin Gu , Qinlin Guo , Yanwei Cao , M. Kareev , J. Chakhalian , Jiandong Guo

Strain engineering with different substrate facets is promising for tuning functional properties of thin film perovskite oxides. By choice of facet, different surface symmetries and chemical bond directions for epitaxial interfaces can be…

Materials Science · Physics 2020-11-26 K. Kjærnes , T. Bolstad , D. M. Evans , E. Lysne , B. A. D. Williamson , D. Meier , S. M. Selbach , T. Tybell

Emergent behavior at complex oxide interfaces has driven much of the research in the oxide thin film community for the past twenty years. Interfaces have been engineered for potential applications in spintronics, topological quantum…

Materials Science · Physics 2021-07-06 Suresh Thapa , Rajendra Paudel , Miles D. Blanchet , Patrick T. Gemperline , Ryan B. Comes

Understanding the physics of structurally and chemically complex transition-metal oxide and polyanionic materials such as those used for battery electrodes is challenging, even at the level of pristine compounds. Yet these materials are…

Materials Science · Physics 2018-07-19 Khang Hoang , M D Johannes

The mechanism responsible for the extraordinary interface conductivity of LaAlO$_{3}$ on SrTiO$_{3}$ and its insulator-metal transition remains controversial. Here, using density functional theory calculations, we establish a comprehensive…

Strongly Correlated Electrons · Physics 2015-07-21 Jun Zhou , Teguh Citra Asmara , Ming Yang , George A. Sawatzky , Yuan Ping Feng , Andrivo Rusydi

Understanding the role of defects in oxide heterostructures is crucial for future materials control and functionalization. We hence study the impact of oxygen vacancies (OVs) at variable concentrations on orbital- and spin exchange in the…

Materials Science · Physics 2015-10-13 Malte Behrmann , Frank Lechermann

We fabricated ultrathin ferroelectric/correlated electron oxide heterostructures composed of the ferroelectric Pb(Zr0.2Ti0.8)O3 and the correlated electron oxide (CEO) La0.8Sr0.2MnO3 on SrTiO3 substrates by pulsed laser epitaxy. The hole…

Materials Science · Physics 2012-07-25 Lu Jiang , Woo Seok Choi , Hyoungjeen Jeen , Takeshi Egami , Ho Nyung Lee

Surface oxides are associated with two-level systems (TLSs) that degrade the performance of niobium-based superconducting quantum computing devices. To address this, we introduce a predictive framework for selecting metal capping layers…

Electric-field effect control of two-dimensional electron gases (2-DEG) has enabled the exploration of nanoscale electron quantum transport in semiconductors. Beyond these classical materials, transition metal-oxide-based structures have…

Mesoscale and Nanoscale Physics · Physics 2019-03-29 A. Jouan , G. Singh , E. Lesne , D. C. Vaz , M. Bibes , A. Barthélémy , C. Ulysse , D. Stornaiuolo , M. Salluzzo , S. Hurand , J. Lesueur , C. Feuillet-Palma , N. Bergeal

Surfaces are at the frontier of every known solid. They provide versatile supports for functional nanostructures and mediate essential physicochemical processes. Being intimately related with 2D materials, interfaces and atomically thin…

Oxide heterostructures have repeatedly been shown to display apical properties at the interfaces, some of which favorable to the formation of two-dimensional electron systems, as well as high transition temperature superconductivity. In…

Superconductivity · Physics 2022-12-21 Wai Hei Terence Tse , Carla Lupo , Evan Sheridan , Evgeny Plekhanov , Cedric Weber

With reduced dimensionality, it is often easier to modify the properties of ultra-thin films than their bulk counterparts. Strain engineering, usually achieved by choosing appropriate substrates, has been proven effective in controlling the…

Mesoscale and Nanoscale Physics · Physics 2017-10-31 S. Thomas , B. Kuiper , J. Hu , J. Smit , Z. Liao , Z. Zhong , G. Rijnders , A. Vailionis , R. Wu , G. Koster , J. Xia

Interfacial charge transfer (ICT) provides a powerful route to engineer electronic phases in correlated oxide heterostructures, yet predictive design principles remain elusive. Here, we systematically investigate superlattices composed of…

It was recently discovered that a conductive, metallic state is formed on the surface of some insulating oxides. Firstly observed on SrTiO$_3$(001), it was then found in other compounds as diverse as anatase TiO$_2$, KTaO$_3$, BaTiO$_3$,…

Strongly Correlated Electrons · Physics 2020-08-26 A. F. Santander-Syro , J. Dai , T. C. Rödel , E. Frantzeskakis , F. Fortuna , R. Weht , M. J. Rozenberg

Iron oxide nanoparticles have tremendous scientific and technological potential in a broad range of technologies, from energy applications to biomedicine. To improve their performance, single-crystalline and defect-free nanoparticles have…

Materials Science · Physics 2021-02-17 Aidin Lak , Sabrina Disch , Philipp Bender

Recent advances in creating complex oxide heterostructures, interfaces formed between two different transition metal oxides, have heralded a new era of materials and physics research, enabling a uniquely diverse set of coexisting physical…

Mesoscale and Nanoscale Physics · Physics 2014-07-07 Joseph A. Sulpizio , Shahal Ilani , Patrick Irvin , Jeremy Levy

Machine learning is changing how we design and interpret experiments in materials science. In this work, we show how unsupervised learning, combined with ab initio modeling, improves our understanding of structural metastability in…

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