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The usual classical behaviour of S = 3/2, B-site ordered double perovskites generally results in simple, commensurate magnetic ground states. In contrast, heat capacity and neutron powder diffraction measurements for the S = 3/2 systems…

Strongly Correlated Electrons · Physics 2015-06-11 A. A. Aczel , D. E. Bugaris , L. Li , J. -Q. Yan , C. de la Cruz , H. -C. zur Loye , S. E. Nagler

Effect of Co, Ru and Cu substitution at B and B' sites on the magnetic and transport properties of LaSrCoRuO$_6$ have been investigated. All the doped compositions crystallize in the monoclinic structure in the space group $P2_1/n$…

Strongly Correlated Electrons · Physics 2010-11-12 P. S. Ramu Murthy , K. R. Priolkar , P. A. Bhobe , A. Das , P. R. Sarode , A. K. Nigam

New double perovskites LaPbMSbO6, where M2+ = Mn2+, Co2+, and Ni2+, were synthesized as polycrystals by an aqueous synthetic route at temperatures below 1000 oC. All samples are monoclinic, space group P21/n, as obtained from Rietveld…

Materials Science · Physics 2013-03-11 D. G. Franco , R. E. Carbonio , G. Nieva

Combining experimental investigations and first-principles DFT calculations, we report physical and magnetic properties of Gd-substituted Y$_2$CoMnO$_6$ double perovskite, which are strongly influenced by antisite-disorder-driven spin…

Materials Science · Physics 2023-02-28 Anasua Khan , Sarita Rajput , M. Anas , V. K. Malik , T. Maitra , T. K Nath , A. Taraphder

Here, we report on the structural, electronic, and magnetic properties of a polycrystalline sample of the LaCaCoIrO$_6$ double-perovskite investigated by means of synchrotron x-ray powder diffraction, x-ray absorption spectroscopy, and…

Strongly Correlated Electrons · Physics 2023-10-03 L. Bufaiçal , L. S. I. Veiga , J. R. L. Mardegan , T. Pohlmann , S. Francoual , S. S. Dhesi , M. B. Fontes , E. M. Bittar

Several double perovskite materials of the form A_2BB'O_6 exhibit high ferromagnetic T_c, and significant low field magnetoresistance. They are also a candidate source of spin polarized electrons. The potential usefulness of these materials…

Strongly Correlated Electrons · Physics 2015-05-19 Viveka Nand Singh , Pinaki Majumdar

Materials with a 5d4 electronic configuration are generally considered to have a nonmagnetic ground state (J=0). Interestingly, Sr2YIrO6 (Ir5+ having 5d4 electronic configuration) was recently reported to exhibit long-range magnetic order…

The 3$d$-5$d$ based double perovskites are of current interest as they provide model system to study the interplay between electronic correlation ($U$) and spin-orbit coupling (SOC). Here we report detailed structural, magnetic and…

Strongly Correlated Electrons · Physics 2017-10-30 K C Kharkwal , A K Pramanik

Single phase polycrystalline sample of perovskite Sr2TiMnO6 (STMO) has been successfully synthesized via solid state reaction route. Its detailed structural and physical properties have been studied using x-ray diffraction, transmission…

Materials Science · Physics 2016-09-06 Shivani Sharma , R. Rawat , N. P. Lalla

In this work we report the synthesis and structural, electronic and magnetic properties of La1.5Ca0.5CoMnO6 double-perovskite. This is a re-entrant spin cluster material which exhibits a non-negligible negative exchange bias effect when it…

B-site ordered thin films of double perovskite Sr$_2$CoIrO$_6$ were epitaxially grown by a metal-organic aerosol deposition technique on various substrates, actuating different strain states. X-ray diffraction, transmission electron…

Strongly Correlated Electrons · Physics 2018-05-23 S. Esser , C. F. Chang , C. -Y. Kuo , S. Merten , V. Roddatis , T. D. Ha , A. Jesche , V. Moshnyaga , H. -J. Lin , A. Tanaka , C. T. Chen , L. H. Tjeng , P. Gegenwart

Here, we present a study of the influence of microstructure on the magnetic properties of polycrystalline samples of the La1.5Sr0.5CoMnO6 double perovskite, with primary attention to the spontaneous exchange bias effect, a fascinating…

We have performed a combined study of magnetization hysteresis loops and time dependence of the magnetization in a broad temperature range for the ferrimagnetic La2Ni(Ni1/3Sb2/3)O6 double perovskite. This material has a ferrimagnetic order…

Materials Science · Physics 2013-03-07 Diego G. Franco , Raul E. Carbonio , G. Nieva

Investigation of the oxygen-deficient 112-type ordered oxides of the type LnBaCoMnO5+\delta (Ln = Nd, Eu) evidences certain unusual magnetic behavior at low temperatures, compared to the LnBaCo2O5+\delta cobaltites. One observes that the…

Materials Science · Physics 2015-05-18 Asish K. Kundu , V. Pralong , B. Raveau , V. Caignaert

The perovskite solid solutions of the type La$_{2x}$Sr$_{2-2x}$Co$_{2x}$Ru$_{2-2x}$O$_{6}$ with 0.25 $\leq$ x $ \leq $ 0.75 have been investigated for their structural, magnetic and transport properties. All the compounds crystallize in…

Strongly Correlated Electrons · Physics 2015-05-20 P. S. R. Murthy , K. R. Priolkar , P. A. Bhobe , A. Das , P. R. Sarode , A. K. Nigam

We present results of a numerical mean field treatment of interacting spins and carriers in doped diluted magnetic semiconductors, which takes into account the positional disorder present in these alloy systems. Disorder is found to enhance…

Disordered Systems and Neural Networks · Physics 2009-10-31 Mona Berciu , R. N. Bhatt

We have studied Ir spin and orbital magnetic moments in the double perovskites La$_{2-x}$Sr$_x$CoIrO$_6$ by x-ray magnetic circular dichroism. In La$_2$CoIrO$_6$, Ir$^{4+}$ couples antiferromagnetically to the weak ferromagnetic moment of…

Strongly Correlated Electrons · Physics 2012-06-22 A. Kolchinskaya , P. Komissinskiy , M. Baghaie Yazdi , M. Vafaee , D. Mikhailova , N. Narayanan , H. Ehrenberg , F. Wilhelm , A. Rogalev , L. Alff

The high temperature ferromagnetism in Sr3YCo4O10+delta perovskite, whose origin has been the subject of a considerable debate, has been studied by neutron powder diffraction and synchrotron X-ray diffraction measurements. Oxygen vacancy…

We report the investigations of crystal structure, electrical resistivity, magnetization, specific heat, thermal conductivity, and thermoelectric power (TEP) on La0.7Sr0.3(Mn1-xRux)O3 (LSMRO) compounds with x = 0 to 0.90. From the analyses…

Strongly Correlated Electrons · Physics 2007-05-23 L. M. Wang. Jyh-Iuan Wu , Y. -K. Kuo

The functional characteristics of double perovskites with unique ferromagnetic-insulator ground state have been controversial due to the unavoidable presence of anti-site disorders (ASDs). Here, we aim to investigate the origin of magnetic…