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We report on TmMnO3 far infrared emissivity and reflectivity spectra from 1910 K to 4 K. At the highest temperature the number of infrared bands is lower than that predicted for centrosymmetric P63/mmc (D6h4) (Z=2) space group due high…

Inelastic neutron scattering is used to measure the temperature dependent phonon dispersion in Ca$_{2-x}$Sr$_{x}$RuO$_{4}$ ($x=0.4$, 0.6). The in-plane $\Sigma_{4}$ octahedral tilt mode softens significantly at the zone boundary of the high…

Strongly Correlated Electrons · Physics 2015-05-13 R. G. Moore , M. D. Lumsden , M. B. Stone , Jiandi Zhang , Y. Chen , J. W. Lynn , R. Jin , D. Mandrus , E. W. Plummer

We have carried out temperature-dependent inelastic neutron scattering measurements of YMnO3 over the temperature range 50 - 1303 K, covering both the antiferromagnetic to paramagnetic transition (70 K), as well as the ferroelectric to…

Cold neutron scattering experiments have been performed to explore the energy, temperature, and wave-vector dependence of the diffuse scattering and the transverse acoustic (TA) phonons in the relaxor PbMg(1/3)Nb(2/3)O3. We have observed a…

Materials Science · Physics 2009-11-10 H. Hiraka , S. -H. Lee , P. M. Gehring , Guangyong Xu , G. Shirane

The soft modes associated with continuous-order phase transitions are associated with strong anharmonicity. This leads to the overdamped limit where the phonon quasi-particle picture can breakdown. However, this limit is commonly restricted…

Materials Science · Physics 2023-10-10 Erik Fransson , Petter Rosander , Fredrik Eriksson , J. Magnus Rahm , Terumasa Tadano , Paul Erhart

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

Fe$_{1.057(7)}$Te undergoes a first-order tetragonal to monoclinc structural transition at T$_{S} \sim 70$ K, breaking the C$_{4}$ lattice symmetry and simultaneously breaking time reversal symmetry with bicollinear magnetic order. We…

Strongly Correlated Electrons · Physics 2024-11-28 K. Guratinder , E. Chan , E. E. Rodriguez , J. A. Rodriguez-Rivera , U. Stuhr , A. Stunault , R. Travers , M. A. Green , N. Qureshi , C. Stock

We report on the structural evolution, spin phonon interactions, and magnetoelastic effects in bulk LaFeO3 perovskite across its antiferromagnetic transition. We found that while the lattice constants exhibit slight deviations at the Neel…

We present a quantitative analysis of the phonon lineshapes obtained by neutron inelastic scattering methods in the relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN). Differences in the shapes and apparent positions of the transverse acoustic…

Materials Science · Physics 2009-11-07 S. Wakimoto , C. Stock , Z. -G. Ye , W. Chen , P. M. Gehring , G. Shirane

Using an {\it ab initio} approach, we report a phonon soft mode in the tetragonal structure described by the space group $I4_{1}22$ of the $1$ K $5d$ superconductor Cd$_2$Re$_2$O$_7$. It induces an orthorhombic distortion to a crystal…

Dielectric properties of BTZ-BCT ceramics were probed in the frequency range from 10 Hz to 100 THz in a broad temperature range (10-900 K). Polar soft phonon observed in infrared spectra softens with cooling, however below 500 K its…

Materials Science · Physics 2016-12-13 S. Kamba , E. Simon , V. Skoromets , V. Bovtun , M. Kempa , J. Pokorny , M. Savinov , J. Koruza , B. Malic

The relaxor ferroelectric PbMg1/Nb2/3O3 was investigated by means of broad-band dielectric and Fourier Transform Infrared (FTIR) transmission spectroscopy in the frequency range from 1 MHz to 15 THz at temperatures between 20 and 900 K…

Materials Science · Physics 2009-11-10 S. Kamba , M. Kempa , V. Bovtun , J. Petzelt , K. Brinkman , N. Setter

We use neutron scattering to study the spin and lattice structures of single crystal and powder samples of Na$_{1-\delta}$FeAs ($T_c = 23$ K). On cooling from room temperature, the system goes through a series of phase transitions: first…

Superconductivity · Physics 2009-07-10 Shiliang Li , Clarina de la Cruz , Q. Huang , G. F. Chen , T. -L. Xia , J. L. Lou , N. L. Wang , Pengcheng Dai

We report lattice dynamical measurements, made using neutron inelastic scattering methods, of the relaxor perovskite PbMg1/3Nb2/3O3 (PMN) at momentum transfers near the edge of the Brillouin zone. Unusual"columns" of phonon scattering that…

Materials Science · Physics 2015-05-13 I. P. Swainson , C. Stock , P. M. Gehring , Guangyong Xu , K. Hirota , Y. Qiu , H. Luo , X. Zhao , J. -F. Li , D. Viehland

Density-functional calculations are presented for high-pressure structural phases of S and Se. The structural phase diagrams, phonon spectra, electron-phonon coupling, and superconducting properties of the isovalent elements are compared.…

Condensed Matter · Physics 2009-10-31 Sven P. Rudin , Amy Y. Liu , J. K. Freericks , A. Quandt

The infrared reflectance of the transition metal chalcogenide 1T-TaS2 has been measured at temperatures from 30K to 360K over 30-45,000cm^-1 (4meV-5.5eV). The optical conductivity was obtained by Kramers-Kronig analysis. At 360K only modest…

Condensed Matter · Physics 2013-10-31 L. V. Gasparov , K. G. Brown , A. C. Wint , D. B. Tanner , H. Berger , R. Gaal , L. Forro , G. Margaritondo

Motivated by predictions of a substantial contribution of the "buckling" vibration of the CuO2 layers to d-wave superconductivity in the cuprates, we have performed an inelastic neutron scattering study of this phonon in an array of…

Strongly Correlated Electrons · Physics 2015-05-30 M. Raichle , D. Reznik , D. Lamago , R. Heid , Y. Li , M. Bakr , C. Ulrich , V. Hinkov , K. Hradil , C. T. Lin , B. Keimer

Temperature-dependent FAR-infrared reflectivity spectra of partially ordered magnetodielectric La2CoMnO6 is presented, from room temperature up to 675 K. A clear first-ordered structural phase transition (SPT) from a monoclinic structure…

Materials Science · Physics 2018-02-22 R. X. Silva , A. Nonato , R. L. Moreira , R. M. Almeida , C. W. A. Paschoal

We performed temperature- and doping-dependent high-resolution Raman spectroscopy experiments on YBa$_2$Cu$_3$O$_{7-\delta}$ to study $B$$_{\rm 1g}$ phonons. The temperature dependence of the real part of the phonon self-energy shows a…

PbTe crystals have a soft transverse optical phonon mode in the terahertz frequency range, which is known to efficiently decay into heat-carrying acoustic phonons, resulting in anomalously low thermal conductivity. Here, we studied this…

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