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We produce ultracold dense trapped samples of 87Rb133Cs molecules in their rovibrational ground state, with full nuclear hyperfine state control, by stimulated Raman adiabatic passage (STIRAP) with efficiencies of 90%. We observe the onset…

Using a non-selective broadband detection scheme we discovered an efficient mechanism of formation of ultracold Cs$_2$ molecules in deeply bound levels ($v=1-9$) of their electronic ground state X$^1 \Sigma_g^+$. They are formed by a…

The interplay of the relativistic and correlation effects in the permanent electric dipole moments (PDMs) of the X2{\Sigma}+ ({\nu} = 0) electronic ground states of the alkaline earth monoflourides (BeF, MgF, CaF, SrF and BaF) has been…

Atomic Physics · Physics 2016-04-20 V. S. Prasannaa , Sreerekha S , M. Abe , V. M. Bannur , B. P. Das

We experimentally show that an electric dipole moment of more than 1 Debye can be induced in the dysprosium (Dy) atom, in a long-lived state that is about 17513 cm$^{-1}$ above the ground state. This metastable state is part of a strongly…

Atomic Physics · Physics 2026-04-14 Johannes Seifert , Sid C. Wright , Boris G. Sartakov , Giacomo Valtolina , Gerard Meijer

This paper describes the results of the most recent measurement of the permanent electric dipole moment (EDM) of neutral $^{199}$Hg atoms. Fused silica vapor cells containing enriched $^{199}$Hg are arranged in a stack in a common magnetic…

Atomic Physics · Physics 2017-08-21 B. Graner , Y. Chen , E. G. Lindahl , B. R. Heckel

Ultracold dipolar molecules hold great promise for the creation of novel quantum states of matter, but the realization of long-lived molecular bulk samples with strong dipole-dipole interactions has remained elusive. Here, we realize a…

We propose a very sensitive method for measuring the electric dipole moment of the electron using polar molecules embedded in a cryogenic solid matrix of inert-gas atoms. The polar molecules can be oriented in the $\hat{\rm{z}}$ direction…

Atomic Physics · Physics 2018-01-29 A. C. Vutha , M. Horbatsch , E. A. Hessels

Quantum gases of doubly-polar molecules represent appealing frameworks for a variety of cross-disciplinary applications, encompassing quantum simulation and computation, controlled quantum chemistry and precision measurements. Through a…

We present results of the first experiment to probe for the electric dipole moment (EDM) of the electron using an $\Omega$-doublet state in a polar molecule. If the molecule is both massive and has a large molecular-fixed frame dipole…

Atomic Physics · Physics 2015-06-15 S. Eckel , P. Hamilton , E. Kirilov , H. W. Smith , D. DeMille

The rapid development of experimental techniques to produce ultracold alkali molecules opens the ways to manipulate them and to control their dynamics using external electric fields. A prerequisite quantity for such studies is the knowledge…

We report the results of a new experimental search for a permanent electric dipole moment of 199Hg utilizing a stack of four vapor cells. We find d(199Hg) = (0.49 \pm 1.29_stat \pm 0.76_syst) x 10^{-29} e cm, and interpret this as a new…

Atomic Physics · Physics 2009-03-11 W. C. Griffith , M. D. Swallows , T. H. Loftus , M. V. Romalis , B. R. Heckel , E. N. Fortson

The relativistic configuration interaction valence bond method has been used to calculate permanent and transition electric dipole moments of the KRb heteronuclear molecule as a function of internuclear separation. The permanent dipole…

Soft Condensed Matter · Physics 2009-11-10 S. Kotochigova , P. S. Julienne , E. Tiesinga

The dipolar collision between ultracold polar molecules is an important topic both by its own right from the fundamental point of view and for the successful exploration of many-body physics with strong and long-range dipolar interactions.…

We create fermionic dipolar $^{23}$Na$^6$Li molecules in their triplet ground state from an ultracold mixture of $^{23}$Na and $^6$Li. Using magneto-association across a narrow Feshbach resonance followed by a two-photon STIRAP transfer to…

We present the first high-resolution spectroscopic study of LiCs. LiCs is formed in a heat pipe oven and studied via laser-induced fluorescence Fourier-transform spectroscopy. By exciting molecules through the X$^1\Sigma^+$-B$^1\Pi$ and…

Atomic Physics · Physics 2007-05-23 Peter Staanum , Asen Pashov , Horst Knoeckel , Eberhard Tiemann

Electric dipole moments constitute a competitive method to search for new physics, being particularly sensitive to new CP-violating phases. Given the experimental and theoretical progress in this field and more generally in particle…

High Energy Physics - Phenomenology · Physics 2015-06-12 Martin Jung

Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well…

We propose a new method to produce an electric and magnetic dipolar gas of ultracold dysprosium atoms. The pair of nearly degenerate energy levels of opposite parity, at 17513.33 cm$^{-1}$ with electronic angular momentum $J=10$, and at…

Atomic Physics · Physics 2018-08-15 Maxence Lepers , Hui Li , Jean-François Wyart , Goulven Quéméner , Olivier Dulieu

Using resonance-enhanced two-photon ionization, we detect ultracold, ground-state RbCs molecules formed via photoassociation in a laser-cooled mixture of 85Rb and 133Cs atoms. We obtain extensive bound-bound excitation spectra of these…

Atomic Physics · Physics 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , Thomas Bergeman , David DeMille

The hyperfine coupling constants of the proton dripline odd-odd $^{40}$Sc nucleus were deduced from the hyperfine spectrum of the $3d4s\,^3\text{D}_2$\,$\leftrightarrow$\,$3d4p\,^3\text{F}^\circ_3$ transition in Sc II, measured by the…