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We present an analytical approach to the strong coupling regime of similarly and highly charged plates in the presence of counter-ions. The procedure is physically transparent and based on an exact expansion around the ground state formed…

Statistical Mechanics · Physics 2011-02-23 L. Samaj , E. Trizac

We are interested in rationalizing the phenomenon of like-charge attraction between charged bodies, such as a pair of colloids, in the strong coupling regime. The two colloids are modelled as uniformly charged parallel plates, neutralized…

Soft Condensed Matter · Physics 2025-01-13 L. Samaj , E. Trizac , M. Trulsson

We study equilibrium statistical mechanics of classical point counter-ions, formulated on 2D Euclidean space with logarithmic Coulomb interactions (infinite number of particles) or on the cylinder surface (finite particle numbers), in the…

Soft Condensed Matter · Physics 2011-03-08 L. Samaj , E. Trizac

Realistic charged macromolecules are characterized by discrete (rather than homogeneous) charge distributions. We investigate the effects of surface charge discretization on the counterion distribution at the level of mean-field theory…

Soft Condensed Matter · Physics 2007-05-23 Mark L. Henle , Christian D. Santangelo , Deena M. Patel , Philip A. Pincus

We report molecular dynamics simulation of the (overall neutral) system consisting of an immobile macroion surrounded by the electrolyte of multivalent counterions and monovalent coions. As expected theoretically, counterions adsorb on the…

Soft Condensed Matter · Physics 2009-11-07 Motohiko Tanaka , Alexander Grosberg

By molecular dynamics simulation, we study the charge inversion phenomenon of a rod macroion in the presence of polyelectrolyte counterions. We simulate electrophoresis of the macroion under an applied electric field. When both counterions…

Soft Condensed Matter · Physics 2015-06-24 Motohiko Tanaka

The phase behavior of charge-stabilized colloidal suspensions is modeled by a combination of response theory for electrostatic interparticle interactions and variational theory for free energies. Integrating out degrees of freedom of the…

Soft Condensed Matter · Physics 2009-11-11 Alan R. Denton

By a length scale analysis, we study the equilibrium interactions between two like-charge planes confining neutralising counter-ions. At large Coulombic couplings, approaching the two charged bodies leads to an unbinding of counter-ions, a…

Soft Condensed Matter · Physics 2012-10-23 E. Trizac , L. Samaj

The sliding motion of aqueous droplets on hydrohobic surfaces leads to charge separation at the trailing edge, with implications from triple-line friction to hydrovoltaic energy generation. Charges deposited on the solid surface have been…

Soft Condensed Matter · Physics 2025-09-12 Zouhir Benrahla , Tristan Saide , Louis Burnaz , Emilie Verneuil , Simon Gravelle , Jean Comtet

The electrostatic interaction between colloidal particles trapped at the interface between two immiscible electrolyte solutions is studied in the limit of small inter-particle distances. Within an appropriate model exact analytic…

Soft Condensed Matter · Physics 2014-05-07 Arghya Majee , Markus Bier , S. Dietrich

The physics of an electron solid, held on a cryogenic liquid surface by a pressing electric field, is examined in a low-density regime that has not been explored before. We consider the effect of the pressing field in distorting the surface…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Masudul Haque , Indranil Paul , Sergey Pankov

Effect of static charges on charge carrier transport in disordered organic materials is considered. Long range nature of Coulomb interaction requires to take into consideration a finite thickness of the transport layer. Presence of…

Disordered Systems and Neural Networks · Physics 2007-05-23 Sergey Novikov

Over the past few decades the experimental literature has consistently reported observations of attraction between like-charged colloidal particles and macromolecules in solution. Examples include nucleic acids and colloidal particles in…

Soft Condensed Matter · Physics 2020-04-22 Alzbeta Kubincova , Philippe H. Hunenberger , Madhavi Krishnan

We show that when particles are suspended in an electrolyte confined between corrugated charged surfaces, electrokinetic flows lead to a new set of phenomena such as particle separation, mixing for low-Reynolds micro- and nano-metric…

Soft Condensed Matter · Physics 2015-06-22 Paolo Malgaretti , Ignacio Pagonabarraga , J. Miguel Rubi

We consider an overall neutral system consisting of two similarly charged plates and their oppositely charged counterions and analyze the electrostatic interaction between the two surfaces beyond the mean-field Poisson-Boltzmann…

Soft Condensed Matter · Physics 2016-08-31 A. W. C. Lau , P. Pincus

The interaction between charged objects in solution is generally expected to recapitulate two central principles of electromagnetics: (i) like-charged objects repel, and (ii) they do so regardless of the sign of their electrical charge.…

Soft Condensed Matter · Physics 2022-12-27 Sida Wang , Rowan Walker-Gibbons , Bethany Watkins , Melissa Flynn , Madhavi Krishnan

A mobile Coulomb gas permeating a fixed background crystalline lattice of charged colloidal crystals is subject to an electrostatic-elastic coupling, which we study on the continuum level by introducing a minimal coupling between…

Soft Condensed Matter · Physics 2025-02-14 Hao Wu , Zhong-Can Ou-Yang , Rudolf Podgornik

We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

Soft Condensed Matter · Physics 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

Experiments with polymer latex solutions show the coexistence of order-disorder structures of macroions. Because of the large macroions' sizes, this order-disorder phase coexistence imply the existence of very long-range attractive and…

Soft Condensed Matter · Physics 2019-02-20 Alfredo González-Calderón , Enrique González-Tovar , Marcelo Lozada-Cassou

The properties of a system of charged particles on a 2D lattice, subject to an anisotropic Jahn-Teller-type interaction and 3D Coulomb repulsion are investigated. In the mean-field approximation without Coulomb interaction, the system…

Strongly Correlated Electrons · Physics 2008-11-19 T. Mertelj , V. V. Kabanov , D. Mihailovic