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A class of binary mixtures of Janus fluids formed by colloidal spheres with the hydrophobic hemispheres constrained to point either up or down are studied by means of Gibbs ensemble Monte Carlo simulations and simple analytical…

Soft Condensed Matter · Physics 2013-11-14 Riccardo Fantoni , Achille Giacometti , Miguel Ángel G. Maestre , Andrés Santos

We deeply investigate a simple model representative of the recently synthesized Janus particles, i.e. colloidal spherical particles whose surface is divided into two areas of different chemical composition. When the two surfaces are…

Soft Condensed Matter · Physics 2009-12-21 Francesco Sciortino , Achille Giacometti , Giorgio Pastore

We have recently investigated the phase behaviour of model colloidal dumbbells constituted by two identical tangent hard spheres, with the first one being surrounded by an attractive square-well interaction (Janus dumbbells, Muna\`o G et al…

Patchy colloidal model with three and four equivalent patches, confined in the attractive random porous media, undergo re-entrant gas-liquid phase separation with the possibility for the liquid phase density to approach zero. This unusual…

Soft Condensed Matter · Physics 2022-05-11 Taras Hvozd , Yurij V. Kalyuzhnyi , Vojko Vlachy , Peter T. Cummings

The equilibrium properties of a Janus fluid confined to a one-dimensional channel are exactly derived. The fluid is made of particles with two faces (active and passive), so that the pair interaction is that of hard spheres, except if the…

Statistical Mechanics · Physics 2020-07-01 M. A. G. Maestre , A. Santos

We study experimentally and numerically a (quasi) two dimensional colloidal suspension of self-propelled spherical particles. The particles are carbon-coated Janus particles, which are propelled due to diffusiophoresis in a near-critical…

Soft Condensed Matter · Physics 2013-06-10 Ivo Buttinoni , Julian Bialké , Felix Kümmel , Hartmut Löwen , Clemens Bechinger , Thomas Speck

Colloidal Janus spheres in water (one hemisphere attractive and the other repulsive) assemble into two-dimensional hexagonal crystals with orientational order controlled by anisotropic interactions. We exploit the decoupled translational…

Soft Condensed Matter · Physics 2014-06-11 Shan Jiang , Jing Yan , Jonathan K. Whitmer , Stephen M. Anthony , Erik Luijten , Steve Granick

We apply a simple statistical mechanics cluster approximation for studying clustering in the Kern and Frenkel model of Janus fluids. The approach is motivated by recent Monte Carlo simulations work on the same model revealing that the vapor…

Soft Condensed Matter · Physics 2011-03-14 Riccardo Fantoni , Achille Giacometti , Francesco Sciortino , Giorgio Pastore

A simple three-dimensional model of a fluid whose constituent particles interact via a short range attractive and long range repulsive potential is used to model the aggregation into large spherical-like clusters made up of hundreds of…

Soft Condensed Matter · Physics 2025-02-11 Antonio Díaz-Pozuelo , Diego González-Salgado , Enrique Lomba

We study the thermodynamic and structural properties of a simple, one-patch fluid model using the reference hypernetted-chain (RHNC) integral equation and specialized Monte Carlo simulations. In this model, the interacting particles are…

Soft Condensed Matter · Physics 2015-05-14 Achille Giacometti , Fred Lado , Julio Largo , Giorgio Pastore , Francesco Sciortino

Colloidal particles are not simple rigid particles, in general an isolated particle is a system with many degrees of freedom in its own right, e.g., the counterions around a charged colloidal particle.The behaviour of model colloidal…

Statistical Mechanics · Physics 2009-10-31 Richard P. Sear

We report theoretical and numerical evaluations of the phase diagram for patchy colloidal particles of new generation. We show that the reduction of the number of bonded nearest neighbours offers the possibility of generating liquid states…

Soft Condensed Matter · Physics 2009-11-11 Emanuela Bianchi , Julio Largo , Piero Tartaglia , Emanuela Zaccarelli , Francesco Sciortino

We use numerical simulations to understand how random deviations from the ideal spherical shape affect the ability of hard particles to form fcc crystalline structures. Using a system of hard spheres as a reference, we determine the…

Soft Condensed Matter · Physics 2010-12-23 William L. Miller , Angelo Cacciuto

Multicanonical ensemble sampling simulations have been performed to calculate the phase diagram of a Lennard-Jones fluid embedded in a fractal random matrix generated through diffusion limited cluster aggregation. The study of the system at…

Statistical Mechanics · Physics 2015-06-25 V. De Grandis , P. Gallo , M. Rovere

A system of identical particles interacting through an isotropic potential that allows for two preferred interparticle distances is numerically studied. When the parameters of the interaction potential are adequately chosen, the system…

Condensed Matter · Physics 2009-10-31 E. A. Jagla

Using mesoscopic numerical simulations and analytical theory we investigate the coarsening of the solvent structure around a colloidal particle emerging after a temperature quench of the colloid surface. Qualitative differences in the…

Soft Condensed Matter · Physics 2018-04-18 Sutapa Roy , S. Dietrich , Anna Maciolek

Open structures can display a number of unusual properties, including a negative Poisson's ratio, negative thermal expansion, and holographic elasticity, and have many interesting applications in engineering. However, it is a grand…

Soft Condensed Matter · Physics 2015-10-14 D. Zeb Rocklin , Xiaoming Mao

We study colloidal particle dynamics of a model glass system using confocal and fluorescence microscopy as the sample evolves from a hard-sphere glass to a liquid with attractive interparticle interactions. The transition from hard-sphere…

Soft Condensed Matter · Physics 2015-05-13 Andrzej Latka , Yilong Han , Ahmed M. Alsayed , Andrew B. Schofield , A. G. Yodh , Piotr Habdas

Using Aggregation-Volume-Bias Monte Carlo simulations along with Successive Umbrella Sampling and Histogram Re-weighting, we study the phase diagram of a system of dumbbells formed by two touching spheres having variable sizes, as well as…

Soft Condensed Matter · Physics 2016-12-20 Patrick O'Toole , Achille Giacometti , Toby Hudson

Active colloidal systems with non-equilibrium self-organization is a long-standing, challenging area in biology. To understand how hydrodynamic flow may be used to actively control self-assembly of Janus particles (JPs), we use a model…

Soft Condensed Matter · Physics 2022-08-09 Szu-Pei Fu , Rolf Ryham , Bryan Quaife , Y. -N. Young
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