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In the present paper, we report the details of the kinetic energy and angular distributions of the H^{-}, S^{-}/SH^{-} fragment ions produced due to dissociative electron attachment in H_{2}S molecules at resonances peaking at 2.2 eV, 5.2…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

In this paper, we discuss the dissociative electron attachment process in Methane. Kinetic energy and angular distributions of H^{-} and CH_{2}^{-} fragment anions across the broad resonance about 10 eV is reported. Angular distribution of…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

In this paper, we discuss the dissociative electron attachment process in Formic Acid and Propyl Amine. These are molecules containing more than one functional group and have low symmetry (Cs group). We measured the kinetic energy and…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

Complete dissociation dynamics of low energy electron attachment to ammonia molecule has been studied using velocity slice imaging (VSI) spectrometer. One low energy resonant peak around 5.5 eV and a broad resonance around 10.5 eV incident…

Atomic and Molecular Clusters · Physics 2019-09-11 Dipayan Chakraborty , Aranya Giri , Dhananjay Nandi

Using the velocity map imaging technique, we studied and characterized the process of Dissociative Electron Attachment (DEA) in polyatomic molecules like Water, Hydrogen Sulphide, Ammonia, Methane, Formic Acid and Propyl Amine. We present…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , V. S. Prabhudesai , E. Krishnakumar

Kinetic energy and angular distributions of O$^-$ ions formed by dissociative electron attachment to CO molecule have been studied for 9, 9.5, 10, 10.5, 11, 11.5 eV incident electron energies around the resonance using time sliced velocity…

Atomic and Molecular Clusters · Physics 2015-02-10 Pamir Nag , Dhananjay Nandi

Motivated by the huge need of data for non-equilibrium plasma modeling, a theoretical investigation of dissociative electron attachment to the NO molecule is performed. The calculations presented here are based on the…

Atomic Physics · Physics 2020-12-02 V. Laporta , I. F. Schneider , J. Tennyson

We present experimental results for dissociative electron attachment to acetylene near the 3 eV $^2\Pi_g$ resonance. In particular, we use an ion-momentum imaging technique to investigate the dissociation channel leading to C$_2$H$^-$…

Chemical Physics · Physics 2014-10-29 M. Fogle , D. J. Haxton , A. L. Landers , A. E. Orel , T. N. Rescigno

Complete dissociation dynamics of low-energy electron attachment to carbon disulfide have been studied using the velocity slice imaging (VSI) technique. The ion yields of S- and CS- fragment ions as the function of incident electron energy…

Atomic and Molecular Clusters · Physics 2022-09-28 Anirban Paul , Dhananjay Nandi

The fragmentation of 1-propanol resulting from dissociative electron attachment has been explored across an energy range of 3.5 to 16 eV. Four distinct ion species are identified: $\text{H}^{-}$, $\text{O}^{-}$, $\text{OH}^{-}$, and…

Atomic and Molecular Clusters · Physics 2026-02-06 Soumya Ghosh , Dipayan Chakraborty , Anirban Paul , Dhananjay Nandi

In the present study, dissociative electron attachment (DEA) measurements with gas phase HMX, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, $C_4H_8N_8O_8$, have been performed by means of a crossed electron-molecular beam experiment.…

Complete dissociation dynamics of low energy electron attachment to nitrogen dioxide around 8.5 eV resonance has been studied using a velocity map imaging (VMI) spectrometer. Besides the three prominent resonant peaks at around 1.4 eV, 3.1…

Atomic and Molecular Clusters · Physics 2023-04-25 Anirban Paul , Dipayan Biswas , Dhananjay Nandi

Dissociative electron attachment (DEA) to the HNC$_3$ is modeled theoretically using a first-principles approach. In HNC$_3$+$e^-$ collisions, there is a low-energy resonance, which has a repulsive character along the H+NC$_3$ coordinate…

Exploring the molecular fragmentation dynamics induced by low-energy electrons offers compelling insights into the complex interplay between the projectile and target. In this study, we investigate the phenomenon of dissociative electron…

Atomic and Molecular Clusters · Physics 2024-01-05 Anirban Paul , Ian Carmichael , Dhananjay Nandi , Sylwia Ptasinska , Dipayan Chakraborty

We present the results of calculations defining global, three-dimensional representations of the complex-valued potential-energy surfaces of the doublet B1, doublet A1, and doublet B2 metastable states of the water anion that underlie the…

Chemical Physics · Physics 2009-11-13 Daniel J. Haxton , C. W. McCurdy , T. N. Rescigno

Dissociative electron attachment, that is, the cleavage of chemical bonds induced by low-energy electrons, is difficult to model with standard quantum-chemical methods because the involved anions are not bound but subject to autodetachment.…

Chemical Physics · Physics 2022-10-03 Jerryman A. Gyamfi , Thomas -C. Jagau

The transfer of charges, including electrons and holes, is a key step in heterogeneous catalysis, taking part in the reduction and oxidation of adsorbate species on catalyst surfaces. In plasmonic catalysis, electrons can transfer from…

Materials Science · Physics 2024-08-13 Robin E. Moorby , Valentina Parravicini , Thomas-C. Jagau , Maristella Alessio

We report the results of a first-principles study of dissociative electron attachment to H2O. The cross sections are obtained from nuclear dynamics calculations carried out in full dimensionality within the local complex potential model by…

Chemical Physics · Physics 2007-10-10 Daniel J. Haxton , T. N. Rescigno , C. W. McCurdy

We report the detailed dynamics of the site selectivity observed in the dissociative electron attachment (DEA) process in ethanol based on the momentum images obtained using the velocity slice imaging technique. The H- dissociation channel…

Chemical Physics · Physics 2023-08-15 Sukanta Das , Suvasis Swain , Vaibhav S. Prabhudesai

We report the results of a joint experimental {and} theoretical study of dissociative electron attachment to formic acid (HCOOH) in the 6-9 eV region, where H$^-$ fragment ions are a dominant product. Breaking of the CH and OH bonds is…

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