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In this paper, we discuss the dissociative electron attachment process in Ammonia. Kinetic energy and angular distributions of H^{-} and NH_{2}^{-} fragment anions across the two well known resonances at 5.5 eV and 10.5 eV are reported. The…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

In this paper, we discuss the dissociative electron attachment process in Formic Acid and Propyl Amine. These are molecules containing more than one functional group and have low symmetry (Cs group). We measured the kinetic energy and…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

Dissociative electron attachment (DEA) to the HNC$_3$ is modeled theoretically using a first-principles approach. In HNC$_3$+$e^-$ collisions, there is a low-energy resonance, which has a repulsive character along the H+NC$_3$ coordinate…

Kinetic energy and angular distributions of O$^-$ ions formed by dissociative electron attachment to CO molecule have been studied for 9, 9.5, 10, 10.5, 11, 11.5 eV incident electron energies around the resonance using time sliced velocity…

Atomic and Molecular Clusters · Physics 2015-02-10 Pamir Nag , Dhananjay Nandi

In the present paper, we report the details of the kinetic energy and angular distributions of the H^{-}, S^{-}/SH^{-} fragment ions produced due to dissociative electron attachment in H_{2}S molecules at resonances peaking at 2.2 eV, 5.2…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

Dissociative electron attachment (DEA) shows functional group-dependent site selectivity in the $H^-$ ion channel. In this context, the thiol functional group has yet to be studied in great detail, although this functional group carries…

Chemical Physics · Physics 2024-04-17 Sukanta Das , Vaibhav S. Prabhudesai

Dissociative electron attachment (DEA) is one of the processes that shows a strong coupling between the nuclear and electronic degrees of freedom in a molecule. This coupling results in an efficient transformation of the kinetic energy of…

Chemical Physics · Physics 2024-04-17 Suvasis Swain , Akshay Kumar , E. Krishnakumar , Vaibhav S. Prabhudesai

In the present study, dissociative electron attachment (DEA) measurements with gas phase HMX, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, $C_4H_8N_8O_8$, have been performed by means of a crossed electron-molecular beam experiment.…

In this paper, we discuss the dissociative electron attachment process in Methane. Kinetic energy and angular distributions of H^{-} and CH_{2}^{-} fragment anions across the broad resonance about 10 eV is reported. Angular distribution of…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

Momentum imaging measurements from two experiments are presented and interpreted with the aid of new ab initio theoretical calculations to describe the dissociative electron attachment (DEA) dynamics. We address the problem of how the 4 eV…

We present a kinematically complete study of dissociative electron attachment (DEA) in linear OCS molecules, focusing on how electrons resonantly attach and trigger dissociation. Near the Franck-Condon regime, DEA is dominated by molecular…

Atomic and Molecular Clusters · Physics 2025-05-02 Narayan Kundu , Meenakshi Rana , Aryya Ghosh , Dhananjay Nandi

We present the results of calculations defining global, three-dimensional representations of the complex-valued potential-energy surfaces of the doublet B1, doublet A1, and doublet B2 metastable states of the water anion that underlie the…

Chemical Physics · Physics 2009-11-13 Daniel J. Haxton , C. W. McCurdy , T. N. Rescigno

We report the results of a first-principles study of dissociative electron attachment to H2O. The cross sections are obtained from nuclear dynamics calculations carried out in full dimensionality within the local complex potential model by…

Chemical Physics · Physics 2007-10-10 Daniel J. Haxton , T. N. Rescigno , C. W. McCurdy

We report the detailed dynamics of the site selectivity observed in the dissociative electron attachment (DEA) process in ethanol based on the momentum images obtained using the velocity slice imaging technique. The H- dissociation channel…

Chemical Physics · Physics 2023-08-15 Sukanta Das , Suvasis Swain , Vaibhav S. Prabhudesai

An observed broad resonance peak in dissociative electron attachment (DEA) cross sections to a molecule might be due to either closely lying or overlapping resonances involved in the process. We developed a state-of-the-art experimental…

Chemical Physics · Physics 2015-06-09 Pamir Nag , Dhananjay Nandi

Complete dissociation dynamics of low energy electron attachment to ammonia molecule has been studied using velocity slice imaging (VSI) spectrometer. One low energy resonant peak around 5.5 eV and a broad resonance around 10.5 eV incident…

Atomic and Molecular Clusters · Physics 2019-09-11 Dipayan Chakraborty , Aranya Giri , Dhananjay Nandi

In this article, density functional theory (DFT) and natural bond orbital (NBO) calculations are performed to understand experimental observations of dissociative electron attachment (DEA) to SO$_2$. The molecular structure, fundamental…

Atomic and Molecular Clusters · Physics 2018-07-09 Irina Jana , Sumit Naskar , Mousumi Das , Dhananjay Nandi

Dissociative electron attachment (DEA) to gas-phase carbonyl sulfide (OCS) has been studied diligently using the time-of-flight (TOF) based state-of-the-art velocity map imaging (VMI) technique. Three well-resolved DEA resonances are…

Atomic Physics · Physics 2022-02-24 Narayan Kundu , Vikrant Kumar , Tejas Jani , Minaxi Vinodkumar , Dhananjay Nandi

Motivated by the huge need of data for non-equilibrium plasma modeling, a theoretical investigation of dissociative electron attachment to the NO molecule is performed. The calculations presented here are based on the…

Atomic Physics · Physics 2020-12-02 V. Laporta , I. F. Schneider , J. Tennyson

The fragmentation of 1-propanol resulting from dissociative electron attachment has been explored across an energy range of 3.5 to 16 eV. Four distinct ion species are identified: $\text{H}^{-}$, $\text{O}^{-}$, $\text{OH}^{-}$, and…

Atomic and Molecular Clusters · Physics 2026-02-06 Soumya Ghosh , Dipayan Chakraborty , Anirban Paul , Dhananjay Nandi
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