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We present a qualitative model for a fundamental process in molecular electronics: the change in conductance upon bond breaking. In our model a diatomic molecule is attached to spin-polarized contacts. Employing a Hubbard Hamiltonian,…

Materials Science · Physics 2008-06-24 Ali Goker , Francois Goyer , Matthias Ernzerhof

We theoretically analyzed inelastic effects in the electron transport through molecular junctions originating from electron-vibron interactions. The molecular bridge was simulated by a periodic chain of identical interacting hydrogen-like…

Materials Science · Physics 2010-01-03 Natalya A. Zimbovskaya , Maija M. Kuklja

As a step towards a more realistic modeling of vibrations in single-molecule devices, we investigate the effects of charge-dependent vibrational frequencies and anharmonic potentials on electronic transport. For weak phonon relaxation, we…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jens Koch , Felix von Oppen

Torque is ubiquitous in many molecular systems, including collisions, chemical reactions, vibrations, electronic excitations and especially rotor molecules. We present a straightforward theoretical method based on forces acting on atoms and…

Chemical Physics · Physics 2016-11-23 Rui-Qin Zhang , Yan-Ling Zhao , Fei Qi , Klaus Hermann , Michel A. Van Hove

We investigate the transient nonequilibrium dynamics of a molecular junction biased by a finite voltage and strongly coupled to internal vibrational degrees of freedom. Using two different, numerical exact techniques, diagrammatic Monte…

Mesoscale and Nanoscale Physics · Physics 2012-10-05 Klaus Ferdinand Albrecht , Haobin Wang , Lothar Muehlbacher , Michael Thoss , Andreas Komnik

The role of local electron-vibration and electron-electron interactions on the thermoelectric properties of molecular junctions is theoretically analyzed focusing on devices based on fullerene molecules. A self-consistent adiabatic approach…

Mesoscale and Nanoscale Physics · Physics 2019-08-08 C. A. Perroni , V. Cataudella

A new proposal is given to control local magnetic field in a molecular junction. In presence of finite bias a net circular current is established in the molecular ring which induces a magnetic field at its centre. Allowing a direct coupling…

Mesoscale and Nanoscale Physics · Physics 2017-03-07 Moumita Patra , Santanu K. Maiti

From first-principles approaches, we illustrate that the current-induced forces and the selection rule for inelastic effects are highly relevant to the current density in an asymmetric molecular junction. The curved flow of current…

Mesoscale and Nanoscale Physics · Physics 2011-06-10 Bailey C. Hsu , Allen Tseng , Yu-Chang Chen

We derive a model describing spatio-temporal organization of an array of microtubules interacting via molecular motors. Starting from a stochastic model of inelastic polar rods with a generic anisotropic interaction kernel we obtain a set…

Soft Condensed Matter · Physics 2007-05-23 Igor S. Aronson , Lev S. Tsimring

We calculate the zero temperature conductance and characteristic correlation functions of a molecule with a center of mass (CM) motion which modulates couplings to the leads. In the first model studied, the CM vibrational mode is…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 J. Mravlje , A. Ramsak , T. Rejec

Using first-principles calculations based on density functional theory combined with the non-equilibrium Green's function approach, the transport behaviors of a single-molecule junction formed by benzenedithiol connected to gold electrodes…

Materials Science · Physics 2022-09-20 Rigao Wang , Feng Shuang , Xiaowen Shi , Mingyan Chen

Here we present a theoretical analysis of inelastic effects on thermoelectric properties of molecular-scale junction in both linear and nonlinear response regimes. Considered device is composed of molecular quantum dot (with discrete energy…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Kamil Walczak

We theoretically analyze correlation effects on the transport properties of a benzene molecule that are mediated by interactions between the motion of the nuclei and the transmitted charge. We focus on the lowest-lying molecular vibrational…

Mesoscale and Nanoscale Physics · Physics 2013-08-09 Michael Knap , Enrico Arrigoni , Wolfgang von der Linden

Recent experiments have shown that transport properties of molecular-scale devices can be reversibly altered by the surrounding solvent. Here, we use a combination of first-principles calculations and experiment to explain this change in…

Mesoscale and Nanoscale Physics · Physics 2015-09-03 Michele Kotiuga , Pierre Darancet , Carlos R. Arroyo , Latha Venkataraman , Jeffrey B. Neaton

We provide analytical results for the perturbative correction to the current-voltage relation through a vibrating molecule for weak electron-phonon coupling. The nonlinear conductance exhibits a step-like feature at $eV=\hbar \omega_0$,…

Mesoscale and Nanoscale Physics · Physics 2008-03-14 R. Egger , A. O. Gogolin

We investigate the effect on molecular transport due to the different structural aspects of metal-molecule interfaces. The example system chosen is the prototypical molecular device formed by sandwiching the phenyl dithiolate molecule (PDT)…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark Ratner

The quantum master equation applied to electronic transport through nanoscopic devices provides information not only on the stationary state but also on the dynamics. The dynamics is characterized by the eigenvalues of the transition-rate…

Mesoscale and Nanoscale Physics · Physics 2012-11-01 Agnieszka Donabidowicz-Kolkowska , Carsten Timm

With the objective to understand microscopic principles governing thermal energy flow in nanojunctions, we study phononic heat transport through metal-molecule-metal junctions using classical molecular dynamics (MD) simulations. Considering…

Mesoscale and Nanoscale Physics · Physics 2022-11-23 Jonathan J. Wang , Jie Gong , Alan J. H. McGaughey , Dvira Segal

We study the statistical properties of charge and energy transport in electron conducting junctions with electron-phonon interactions, specifically, the thermoelectric efficiency and its fluctuations. The system comprises donor and acceptor…

Statistical Mechanics · Physics 2016-01-20 Bijay Kumar Agarwalla , Jian-Hua Jiang , Dvira Segal

An analog of the Meir-Wingreen formula for the steady-state heat current through a model molecular junction is derived. The expression relates the heat current to correlation functions that involve operators only acting on the degrees of…

Mesoscale and Nanoscale Physics · Physics 2010-08-26 Kirill A. Velizhanin , Michael Thoss , Haobin Wang