Related papers: Ortho-to-para ratio of interstellar heavy water
Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance distribution with other star-forming regions, and to constrain their HDO/H2O ratios. Methods.…
Accurate quantification of the column density of di-deuterated methanol is a key missing puzzle piece in the otherwise thoroughly constrained family of D-bearing methanol in the deeply embedded low-mass protostellar system and astrochemical…
Water is a key molecule in the star formation process, but its spatial distribution in star-forming regions is not well known. We study the distribution of dust continuum and H2O and 13CO line emission in DR21, a luminous star-forming…
We present Herschel/HIFI observations of 30 transitions of water isotopologues toward the high-mass star forming region NGC 6334 I. The line profiles of H_2^{16}O, H_2^{17}O, H_2^{18}O, and HDO show a complex pattern of emission and…
The spatial distribution of the chemical reservoirs in protoplanetary disks is key to elucidate the composition of planets, especially habitable ones. However, the partitioning of the main elements among the refractory and volatile phases…
Water and methanol are key components of interstellar ices and gas in star- and planet-forming regions, but direct observations of water in low-mass protostars are challenging due to atmospheric absorption. We present high-resolution (R =…
We report the first detection of the S(1) pure rotational line of ortho-H2 at 17.04 um in an asymptotic giant branch star, using observations of IRC+10216 with the Echelon-cross-echelle Spectrograph (EXES) mounted on the Stratospheric…
We report in this review recent fully-quantum time-independent calculations of cross sections and rate constants for the gas phase ortho-to-para conversion of H$_2$ by H and H$^+$. Such processes are of crucial interest and importance in…
Models of pure gas-phase chemistry in well-shielded regions of molecular clouds predict relatively high levels of molecular oxygen, O2, and water, H2O. Contrary to expectation, the space missions SWAS and Odin found only very small amounts…
We have used the Herschel-HIFI instrument to observe both nuclear spin symmetries of amidogen (NH2) towards the high-mass star-forming regions W31C (G10.6-0.4), W49N (G43.2-0.1), W51 (G49.5-0.4) and G34.3+0.1. The aim is to investigate the…
[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…
The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We…
Studies of the abundances of deuterium in different astrophysical sites are of fundamental importance to answering the question about how much deuterium was produced during big bang nucleosynthesis and what fraction of it was destroyed…
Water is a sensitive tracer of physical conditions in star-forming regions because of its large abundance variations between hot and cold regions. We use spectrally resolved observations of rotational lines of H$_2$O and its isotopologs…
Context. IRAS 16293E is a rare case of a prestellar core being subjected to the effects of at least one outflow.Aims. We want to disentangle the actual structure of the core from the outflow impact and evaluate the evolutionary stage of the…
We identify a prominent absorption feature at 1115 GHz, detected in first HIFI spectra towards high-mass star-forming regions, and interpret its astrophysical origin. The characteristic hyperfine pattern of the H2O+ ground-state rotational…
Water is detected in environments representing every stage of star and solar system formation, but its chemical evolution throughout these stages remains poorly constrained. Deuterium ratios offer a means of probing chemical links between…
Because the ionization balances for HI, OI, and DI are locked together by charge exchange, D/O is an important tracer for the value of the D/H ratio and for potential spatial variations in the ratio. As the DI and OI column densities are of…
We have detected the S(1), S(2), S(3), S(4) and S(5) pure rotational lines of molecular hydrogen toward the outflow source HH 54, using the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO). The observed H2…
(Abridged) We use HIFI maps of the 987 GHz H2O 2(02)-1(11) emission to measure the sizes and shapes of 19 high-mass protostellar envelopes. To identify infall, we use HIFI spectra of the optically thin C18O 9-8 and H2O-18 1(11)-0(00) lines.…