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Cupric oxide is a unique magnetic ferroelectric material with a transition temperature significantly higher than the boiling point of liquid nitrogen. However, the mechanism of high-T$_c$ multiferroicity in CuO remains puzzling. In this…

Materials Science · Physics 2015-06-03 Guangxi Jin , Kun Cao , Guang-Can Guo , Lixin He

We have studied the high temperature multiferroic cupric oxide using polarized neutron diffraction as a function of temperature and applied electric field. We find that the chiral domain population can be varied using an external electric…

Strongly Correlated Electrons · Physics 2012-08-08 P. Babkevich , A. Poole , R. D. Johnson , B. Roessli , D. Prabhakaran , A. T. Boothroyd

Motivated by the discovery of multiferroicity in the geometrically frustrated triangular antiferromagnet CuCrO$_2$ below its N\'eel temperature $T_N$, we investigate its magnetic and ferroelectric properties using ab initio calculations and…

Materials Science · Physics 2017-10-23 Ahmed Albaalbaky , Yaroslav Kvashnin , Denis Ledue , Renaud Patte , Raymond Frésard

The magnetic phase transitions reported below 230 K in cupric oxide are analyzed theoretically at the macroscopic and microscopic levels. The incommensurate multiferroic and lock-in commensurate phases are shown to realize an inverted…

We uncover a new pathway towards multiferroicity, showing how magnetism can drive ferroelectricity without relying on inversion symmetry breaking of the magnetic ordering. Our free-energy analysis demonstrates that any commensurate…

Materials Science · Physics 2009-11-11 Joseph J. Betouras , Gianluca Giovannetti , Jeroen van den Brink

"Magnetic ferroelectric" has been found in a wide range of spiral magnets. However, these materials all suffer from low critical temperatures, which are usually below 40 K, due to strong spin frustration. Recently, CuO has been found to be…

Materials Science · Physics 2012-05-08 Guangxi Jin , Kun Cao , Guang-Can Guo , Lixin He

Magnetic, dielectric, and magnetoelectric properties in a spin-state transition system are examined, motivated by the recent discovery of a multiferroic behavior in a cobalt oxide. We construct an effective model Hamiltonian based on the…

Strongly Correlated Electrons · Physics 2018-06-13 Makoto Naka , Eriko Mizoguchi , Joji Nasu , Sumio Ishihara

A systematic microscopic theory of magnetically induced ferroelectricity and lattice modulation is presented for all electron configurations of Mott-insulating transition-metal oxides. Various mechanisms of polarization are identified in…

Strongly Correlated Electrons · Physics 2009-11-13 Chenglong Jia , Shigeki Onoda , Naoto Nagaosa , Jung Hoon Han

The magnetic polarization induced by nonmagnetic impurities such as Zn in high Tc cuprate compounds is studied by the variational Monte Carlo simulation. The variational wave function is constructed from the eigenstates obtained from…

Strongly Correlated Electrons · Physics 2009-11-07 Shi-Dong Liang , T. K. Lee

Within the broad class of multiferroics (compounds showing a coexistence of magnetism and ferroelectricity), we focus on the subclass of "improper electronic ferroelectrics", i.e. correlated materials where electronic degrees of freedom…

Materials Science · Physics 2012-07-26 Silvia Picozzi , Alessandro Stroppa

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

We report multiferroic behavior in double perovskite Y2CoMnO6 with ferroelectric transition temperature Tc = 80K. The origin of ferroelectricity is associated with magnetic ordering of Co2+ and Mn4+ moments in a up-up-down-down arrangement.…

Materials Science · Physics 2015-06-15 G. Sharma , J. Saha , S. Patnaik

Magnetoelectric properties were investigated for an S=1/2 chain antiferromagnet CuCl2, which turns out to be the first example of non-chalcogen based spiral-spin induced multiferroics. Upon the onset of helimagnetic order propagating along…

Strongly Correlated Electrons · Physics 2010-09-01 S. Seki , T. Kurumaji , S. Ishiwata , H. Matsui , H. Murakawa , Y. Tokunaga , Y. Kaneko , T. Hasegawa , Y. Tokura

Multiferroic materials, in which ferroelectric and magnetic ordering coexist, are of fundamental interest for the development of multi-state memory devices that allow for electrical writing and non-destructive magnetic read-out operation.…

Materials Science · Physics 2013-09-03 Xavier Rocquefelte , Karlheinz Schwarz , Peter Blaha , Sanjeev Kumar , Jeroen van den Brink

Magnetic and/or dielectric behaviors have been studied for YBaCuFeO5, LuBaCuFeO5 and TmBaCuFeO5, which are known as members of oxygen-defect ordered perovskite systems RBaCuFeO5 (R=lanthanides Ln and other trivalent elements) and have two…

Strongly Correlated Electrons · Physics 2010-09-21 Yuji Kawamura , Takahiro Kai , Erika Satomi , Yukio Yasui , Yoshiaki Kobayashi , Masatoshi Sato

From magnetic susceptibility, dielectric permittivity, electric polarization and specific heat measurements, we discover spin-induced ferroelectricity and magnetoelectric coupling in Mn3TeO6 and observe two successive magnetic transitions…

Materials Science · Physics 2015-12-01 L. Zhao , Z. Hu , C. Y. Kuo , T. -W. Pi , M. -K. Wu , L. H. Tjeng , A. C. Komarek

Magnetoelectric multiferroics are highly sought after for applications in low-power electronics and for advancing fundamental research, including axion insulators and dark matter detection. However, achieving a combination of ferroic spin…

Materials Science · Physics 2024-12-02 Libor Šmejkal

Perovskite manganites with small A-site ions, as the first and canonical branch of type-II multiferroics, are ideal systems to exhibit magnetism-induced ferroelectricity. Despite their established magnetoelectric phase diagrams under low…

Materials Science · Physics 2026-01-15 Ming Yang , Jun Chen , Junfeng Wang , Chao Dong , Chengliang Lu , Gang Xu , Jinguang Cheng , Jianshi Zhou , Shuai Dong

We present a strategy to design structures for which a polar lattice distortion induces weak ferromagnetism. We identify a large class of multiferroic oxides as potential realizations and use density-functional theory to screen several…

Materials Science · Physics 2013-05-29 Craig J. Fennie

Magnetoelectric mutual control in multiferroics, which is the electric control of magnetization, or reciprocally the magnetic control of polarization has attracted much attention because of its possible applications to spintronic devices,…

Materials Science · Physics 2024-05-10 Shimon Tajima , Hidetoshi Masuda , Yoichi Nii , Shojiro Kimura , Yoshinori Onose
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