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By means of multicanonical computer simulations, we investigate thermodynamic properties of the aggregation of interacting semiflexible polymers. We analyze a mesoscopic bead-stick model, where nonbonded monomers interact via Lennard-Jones…

Soft Condensed Matter · Physics 2015-05-28 Christoph Junghans , Michael Bachmann , Wolfhard Janke

Engineering technologies frequently draw inspiration from nature, as exemplified in bio-inspired adhesive surfaces. These surfaces present textures adorned by pillars, mimicking the topography found on the pads of certain animals renowned…

Soft Condensed Matter · Physics 2024-11-14 Guido Violano , Savino Dibitonto , Luciano Afferrante

We present results from molecular dynamics simulations of a spherically confined neutral polymer in the presence of crowding agents, studying polymer shapes and conformations as a function of the confining potential, solvent quality and the…

Soft Condensed Matter · Physics 2020-01-29 Kamal Tripathi , Gautam I. Menon , Satyavani Vemparala

We study absorbing phase transitions in the one-dimensional branching annihilating random walk with long-range repulsion. The repulsion is implemented as hopping bias in such a way that a particle is more likely to hop away from its closest…

Statistical Mechanics · Physics 2023-07-26 Su-Chan Park

We conjecture the exact scaling theory for the adsorption of two-dimensional polymers by using boundary S matrices. We compute the boundary free energy (the ``g-function''), study the flow from adsorbed to desorbed phase, and derive the…

Condensed Matter · Physics 2009-10-22 P. Fendley , H. Saleur

The stability of a $\beta$-sheeted conformation and its transition into a random coil are studied with a 2D lattice biopolymer model. At low temperature and low external force, the polymer folds back and forth on itself and forms a…

Soft Condensed Matter · Physics 2007-05-23 Haijun Zhou

Plasma treatment of polymer films results in their electrical charging, which in turn gives rise to an increase in their surface energy. The process results in pronounced hydrophilization of the polymer surfaces. A phenomenological theory…

In this article we study from a non-perturbative point of view the entanglement of two directed polymers subjected to repulsive interactions given by a Dirac $\delta-$function potential. An exact formula of the so-called second moment of…

Soft Condensed Matter · Physics 2009-11-10 Franco Ferrari , Vakhtang G. Rostiashvili , Thomas A. Vilgis

Adsorption of a symmetric (AB) random copolymer (RC) onto a symmetric (ab) random heterogeneous surface (RS) is studied in the annealed approximation by using a two-dimensional partially directed walk model of the polymer. We show that in…

Soft Condensed Matter · Physics 2015-06-15 A. A. Polotsky

In this paper we consider a model which describes a polymer chain interacting with an infinity of equi-spaced linear interfaces. The distance between two consecutive interfaces is denoted by T = T_N and is allowed to grow with the size N of…

Probability · Mathematics 2009-01-20 Francesco Caravenna , Nicolas Pétrélis

Polymer chains decorated with a fraction of monomers capable of forming reversible bonds form transient polymer networks that are important in soft and biological systems. If chains are flexible and the attractive monomers are all of the…

Soft Condensed Matter · Physics 2023-10-18 Lorenzo Rovigatti , Francesco Sciortino

We study the long-range directed polymer model on $\mathbbm{Z}$ in a random environment, where the underlying random walk lies in the domain of attraction of an $\alpha$-stable process for some $\alpha\in(0,2]$. Similar to the more classic…

Probability · Mathematics 2016-11-24 Ran Wei

Using Langevin dynamics complemented by Wang-Landau Monte Carlo simulations, we study the phase behavior of single and multiple semiflexible polymer chains in solution under poor-solvent conditions. In the case of a single chain, we obtain…

We present the results of analytic calculations and numerical simulations of the behaviour of a new class of chain molecules which we call thick polymers. The concept of the thickness of such a polymer, viewed as a tube, is encapsulated by…

Soft Condensed Matter · Physics 2015-06-25 D. Marenduzzo , A. Flammini , A. Trovato , J. R. Banavar , A. Maritan

Through extensive Monte Carlo simulations, we systematically study the effect of chain stiffness on the packing ability of linear polymers composed of hard spheres in extremely confined monolayers, corresponding effectively to 2D films.…

We analyze here a model for an adsorbate system composed of many layers by extending a theoretical approach used to describe pattern formation on a monolayer of adsorbates with lateral interactions. The approach shows, in addition to a…

Statistical Mechanics · Physics 2009-11-07 S. B. Casal , Horacio S. Wio , S. Mangioni

The disjoining pressure isotherm in foam films is theoretically studied and an important contribution of adsorption is discovered. On the basis of the interfacial thermodynamics an adsorption disjoining pressure component is derived, which…

Mesoscale and Nanoscale Physics · Physics 2012-01-19 R. Tsekov

Motivated by a recent adsorption experiment [M.O. Blunt et al., Science 322, 1077 (2008)], we study tilings of the plane with three different types of rhombi. An interaction disfavors pairs of adjacent rhombi of the same type. This is shown…

Statistical Mechanics · Physics 2013-05-29 Jesper Lykke Jacobsen , Fabien Alet

Entangled polymers are deformed by a strong shear flow. The shape of the polymer, called the form factor, is measured by small angle neutron scattering. However, the real-space molecular structure is not directly available from the…

We study the thermodynamics of the one-dimensional extended Hubbard model at half-filling using a density-matrix renormalization group method applied to transfer matrices. We show that the various phase transitions in this system can be…

Strongly Correlated Electrons · Physics 2007-11-04 S. Glocke , A. Klümper , J. Sirker