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Graphene, a 2-dimensional monolayer form of sp2 hybridizated carbon atoms, is attracting increasing attention due to its unique and superior physicochemical properties. Covalently functionalized graphene layers, with their modifiable…

Materials Science · Physics 2014-08-11 Karolina Z. Milowska , Jacek A. Majewski

\textit{Ab initio} calculations within the density functional theory formalism are performed to investigate the stability and electronic properties of fluorinated bilayer graphene (bilayer fluorographene). A comparison is made to previously…

Materials Science · Physics 2013-01-25 Jozef Sivek , Ortwin Leenaerts , Bart Partoens , Francois Peeters

The electronic and magnetic properties of varying width, oxygen-functionalized armchair graphene nanoribbons (AGNRs) are investigated using first-principles density functional theory (DFT). Our study shows that O-passivation results in a…

The feature-rich electronic and magnetic properties of fluorine-doped graphene nanoribbons are investigated by the first-principles calculations. They arise from the cooperative or competitive relations among the significant chemical bonds,…

Mesoscale and Nanoscale Physics · Physics 2017-03-01 Duy Khanh Nguyen , Yu-Tsung Lin , Shih-Yang Lin , Yu-Huang Chiu , Ngoc Thanh Thuy Tran , Ming Fa-Lin

DFT calculations of the electronic structure of graphane and stoichiometrically halogenated graphene derivatives (fluorographene and other analogous graphene halides) show (i) localized orbital basis sets can be successfully and effectively…

Materials Science · Physics 2012-09-20 František Karlický , Radek Zbořil , Michal Otyepka

Motivated by the state of the art method for fabricating high density periodic nanoscale defects in graphene, the structural, mechanical and electronic properties of defect-patterned graphene nanomeshes including diverse morphologies of…

Mesoscale and Nanoscale Physics · Physics 2011-06-22 Hasan Sahin , Salim Ciraci

We show that, in graphene with a small concentration of adatoms, the total magnetic moment $\mu_T$ can be switched on and off by varying the Fermi energy $E_F$, either by applying a gate voltage or by suitable chemical doping. Our…

Mesoscale and Nanoscale Physics · Physics 2014-08-08 N. A. Pike , D. Stroud

A novel nanoelectronic device is constructed by graphyne that is robustly connected between graphene electrodes, where graphyne is composed of hexagonal carbon rings and carbon chains. Owing to similarities between the bond lengths and unit…

Mesoscale and Nanoscale Physics · Physics 2013-07-17 Young I. Jhon , Myung S. Jhon

The rapid technological progress in the 21st century demands new multi-functional materials applicable to a wide variety of industries. Two-dimensional (2D) materials are predicted to have a revolutionary impact on the cost, size, weight,…

Applied Physics · Physics 2019-05-17 Samira Naghdi , Gonzalo Sanchez-Arriaga , Kyong Yop Rhee

The paper presents a computational study of the ground-state magnetic phases of a selected bilayer graphene nanoflake in external electric field and magnetic field. The electric field has parallel and perpendicular component while the…

Materials Science · Physics 2017-05-02 Karol Szałowski

It is shown, by DFT calculations, that the uniform functionalization of upper layer of graphite by hydrogen or fluorine does not change essentially its bonding energy with the underlying layers, whereas the functionalization by phenyl…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 D. W. Boukhvalov , M. I. Katsnelson

Recent studies on graphene hydrogenation processes showed that hydrogenation occurs via island growing domains, however how the substrate can affect the hydrogenation dynamics and/or pattern formation has not been yet properly investigated.…

Graphene nanoflakes are interesting because electrons are naturally confined in these quasi-zero-dimensional structures, whereas confinement in bulk graphene would require a band gap. Vacancies inside the graphene lattice lead to localized…

Mesoscale and Nanoscale Physics · Physics 2015-04-06 Matthias Droth , Guido Burkard

Ab initio calculations within the density-functional theory formalism are performed to investigate the chemical functionalization of a graphene-like monolayer of silicon - silicene - with B, N, Al or P atoms. The structural, electronic,…

Materials Science · Physics 2014-09-05 Jozef Sivek , Hasan Şahin , Bart Partoens , François M. Peeters

We theoretically design a graphene-based all-organic ferromagnetic semiconductor by terminating zigzag graphene nanoribbons (ZGNRs) with organic magnets. A large spin-split gap with 100% spin polarized density of states near the Fermi…

Materials Science · Physics 2017-09-13 D. Hou , J. H. Wei , S. J. Xie

It is generally believed that free-standing graphene does not demonstrate any ferroic properties. In the present work we revise this statement and show that single graphene sheet with a pair of magnetic adatoms can be driven into…

Strongly Correlated Electrons · Physics 2016-11-15 Y. Marques , L. S. Ricco , F. A. Dessotti , R. S. Machado , I. A. Shelykh , M. de Souza , A. C. Seridonio

Experimental and theoretical results on chemical functionalization of graphene are reviewed. Using hydrogenated graphene as a model system, general principles of the chemical functionalization are formulated and discussed. It is shown that,…

Materials Science · Physics 2009-01-05 D. W. Boukhvalov , M. I. Katsnelson

The electronic structure of selected rare-earth atoms adsorbed on a free-standing graphene was investigated using methods beyond the conventional density functional theory (DFT+U, DFT+HIA and DFT+ED). The influence of the electron…

Strongly Correlated Electrons · Physics 2016-09-12 Agnieszka L. Kozub , Alexander B. Shick , Frantisek Maca , Jindrich Kolorenc , Alexander I. Lichtenstein

Using the density-functional-based tight-binding method we performed a systematic comparative study of stability, structural and electronic properties for 12 various types of graphene allotropes, which are likely candidates for engineering…

Materials Science · Physics 2015-05-20 A. N. Enyashin , A. L. Ivanovskii

We describe a peculiar fine structure acquired by the in-plane optical phonon at the Gamma-point in graphene when it is brought into resonance with one of the inter-Landau-level transitions in this material. The effect is most pronounced…

Mesoscale and Nanoscale Physics · Physics 2009-09-24 M. O. Goerbig , J. -N. Fuchs , K. Kechedzhi , Vladimir I. Fal'ko