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Quantum theory of self-phase and cross-phase modulation of ultrashort light pulses in the Kerr medium is developed with taking into account the response time of an electronic nonlinearity. The correspondent algebra of time-dependent…

Quantum Physics · Physics 2007-05-23 F. Popescu , A. S. Chirkin

Efficient strategies that allow the preparation of molecular systems in particular vibrational states are important in the application of quantum control schemes to chemical reactions. In this paper, we propose the preparation of…

Chemical Physics · Physics 2022-07-11 Luis H. Delgado G , Carlos A. Arango , José G. López

We present a technique for engineering quantum magnets via ultracold polar molecules in optical lattices and explore exotic interplay between its spin superfluidity and solidity. The molecular ground and first excited rotational states are…

Quantum Gases · Physics 2009-10-27 Hongyi Yu , W. M. Liu , Chaohong Lee

A model based on the strong-field and Born-Oppenheimer approximations qualitatively describes the distribution over vibrational states formed in a diatomic molecular ion following ionization of the neutral molecule by intense laser pulses.…

Atomic Physics · Physics 2007-05-23 Thomas Kim Kjeldsen , Lars Bojer Madsen

Ultracold paramagnetic and polar diatomic molecules are among the promising systems for quantum simulation of lattice-spin models. Unfortunately, their experimental observation is still challenging. Based on our recent \textit{ab-initio}…

One of the primary challenges prohibiting demonstrations of practical quantum advantages for near-term devices amounts to excessive measurement overheads for estimating relevant physical quantities such as ground state energies. However,…

We investigate theoretically the ability of an optical centrifuge - a laser pulse whose linear polarization is rotating at an accelerated rate, to control molecular rotation in the regime when the rigid-rotor approximation breaks down due…

Quantum Physics · Physics 2025-12-11 J. M. García-Garrido , V. Milner , C. P. Koch , R. González-Férez

Ultrashort non-resonant electromagnetic pulses applied to effective one-electron systems may operate on the electronic state as a position or momentum translation operator. As derived here, extension to many-body correlated systems exposes…

Quantum Physics · Physics 2015-04-22 Y. Pavlyukh , J. Berakdar

The complexity of ultrafast molecular photoionization presents an obstacle to the modelling of pump-probe experiments. Here, a simple optimized model of atomic rubidium is combined with a molecular dynamics model to predict quantitatively…

Atomic Physics · Physics 2013-05-29 Hugo E. L. Martay , David J. McCabe , Duncan G. England , Ian A. Walmsley

We explore the uses of ultracold molecules as a platform for future experiments in the field of quantum simulation, focusing on two molecular species, $^{40}$Ca$^{19}$F and $^{87}$Rb$^{133}$Cs. We report the development of coherent quantum…

Hybrid ion-atom systems provide an excellent platform for studies of state-resolved quantum chemistry at low temperatures, where quantum effects may be prevalent. Here we study theoretically the process of vibrational relaxation of an…

Atomic Physics · Physics 2020-04-01 Krzysztof Jachymski , Florian Meinert

We observe "trilobite-like" states of ultracold 85Rb2 molecules, in which a ground-state atom is bound by the electronic wavefunction of its Rydberg-atom partner. We populate these states through the ultraviolet excitation of weakly-bound…

Atomic Physics · Physics 2015-06-15 M. A. Bellos , R. Carollo , J. Banerjee , E. E. Eyler , P. L. Gould , W. C. Stwalley

Molecular vibrational spectroscopy with the scanning tunneling microscope is feasible but usually detects few vibrational modes. We harness sharp Yu-Shiba-Rusinov (YSR) states observed from molecules on a superconductor to significantly…

Mesoscale and Nanoscale Physics · Physics 2022-09-21 Jan Homberg , Alexander Weismann , Troels Markussen , Richard Berndt

We perform one- and two-photon high resolution spectroscopy on ultracold samples of RbCs Feshbach molecules with the aim to identify a suitable route for efficient ground-state transfer in the quantum-gas regime to produce quantum gases of…

An optimal dynamical decoupling of a quantum system coupled to a noisy environment must take into account also the imperfections of the control pulses. We present a new formalism which describes, in a closed-form expression, the evolution…

Quantum Physics · Physics 2016-10-19 Ido Almog , Gil Loewenthal , Jonathan Coslovsky , Yoav Sagi , Nir Davidson

Vibrational degrees of freedom in trapped-ion systems have recently been gaining attention as a quantum resource, beyond the role as a mediator for entangling quantum operations on internal degrees of freedom, because of the large available…

Quantum Physics · Physics 2021-07-01 Wentao Chen , Jaren Gan , Jing-Ning Zhang , Dzmitry Matuskevich , Kihwan Kim

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

The extraordinary success in laser cooling, trapping, and coherent manipulation of atoms has energized the efforts in extending this exquisite control to molecules. Not only are molecules ubiquitous in nature, but the control of their…

Atomic Physics · Physics 2022-04-27 D. Mitra , K. H. Leung , T. Zelevinsky

We show that the precise preparation of a quantum superposition between three rotational states of an ultracold dipolar molecule generates controllable interferences in their two-body scattering dynamics and collisional rate coefficients,…

Quantum Gases · Physics 2024-06-21 Thibault Delarue , Goulven Quéméner

We examine dark quantum superposition states of weakly bound Rb2 Feshbach molecules and tightly bound triplet Rb2 molecules in the rovibrational ground state, created by subjecting a pure sample of Feshbach molecules in an optical lattice…