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We develop a statistical method to learn a molecular Hamiltonian matrix from a time-series of electron density matrices. We extend our previous method to larger molecular systems by incorporating physical properties to reduce…

Chemical Physics · Physics 2021-08-03 Prachi Gupta , Harish S. Bhat , Karnamohit Ranka , Christine M. Isborn

We study a quantum theory with complex time parameter and non-Hermitian Hamiltonian structure. In this theory, the real part of the complex time is equal to `usual' physical time, whereas the imaginary one is proportional to inverse…

High Energy Physics - Theory · Physics 2007-05-23 Vadim V. Asadov , Oleg V. Kechkin

Dynamical evolution of the quantum ground state (vacuum) is analyzed for time variant harmonic oscillators characterized by asymptotically constant frequency. The oscillatory density matrix in the asymptotic future is uniquely determined by…

High Energy Physics - Theory · Physics 2007-05-23 M. Yoshimura

The most widely used approach for simulating the dynamics of time-dependent Hamiltonians via quantum computation depends on the quantum-classical hybrid variational quantum time evolution algorithm, in which ordinary differential equations…

Quantum Physics · Physics 2026-03-19 Minchen Qiao , Zi-Ming Li , Yu-xi Liu

We investigate the energy transfer dynamics in a donor-acceptor model by developing a time-local master equation technique based on a variational transformation of the underlying Hamiltonian. The variational transformation allows a…

Quantum Physics · Physics 2011-09-19 Dara P. S. McCutcheon , Ahsan Nazir

The smallness of the variation rate of the hamiltonian matrix elements compared to the (square of the) energy spectrum gap is usually believed to be the key parameter for a quantum adiabatic evolution. However it is only perturbatively…

Quantum Physics · Physics 2007-05-23 Daniel Comparat

All elementary Hamiltonians in nature are expected to be invariant under rotation. Despite this restriction, we usually assume that any arbitrary measurement or unitary time evolution can be implemented on a physical system, an assumption…

Quantum Physics · Physics 2009-11-13 I. Marvian , R. B. Mann

Starting from a master equation in a quantum Hamilton form we study analytically a nonequilibrium system which is coupled locally to two heat bathes at different temperatures. Based on a lattice gas description an evolution equation for the…

Statistical Mechanics · Physics 2007-05-23 Steffen Trimper , Simone Artz

Hamiltonian mechanics describes the evolution of a system through its Hamiltonian. The Hamiltonian typically also represents the energy observable, a Noether-conserved quantity associated with the time-invariance of the law of evolution. In…

Quantum Physics · Physics 2024-03-29 Libo Jiang , Daniel R. Terno , Oscar Dahlsten

Hybrid quantum-classical algorithms are among the most promising systems to implement quantum computing under the Noisy-Intermediate Scale Quantum (NISQ) technology. In this paper, at first, we investigate a quantum dynamics algorithm for…

Quantum Physics · Physics 2020-08-13 Mahmoud Mahdian , H. Davoodi Yeganeh

A general formalism is developed for constructing modified Hamiltonian dynamical systems which preserve a canonical equilibrium distribution by adding a time evolution equation for a single additional thermostat variable. When such systems…

Statistical Mechanics · Physics 2015-12-09 John D. Ramshaw

We present a general framework for finding the time-optimal evolution and the optimal Hamiltonian for a quantum system with a given set of initial and final states. Our formulation is based on the variational principle and is analogous to…

Quantum Physics · Physics 2007-05-23 Alberto Carlini , Akio Hosoya , Tatsuhiko Koike , Yosuke Okudaira

We examine the time evolution of an asymmetric Hubbard dimer, which has a different on-site interaction on the two sites. The Hamiltonian has a time-dependent hopping term, which can be employed to describe an electric field (which creates…

Strongly Correlated Electrons · Physics 2016-10-11 Shankar Balasubramanian , J. K. Freericks

We discuss the notion of quantum mechanical coherence in its connection with time evolution and stationarity. The transition from coherence to decoherence is examined in terms of an equation for the time dependence of the density matrix. It…

Quantum Physics · Physics 2007-05-23 L. Stodolsky

We study the effects of inhomogeneities on the evolution of the Universe, by considering a range of cosmological models with discretized matter content. This is done using exact and fully relativistic methods that exploit the symmetries in…

General Relativity and Quantum Cosmology · Physics 2015-06-17 Timothy Clifton , Daniele Gregoris , Kjell Rosquist , Reza Tavakol

We discuss a few mathematical aspects of random dynamical decoupling, a key tool procedure in quantum information theory. In particular, we place it in the context of discrete stochastic processes, limit theorems and CPT semigroups on…

Quantum Physics · Physics 2015-06-19 Robin Hillier , Christian Arenz , Daniel Burgarth

We consider the interaction dynamics of a classical oscillator and a quantum two-level system for different pure-dephasing Hamiltonians of the type $\widehat{H}(q,p)=H_C(q,p)\boldsymbol{1}+H_I(q,p)\widehat\sigma_z$. This type of systems…

Chemical Physics · Physics 2023-03-15 Giovanni Manfredi , Antoine Rittaud , Cesare Tronci

A many particle Hamiltonian, where the interaction term conserves the number of particles, is considered. A master equation for the populations of the different levels is derived in an exact way. It results in a local equation with…

Quantum Physics · Physics 2015-06-26 Edgardo T. Garcia Alvarez , Fabian H. Gaioli

Effective Hamiltonians governing the time evolution in a subspace of unstable states can be found using more or less accurate approximations. A convenient tool for deriving them is the evolution equation for a subspace of state space…

Quantum Physics · Physics 2014-09-11 K. Urbanowski

Shortcuts to adiabaticity provide a general approach to mimic adiabatic quantum processes via arbitrarily fast evolutions in Hilbert space. For these counter-diabatic evolutions, higher speed comes at higher energy cost. Here, the…

Quantum Physics · Physics 2017-12-19 Alan C. Santos , Marcelo S. Sarandy