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The glass transition temperature $T_{\rm g}$ and the temperature $T_{\alpha}$ corresponding to the peak in the dielectric loss due to the $\alpha$-process have been simultaneously determined as functions of film thickness d through…

Soft Condensed Matter · Physics 2009-10-31 Koji Fukao , Yoshihisa Miyamoto

We discuss the first infrared reflectivity measurement on a BiFeO3 single crystal between 5 K and room temperature. The 9 predicted ab-plane E phonon modes are fully and unambiguously determined. The frequencies of the 4 A1 c-axis phonons…

Materials Science · Physics 2011-11-10 R. P. S. M. Lobo , R. L. Moreira , D. Lebeugle , D. Colson

It has been considered that polar nanoregions in relaxors form at Burns temperature Td approx 600 K. High-temperature dielectric investigations of Pb(Mg1/3Nb2/3)O3 (PMN) and 0.7PMN-0.3PbTiO3 reveal, however, that the dielectric dispersion…

Materials Science · Physics 2015-05-18 Vid Bobnar , Cene Filipic , Adrijan Levstik , Zdravko Kutnjak

Room-temperature optical constants of crystalline Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ were determined using data extracted from Brillouin light scattering spectra. Optical extinction coefficient-to-refractive index ratios at a wavelength of…

Superconductivity · Physics 2021-04-08 B. D. E. McNiven , J. P. F. LeBlanc , G. T. Andrews

Measurements of the polarization charge accumulated at the -z and the +z bases of the pyroelectric crystals of LiNbO3 and LiTaO3 during changes in temperature are described. An electrometer in the charge mode with its probe attached to the…

Atomic and Molecular Clusters · Physics 2007-05-23 James D. Brownridge , Sol Raboy

Materials with high dielectric constant are in great demand for the miniaturization of electronic devices. More specifically, high dielectric constant polymer-ceramic composites are useful for embedded capacitor applications. A composite…

Materials Science · Physics 2013-01-18 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

The 1kHz real part $\chi'$ of the dielectric constant of a structural glass was measured at low temperature $T$ down to 14 mK. Reducing the sample thickness $h$ to 10 nm suppresses the usual minimum of $\chi'$ for measuring fields $E<.5 $…

Condensed Matter · Physics 2009-11-07 F. Ladieu , J. Le Cochec , P. Pari , P. Trouslard , P. Ailloud

X-ray and neutron powder diffraction data as a function of temperature are analyzed for the colossal dielectric constant material CaCu3Ti4O12. The local structure is studied using atomic pair distribution function analysis. No evidence is…

Materials Science · Physics 2009-11-10 E. S. Bozin , V. Petkov , P. W. Barnes , P. M. Woodward , T. Vogt , S. D. Mahanti , S. J. L. Billinge

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

We report the adiabatic elastic constants of single-crystal thorium dioxide over a temperature range of 77 - 350 K. Time-domain Brillouin scattering (TDBS), an all-optical, non-contact picosecond ultrasonic technique, is used to generate…

Multiferroic (Bi1-xLaxFeO3)0.5(PbTiO3)0.5 ceramics was prepared from mechanical synthesized nanopowders. The XRD studies revealed the tetragonal structure and the tetragonality decreased with La content. Dielectric response of the compounds…

Materials Science · Physics 2013-12-16 E. Markiewicz , B. Andrzejewski , B. Hilczer , M. Balcerzak , A. Pietraszko , M. Jurczyk

Lattice constant of Bi$_2$Se$_3$ and Sb$_2$Te$_3$ crystals is determined by X-ray powder diffraction measurement in a wide temperature range. Linear thermal expansion coefficients ($\alpha$) of the crystals are extracted, and considerable…

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

The microwave, near-millimetre and infrared (IR) dielectric response of Srn+1TinO3n+1 (n=1-4) Ruddlesden-Popper homologous series was studied in the temperature range 10 to 300 K. Remarkable softening of the polar optical mode was observed…

Materials Science · Physics 2007-05-23 D. Noujni , S. Kamba , A. Pashkin , V. Bovtun , J. Petzelt , A-K. Axelsson , N. McN Alford , P. L. Wise , I. M. Reaney

The effects of flexibility and chemical composition in the variation of the glass transition temperature are obtained by using the Lindemann criteria, that relates melting temperature with atomic vibrations. Using this criteria and that…

Disordered Systems and Neural Networks · Physics 2015-10-12 Gerardo G. Naumis

We present the results of aging experiments on a variety of glass formers, including xylitol, glycerol, propylene carbonate, and [Ca(NO3)2]0.4[KNO3]0.6 (CKN). In addition, broadband dielectric spectra of xylitol and CKN are provided. We…

Disordered Systems and Neural Networks · Physics 2011-11-09 R. Wehn , P. Lunkenheimer , A. Loidl

Brillouin scattering has been used to measure the dynamic structure factor of glycerol as a function of temperature from the high temperature liquid to the glassy state. Our investigation aims at understanding the number and the nature of…

Soft Condensed Matter · Physics 2009-11-10 Lucia Comez , Daniele Fioretto , Filippo Scarponi , Giulio Monaco

The perovskite crystal BaTiO3 is modeled using a first-principles based effective Hamiltonian and molecular dynamics simulations are performed to estimate the pyroelectric response. The electrocaloric temperature change, \DeltaT, is…

Materials Science · Physics 2012-08-30 S. P. Beckman , L. F. Wan , Jordan A. Barr , Takeshi Nishimatsu

Calcium fluoride (fluorspar, CaF2 ) is of consummate importance for the manufacturing of optical components. In many cases, its wide transmission band eliminates the need for antireflective coatings. It is thus of interest to study its…

Materials Science · Physics 2025-09-10 T. Das , D. Alam , C. A. Ullrich , U. D. Jentschura

The effect of pressure on the low-frequency dielectric constant, $\epsilon_0$, of single crystals of KNbO_3 is investigated by means of capacitance measurements. The dielectric constant increases with pressure up to 22.5 kbar, where it…

Materials Science · Physics 2016-08-15 D. Errandonea , E. Moya