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We investigate the magnetic structure of Mn3-xFexSn2 using neutron powder diffraction experiments and electronic structure calculations. These alloys crystallize in the orthorhombic Ni3Sn2 type of structure (Pnma) and comprise two…

Materials Science · Physics 2013-09-03 Q. Recour , V. Ban , Z. Gercsi , T. Mazet , M. Francois , B. Malaman

Spin tunneling in the particular case of the magnetic molecular cluster octanuclear iron(III), Fe8, is treated by an effective Hamiltonian that allows for an angle-based description of the process. The presence of an external magnetic field…

Quantum Physics · Physics 2009-11-13 D. Galetti , E. C. Silva

Search for single-molecule magnets (SMMs) with high blocking temperature (TB) is urgent for practical applications in magnetic recording, molecular spintronics and quantum computing. Based on the First-principles calculations, magnetic…

Materials Science · Physics 2014-02-04 Jun Hu , Ruqian Wu

The magnetization reversal in a single molecular magnet (SMM) weakly coupled to an electrode with spin-dependent splitting of chemical potentials (spin bias) is theoretically investigated by means of the rate equation. A microscopic…

Mesoscale and Nanoscale Physics · Physics 2009-05-14 Hai-Zhou Lu , Bin Zhou , Shun-Qing Shen

Interplay between topology and magnetism induces various exotic quantum phenomena, with magnetic topological insulators (MTIs) serving as a prominent example due to their ability to host the quantum anomalous Hall effect (QAHE). However,…

Materials Science · Physics 2025-10-14 Ming Xi , Yuchong Zhang , Wenju Zhou , Famin Chen , Donghan Jia , Huiyang Gou , Tian Qian , Hechang Lei

Single-molecule spin transport represents the lower limit of miniaturization of spintronic devices. These experiments, although extremely challenging, are key to understand the magneto-electronic properties of a molecule in a junction. In…

Mesoscale and Nanoscale Physics · Physics 2019-06-18 Silvia Giménez-Santamarina , Salvador Cardona-Serra , José J. Baldoví

The realization of spin based devices is one of the most aspiring goals of spintronics research. Single molecule magnets are an important class of nanoscale magnetic systems with potential to realize different spintronic devices where each…

We study a magnetic molecule that exhibits spin tunneling and is free to rotate about its anisotropy axis. Exact low-energy eigenstates of the molecule that are superpositions of spin and rotational states are obtained. We show that…

Mesoscale and Nanoscale Physics · Physics 2011-03-16 E. M. Chudnovsky , D. A. Garanin

Quantum (step-like) magnetization curves are studies for a spin pair with antiferromagnetic coupling in the presence of a magnetic field parallel to the easy axis of the magnetic anisotropy. The consideration is done both analytically and…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 B. A. Ivanov , V. E. Kireev

We calculate the tunneling splittings in a Mn$_{12}$ magnetic molecule taking into account its internal many-spin structure. We discuss the precision and reliability of these calculations and show that restricting the basis (limiting the…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 H. A. De Raedt , A. H. Hams , V. V. Dobrovitski , M. Al-Saqer , M. I. Katsnelson , B. N. Harmon

The single-molecule magnets {Mn$_{70}$} and {Mn$_{84}$} are characterized by a 14-site unit cell with $S=2$ spin sites arranged in a circular geometry. Experimentally, these systems exhibit a magnetic ground state with a notably low total…

Strongly Correlated Electrons · Physics 2025-02-21 R. Rausch , C. Karrasch

Anisotropic open shell 4f ions have magnetic moments that can be read and written as atomic bits. If it comes to qbits where the phase of the wave function has to be written, controlled and read, it is of advantage to rely on more than one…

Quantum Physics · Physics 2024-03-14 Thomas Greber

We present a theoretical approach to calculate the molecular magnetic anisotropy parameters, $D_M$ and $E_M$ for single molecule magnets in any eigenstate of the exchange Hamiltonian, treating the anisotropy Hamiltonian as a perturbation.…

Strongly Correlated Electrons · Physics 2009-11-13 Rajamani Raghunathan , S. Ramasesha , Diptiman Sen

Here we study thermodynamic properties of an important class of single-chain magnets (SCMs), where alternate units are isotropic and anisotropic with anisotropy axes being non-collinear. This class of SCMs shows slow relaxation at low…

Statistical Mechanics · Physics 2012-08-29 Shaon Sahoo , Jean-Pascal Sutter , S. Ramasesha

We investigate the thermally activated magnetization switching of small ferromagnetic particles driven by an external magnetic field. For low uniaxial anisotropy the spins can be expected to rotate coherently, while for sufficient large…

Statistical Mechanics · Physics 2009-10-31 D. Hinzke , U. Nowak

Modeling blocking temperature in molecular magnets has been a long standing problem in the field of molecular magnetism. We investigate this problem using a kinetic Monte Carlo (kMC) approach on an assembly of 100,000 short molecular…

Strongly Correlated Electrons · Physics 2021-06-23 Sumit Haldar , S. Ramasesha

Precise control of spin states and spin-spin interactions in atomic-scale magnetic structures is crucial for spin-based quantum technologies. A promising architecture is molecular spin systems, which offer chemical tunability and…

Starting from a phenomenological Hamiltonian originally written in terms of angular momentum operators we derive a new quantum angle-based Hamiltonian that allows for a discussion on the quantum spin tunneling. The study of the…

Quantum Physics · Physics 2007-05-23 D. Galetti

Using first-principles methods we study theoretically the properties of an individual $\{Fe_4\}$ single-molecule magnet (SMM) attached to metallic leads in a single-electron transistor geometry. We show that the conductive leads do not…

Mesoscale and Nanoscale Physics · Physics 2014-07-01 J. F. Nossa , M. Fhokrul Islam , C. M. Canali , M. R. Pederson

Simple methods are presented allowing the determination of the magnetic anisotropy axes of a crystal of a single-molecule magnet (SMM). These methods are used to determine an upper bound of the easy axis tilts in a standard Mn12-Ac crystal.…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 W. Wernsdorfer , N. E. Chakov , G. Christou
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