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Conventional perovskite-type ferroelectrics are based on octahedral units of oxygen, and often comprise toxic Pb to achieve robust ferroelectricity. Here, we report the ferroelectricity in a silicate-based compound, Bi2SiO5 (BSO), induced…

Improper ferroelectrics are described by two order parameters: a primary one, driving a transition to long-range distortive, magnetic or otherwise non-electric order, and the electric polarization, which is induced by the primary order…

Interaction between dipoles often emerges intriguing physical phenomena, such as exchange bias in the magnetic heterostructures and magnetoelectric effect in multiferroics, which lead to advances in multifunctional heterostructures.…

Hybrid organic--inorganic perovskites with broken inversion symmetry provide a fertile ground for uncovering coupled spin-orbit and ferroelectric phenomena. Here, we investigate the layered family (PA)$_2$CsY$_2$X$_7$ (Y = Pb, Sn; X = I,…

Materials Science · Physics 2025-12-01 Divyanshi Tyagi , Saswata Bhattacharya

Electric field control of the magnetic state in ferrimagnets holds great promise for developing spintronic devices due to low power consumption. Here, we demonstrate a non-volatile reversal of perpendicular net magnetization in a…

By means of first-principles simulations, we unambiguously show that improper ferroelectricity in magnetite in the low-temperature insulating phase is driven by charge-ordering. An accurate comparison between monoclinic ferroelectric Cc and…

Materials Science · Physics 2015-05-13 Kunihiko Yamauchi , Tetsuya Fukushima , Silvia Picozzi

Rotation of MO6 (M = transition metal) octahedra is a key determinant of the physical properties of perovskite materials. Therefore, tuning physical properties, one of the most important goals in condensed matter research, may be…

We review the phenomenology of coupled magnetic and electric order parameters for systems in which ferroelectric and incommensurate magnetic order occur simultaneously. We discuss the role that such materials might play in fabricating novel…

Materials Science · Physics 2007-05-23 A. B. Harris , G. Lawes

Proposing a general formulism in terms of local coordinates representing the tilting of the ligands' octahedra, we evaluate the electric polarization in a chain of transition metal ions with unpolar octahedron rotation. We find the orbital…

Strongly Correlated Electrons · Physics 2015-06-16 Shan Zhu , You-Quan Li

Strong coupling among spontaneous structural symmetric breaking, magnetism and metallicity in an intrinsic polar magnetic metal can give rise to novel physical phenomena and holds great promise for applications in spintronics. Here, we…

Materials Science · Physics 2025-11-04 Hong-Fei Huang , Houssam Sabri , Jiadong Zang , Jie-Xiang Yu

This review article aims at illustrating the recent progresses in the electrical control of magnetism in oxides with profound physics and enormous potential applications. In the first part, we provide a comprehensive summary of the…

Materials Science · Physics 2015-09-08 Cheng Song , Bin Cui , Jingjing Peng , Haijun Mao , Feng Pan

We studied the ferroelectricity of magnetic oxides in which its emergence coincides with the onset of a second incommensurate magnetic order. We solved for the wave function of e_{g} electrons in the presence of magnetic orders. The…

Strongly Correlated Electrons · Physics 2007-05-23 C. D. Hu

It was recently observed that materials showing most striking multiferroic phenomena are frustrated spin-density-wave magnets. We present a simple phenomenological theory, which describes the orientation of the induced electric polarization…

Strongly Correlated Electrons · Physics 2009-11-11 Maxim Mostovoy

The octahedron tilt transitions of ABX_3 perovskite-structure materials lead to an anti-polar (or antiferroelectric) arrangement of dipoles, with the low temperature structure having six sublattices polarized along various crystallographic…

Strongly Correlated Electrons · Physics 2013-05-29 Philip B. Allen , Yiing-Rei Chen , Santanu Chaudhuri , Clare P. Grey

The emergence of altermagnets establishes a new paradigm for multiferroics. Unlike conventional multiferroics relying on direct magnetoelectric coupling, multiferroic altermagnets host a crystal-symmetry-mediated magnetoelectric interaction…

Materials Science · Physics 2026-01-12 Zhou Cui , Ziye Zhu , Xunkai Duan , Bowen Hao , Xianzhang Chen , Jiayong Zhang , Tong Zhou

Multiferroicity and magnetodielectric coupling in metal-organic-frameworks (MOFs) is rare and so far restricted mainly to formate-based systems with perovskite structure. In the course of this work we designed a tetragonal framework…

Materials Science · Physics 2017-10-31 Tathamay Basu , A. Jesche , B. Bredenkotter , M. Grzywa , D. Denysenko , D. Volkmer , A. Loidl , S. Krohns

We have demonstrated that ferroelectric polarization in a spin-driven multiferroic CuFe1-xGaxO2 with x = 0.035 can be controlled by the application of uniaxial pressure. Our neutron diffraction and in-situ ferroelectric polarization…

Strongly Correlated Electrons · Physics 2015-05-28 T. Nakajima , S. Mitsuda , T. Nakamura , H. Ishii , T. Haku , Y. Honma , M. Kosaka , N. Aso , Y. Uwatoko

Two-dimensional (2D) magnets have broad application prospects in the spintronics, but how to effectively control them with a small electric field is still an issue. Here we propose that 2D magnets can be efficiently controlled in a…

Mesoscale and Nanoscale Physics · Physics 2022-02-01 Ping Li , Xue-Song Zhou , Zhi-Xin Guo

Oxygen octahedral distortions including tilts/rotations, deformations and off-centering in (layered) perovskites play the key role in their numerous functional properties. At the polar-centrosymmetric phase boundary in bi-layered perovskite…

Materials Science · Physics 2017-03-10 F. -T. Huang , B. Gao , J. -W. Kim , X. Luo , Y. Wang , M. -W. Chu , C. -K. Chang , H. -S. Sheu , S. -W. Cheong

Although multiferroics have undergone extensive examination for several decades, the occurrence of ferroelectricity induced by orbital order is only scarcely documented. In this study, we propose the existence of spontaneous ferroelectric…

Materials Science · Physics 2025-01-07 Xiao-Feng Luo , Xu He , Rui Wang , Hongjun Xiang , Jin-Zhu Zhao