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Among the parameters determining the efficiency of an organic solar cell, the open-circuit voltage ($V_\text{OC}$) is the one with most room for improvement. Existing models for the description of $V_\text{OC}$ assume that photogenerated…

Applied Physics · Physics 2021-10-07 Tanvi Upreti , Sebastian Wilken , Huotian Zhang , Martijn Kemerink

A model for the extraction of the charge density dependent mobility and variable contact resistance in thin film transistors is proposed by performing a full derivation of the current-voltage characteristics both in the linear and…

The power conversion efficiency of organic solar cells based on donor--acceptor blends is governed by an interplay of polaron pair dissociation and bimolecular polaron recombination. Both processes are strongly dependent on the charge…

Materials Science · Physics 2010-05-26 C. Deibel , A. Wagenpfahl , V. Dyakonov

An important objective of designing lithium-ion rechargeable battery cells is to maximize their rate performance without compromising the energy density, which is mainly achieved through computationally expensive numerical simulations at…

Materials Science · Physics 2020-05-05 Fan Wang , Ming Tang

In organic solar cells, photogenerated singlet excitons form charge transfer (CT) complexes, which subsequently split into free charge carriers. Here, we consider the contributions of excess energy and molecular quadrupole moments to the…

Prototypes for hot-carrier solar cells based on type-II InAs/AlAsSb multiple quantum wells are examined for AC photoconductivity as a function of lattice temperature and photoexcitation energy to determine the photoexcited charge carrier…

Mesoscale and Nanoscale Physics · Physics 2022-04-12 H. P. Piyathilaka , R. Sooriyagoda , V. R. Whiteside , T. D. Mishima , M. B. Santos , I. R. Sellers , A. D. Bristow

Extraction of charge carriers from a hot carrier solar cell using energy selective contacts, and the impact on limiting power conversion efficiency is analyzed. It is shown that assuming isentropic conversion of carrier heat into voltage…

Mesoscale and Nanoscale Physics · Physics 2015-09-24 Steven Limpert , Stephen Bremner

Transient opto-electrical measurements of methylammonium lead iodide (MALI) perovskite solar cells (PSCs) are performed and analyzed in order to elucidate the operating mechanisms. The current response to a light pulse or voltage pulse…

Materials Science · Physics 2016-11-22 Martin Thomas Neukom

The separation of photogenerated polaron pairs in organic bulk heterojunction solar cells is the intermediate but crucial step between exciton dissociation and charge transport to the electrodes. In state-of-the-art devices, above 80% of…

Materials Science · Physics 2009-07-16 C. Deibel , T. Strobel , V. Dyakonov

We investigated the photocurrent in poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C$_{61}$ butyric acid methyl ester (PCBM) solar cells by applying a pulsed measurement technique. For annealed samples, a point of optimal symmetry…

Materials Science · Physics 2010-02-02 M. Limpinsel , A. Wagenpfahl , M. Mingebach , C. Deibel , V. Dyakonov

Hot carrier solar cells allow potential efficiency close to the thermodynamical limit in ideal conditions. However, the feasability of such devices has not been clearly stated so far and only ideal cells were considered in previous studies.…

Direct measurements of photoexcited carrier dynamics in nickel are made using few-femtosecond extreme ultraviolet (XUV) transient absorption spectroscopy at the nickel M$_{2,3}$ edge. It is observed that the core-level absorption lineshape…

We investigate the relaxation dynamics of photogenerated carriers in silicon nanowires consisting of a crystalline core and a surrounding amorphous shell, using femtosecond time-resolved differential reflectivity and transmission…

Mesoscale and Nanoscale Physics · Physics 2012-12-24 Sunil Kumar , M. Khorasaninejad , M. M. Adachi , K. S. Karim , S. S. Saini , A. K. Sood

Charge separation properties, that is the ability of a chromophore, or a chromophore/semiconductor interface, to separate charges upon light absorption, are crucial characteristics for an efficient photovoltaic device. Starting from this…

Chemical Physics · Physics 2019-12-05 Thibaud Etienne , Mariachiara Pastore

We study the mobility of a charged colloidal particle in a constant homogeneous electric field by means of computer simulations. The simulation method combines a lattice Boltzmann scheme for the fluid with standard Langevin dynamics for the…

Soft Condensed Matter · Physics 2007-06-20 Vladimir Lobaskin , Burkhard Duenweg , Christian Holm

We determined the dominant polaron recombination loss mechanism in pristine and annealed polythiophene:fullerene blend solar cells by applying the photo-induced charge extraction by linearly increasing voltage (photo-CELIV) method in…

Materials Science · Physics 2008-10-30 C. Deibel , A. Baumann , V. Dyakonov

Accurate modeling of charge transport and both thermal and luminescent radiation is crucial to the understanding and design of radiative thermal energy converters. Charge carrier dynamics in semiconductors are well-described by the…

Mesoscale and Nanoscale Physics · Physics 2021-07-13 William A. Callahan , Dudong Feng , Zhuomin M. Zhang , Eric S. Toberer , Andrew J. Ferguson , Eric J. Tervo

Theoretical calculations of the electrical conductivity and electroosmotic transfer as functions of the disperse phase volume fraction and non-dissolving boundary layer thickness were provided on the basis of the cell theory of…

Soft Condensed Matter · Physics 2007-05-23 D. Gulo , O. Alexejev

In perovskite solar cells, photovoltaic action is created by charge transport layers (CTLs) either side of the light-absorbing metal halide perovskite semiconductor. Hence, the rates for desirable charge extraction and unwanted interfacial…

We evaluate the linearity of three electric measurement techniques of the initial electron density in laser filaments by comparing their results for a pair of filaments and for the sum of each individual filament. The conductivity measured…