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Related papers: Quasiparticle and Optical Properties of Rutile and…

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We investigate the quasiparticle band structure of anatase TiO2, a wide gap semiconductor widely employed in photovoltaics and photocatalysis. We obtain GW quasiparticle energies starting from density-functional theory (DFT) calculations…

Materials Science · Physics 2012-04-23 Christopher E. Patrick , Feliciano Giustino

The quasiparticle electronic structure and optical excitation of anatase TiO$_2$ is determined within the framework of many-body perturbation theory (MBPT) by combining the $G_0W_0$ method and the Bethe-Salpeter Equation (BSE). A modified…

Materials Science · Physics 2021-12-07 Sruthil Lal S. B , D Murali , Matthias Posselt , Assa Aravindh Sasikala Devi , Alok Sharan

Rutile GeO$_2$ is a visible and near-ultraviolet-transparent oxide that has not been explored for semiconducting applications in electronic and optoelectronic devices. We investigate the electronic and optical properties of rutile GeO$_2$…

Materials Science · Physics 2019-08-27 Kelsey A. Mengle , Sieun Chae , Emmanouil Kioupakis

The optical properties of thermally annealed TiO2 samples depend on their preparation process, and the TiO2 thin films usually exist in the form of anatase or rutile or the mixture of the two phases. The electronic structures and optical…

Materials Science · Physics 2016-11-29 Li Jinping , Meng Songhe , Qin Liyuan , Hantao Lu

In this paper, I demonstrate a density functional theory plus dynamical mean field theory study on the electronic properties of doped $TiO_2$ rutile as well as another tetragonal phase anatase with oxygen vacancy. The density of states and…

Strongly Correlated Electrons · Physics 2021-12-24 S. Koley

The electronic band structure of V$_2$O$_5$ is calculated using an all-electron quasiparticle self-consistent (QS) $GW$ method, including electron-hole ladder diagrams in the screening of $W$. The optical dielectric function calculated with…

Materials Science · Physics 2024-07-31 Claudio Garcia , Santosh Kumar Radha , Swagata Acharya , Walter R. L. Lambrecht

We present a unified ab-initio study of electronic and optical properties of TiO2 rutile and anatase phases, with a combination of Density Functional Theory and Many Body Perturbation Theory techniques. The consistent treatment of…

The optical response functions and band structures of LiCoO$_2$ are studied at different levels of approximation, from density functional theory (DFT) in the generalized gradient approximation (GGA) to quasiparticle self-consistent QS$GW$…

A first-principles computational study is presented of various phases of LiAlO$_2$.The $\beta$ and $\gamma$ tetrahedral phases are found to be very close in energy with the $\gamma$ phase having the lowest energy. The octahedral $\alpha$…

Materials Science · Physics 2022-11-02 Phillip Popp , Walter R. L. Lambrecht

The band structure of $\beta$-LiGaO$_2$ is calculated using the quasiparticle self-consistent QS$G\hat W$ method where the screened Coulomb interaction $\hat W$ is evaluated including electron-hole interaction ladder diagrams and $G$ is the…

Materials Science · Physics 2023-04-26 Niloufar Dadkhah , Walter R. L. Lambrecht , Dimitar Pashov , Mark van Schilfgaarde

Doping is one of the most common strategies for improving the photocatalytic and solar energy conversion properties of TiO$_2$, hence an accurate theoretical description of the electronic and optical properties of doped TiO$_2$ is of both…

Anatase TiO$_2$ is among the most studied materials for light-energy conversion applications, but the nature of its fundamental charge excitations is still unknown. Yet it is crucial to establish whether light absorption creates…

We present theoretical results of the calculations of optical functions for Cu$_2$O quantum well (QW) with Rydberg excitons in an external homogeneous electric field of an arbitrary field strength. Two configurations of an external electric…

Mesoscale and Nanoscale Physics · Physics 2021-09-01 David Ziemkiewicz , Gerard Czajkowski , Karol Karpiński , Sylwia Zielińska - Raczyńska

Knowledge of the molecular frontier levels' alignment in the ground state can be used to predict the photocatalytic activity of an interface. The position of the adsorbate's highest occupied molecular orbital (HOMO) levels relative to the…

Materials Science · Physics 2015-06-16 Huijuan Sun , Duncan J. Mowbray , Annapaola Migani , Jin Zhao , Hrvoje Petek , Angel Rubio

We studied the oxygen vacancies($V_{O}$) in rutile TiO2 by using $G_0W_0$ approximation on top of GGA+$U$ as a method of choice to improve the gap. Since there is no extensive agreement regarding the characteristic of electron localization…

Strongly Correlated Electrons · Physics 2010-12-30 Ali Kazempour , Seyed Javad Hashemifar , Hadi Akbarzadeh

Ab-initio, self-consistent electronic energy bands of rutile TiO2 are reported within the local density functional approximation (LDA). Our first principle, non-relativistic and ground state calculations employed a local density functional…

Materials Science · Physics 2012-03-23 C. E. Ekuma , D. Bagayoko

We present a tight-binding based GW approach for the calculation of quasiparticle energy levels in confined systems such as molecules. Key quantities in the GW formalism like the microscopic dielectric function or the screened Coulomb…

Materials Science · Physics 2009-11-10 T. A. Niehaus , M. Rohlfing , F. Della Sala , A. Di Carlo , Th. Frauenheim

The relative energies of the low-pressure rutile, anatase, and brookite polymorphs and the high-pressure columbite polymorph of TiO$_2$ have been calculated as a function of temperature using the diffusion quantum Monte Carlo (DMC) method…

Materials Science · Physics 2017-04-05 John Trail , Bartomeu Monserrat , Pablo López Ríos , Ryo Maezono , Richard J. Needs

Titanium dioxide is one of the most widely investigated oxides. This is due to its broad range of applications, from catalysis to photocatalysis to photovoltaics. Despite this large interest, many of its bulk properties have been sparsely…

Materials Science · Physics 2010-03-12 L. Chiodo , J. M. García-Lastra , D. J. Mowbray , A. Iacomino , A. Rubio

The quasiparticle (QP) band structures of both strainless and strained monolayer MoS$_{2}$ are investigated using more accurate many body perturbation \emph{GW} theory and maximally localized Wannier functions (MLWFs) approach. By solving…

Materials Science · Physics 2013-04-10 Hongliang Shi , Hui Pan , Yong-Wei Zhang , Boris I. Yakobson
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