Related papers: Recent progress in exploring magnetocaloric materi…
This chapter reviews the basic physics and thermodynamics that govern magnetocaloric materials. The thermodynamics of magnetic materials is discussed by introducing relevant free energy terms together with their microscopic origin leading…
We report an experimental demonstration of the magnetoelectrocaloric effect (MECE) in multiferroic $\mathrm{GdFeO_3}$. The temperature of the magnetic material changes when an external electric field is suddenly changed. MECE is the largest…
Compositionally complex materials (CCMs) present a potential paradigm shift in the design of magnetic materials. These alloys exhibit long-range structural order coupled with limited or no chemical order. As a result, extreme local…
Cost-effective materials are essential for large-scale deployment. The emerging magnetocaloric hydrogen liquefaction technology could transform the liquid hydrogen industry due to its potential in achieving higher efficiency. Most studies…
We report proof-of-concept measurements of the magnetocaloric effect (MCE) in ultrahigh magnetic fields up to 120 T for the classical spin-ice compound Ho$_{2}$Ti$_{2}$O$_{7}$. Radio-frequency resistivity measurements using an…
The large magnetocaloric effect (MCE) observed in Ni-Mn based shape-memory Heusler alloys put them forward to use in magnetic refrigeration technology. It is associated with a first-order magnetostructural (martensitic) phase transition. We…
La(Fe$_x$Si$_{1-x}$)$_{13}$ and derived quaternary compounds are well-known for their giant, tunable, magneto- and barocaloric responses around a first-order paramagnetic-ferromagnetic transition near room temperature with low hysteresis.…
The magnetocaloric effect (MCE) in the A-site ordered manganite NdBaMn2O6 is studied. The MCE in this compound has an anomalous behavior. In low magnetic fields, the abrupt transitions between direct and inverse magnetocaloric effect are…
The rotating magnetocaloric effect (RMCE) induced by self-demagnetization has been investigated in the giant magnetocaloric effect (GMCE) material Gd$_5$Si$_2$Ge$_2$. This shape-dependent effect had thus far only been reported in pure Gd,…
We report the observation of giant magneto-caloric effect (MCE) in ferromagnetic shape memory alloys (FSMAs) of nominal compositions Ni$_2$Mn$_{1.36}$Sn$_{0.64-x}$Ga$_{x}$ ($x$ =0.24, 0.28 and 0.32). Irrespective of the Ga doping, all the…
In this paper we explore the magnetocaloric effect (MCE) of chromium-doped elpasolite Cs$_2$NaAl$_{1-x}$Cr$_x$F$_6$ (x = 0.01 and 0.62) single crystals. Our magnetization and heat capacity data show the magnetocaloric potentials to be…
The advent of caloric materials for magnetocaloric, elastocaloric, and electrocaloric cooling is changing the landscape of solid state cooling technologies with potentials for high-efficiency and environmentally-friendly residential and…
The isostructural alloying of two compounds with extremely different magnetic and thermo-structural properties has resulted in a new system, (MnNiSi)1-x(FeCoGe)x, that exhibits extraordinary magnetocaloric properties with an acute…
In this paper we report the existence of a giant magnetocaloric effect (MCE) in a intermetallic compound non-containing rare-earth. This effect is associated with the concomitant occurrence of a structural and a magnetic transition. The…
We report a novel negative magnetocaloric effect in CoMnSi_{1-x}Ge_{x} arising from a metamagnetic magnetoelastic transition. The effect is of relevance to magnetic refrigeration over a wide range of temperature, including room temperature.…
Giant magnetocaloric effect is widely achieved in hexagonal MnMX-based (M = Co or Ni, X = Si or Ge) ferromagnets at their first-order magnetostructural transition. However, the thermal hysteresis and the low sensitivity of the…
In this article we give a general survey of the main properties of magnetic oxides - mostly the oxides of transition metals, but sometime also containing rare earths ions. This is a very rich class of materials, among which there are…
Transition metal telluride compositions are explored extensively for their unique magnetic behavior. Since chromium telluride (Cr2Te3) exhibits a near-room-temperature phase transition, the material can be effectively used in applications…
We report a giant magnetocaloric effect near room temperature in an off-stoichiometric Mn-Co-Ge alloy, across the magnetostructural transition. The isothermal entropy change accompanying this transition has a peak value of nearly 40 J/kg-K…
A method for direct measurement of the magnetocaloric effect (MCE) in alternating magnetic fields is offered. Main advantages of the method compared to a classical direct one are the high temperature sensitivity (better than 10-3 K); the…