Related papers: Physicochemical Perturbations of Phase Equilibrium…
Droplets abound in nature and technology. In general, they are multicomponent, and, when out of equilibrium, with gradients in concentration, implying flow and mass transport. Moreover, phase transitions can occur, with either evaporation,…
We study the thermodynamic behavior of nonpolar liquid mixtures in the vicinity of curved charged objects, such as electrodes or charged colloids. For small enough charge on the object, or equivalently, small potential, the…
The interface between a pure liquid and its vapor is usually close to saturation temperature, hence strongly hindering any thermocapillary flow. In contrast, when the gas phase contains an inert gas such as air, surface-tension-driven…
A supersolid is a fascinating phase of matter, combining the global phase coherence of a superfluid with hallmarks of solids, e.g. a spontaneous breaking of the translational symmetry. Recently, states with such counter-intuitive properties…
We look at the influence of external fields on systems described by generic free energy functional of the order parameter. The external force may have arbitrary spatial dependence, and the order parameter coupling may be nonlinear. The…
Motion of chemically driven droplets is analyzed by applying a solvability condition of perturbed hydrodynamic equations affected by the adsorbate concentration. Conditions for traveling bifurcation analogous to a similar transition in…
This work is devoted to the consistent modeling of a three-phase mixture of a gas, a liquid and its vapor. Since the gas and the vapor are mis-cible, the mixture is subjected to a non-symmetric constraint on the volume. Adopting the Gibbs…
A thermodynamically consistent framework able to model either diffusive and displacive phase transitions is proposed. The first law of thermodynamics, the balance of linear momentum equation and the Cahn-Hilliard equation for solute mass…
We study nonequilibrium phase transitions in a mass-aggregation model which allows for diffusion, aggregation on contact, dissociation, adsorption and desorption of unit masses. We analyse two limits explicitly. In the first case mass is…
The liquid-gas phase transition in finite nuclei is studied in a heated liquid-drop model where the drop is assumed to be in thermodynamic equilibrium with the vapour emanated from it. Changing pressure along the liquid-gas coexistence line…
We develop a phase-field model for evaporation from a porous medium by explicitly considering a vapor component together with the liquid and gas phases in the system. The phase-field model consists of the conservation of mass (for phases…
Equilibrium thermodynamics is grounded in the law of energy conservation, with a specific focus on how systems exchange energy with their environment during transitions between equilibrium states. These transitions are typically…
A phase-field approach to the dynamics of liquid-solid interfaces that evolve due to precipitation and/or dissolution is presented. For the purpose of illustration and comparison with other methods, phase field simulations were carried out…
A flux of ideal fluid coupled to perturbation is investigated by nonperturbative methods of the quantum field theory. Asymptotic behavior of the flux coupled to perturbation turns out to be similiar to that of superfluids.
The Liouville theorem is a fundamental concept in understanding the properties of systems that adhere to Hamilton's equations. However, the traditional notion of the theorem may not always apply. Specifically, when the entropy gradient in…
Pair potentials that are bounded at the origin provide an accurate description of the effective interaction for many systems of dissolved soft macromolecules (e.g., flexible dendrimers). Using numerical free-energy calculations, we…
In this paper, the physics of flow instability and turbulent transition in shear flows is studied by analyzing the energy variation of fluid particles under the interaction of base flow with a disturbance. For the first time, a model…
We propose a model describing the liquid-vapour phase transition according to a phase-field approach. The model takes up a setting proposed by the second author, where a phase field is introduced whose equilibrium values 0 and 1 are…
The problem of the flow trough a porous media is formulated in terms of a pressure equation, based on arguments of volume conservation which state the mechanical equilibrium between the solid and the fluid phases. In the resulting governing…
In the present paper, the connection between surface order-disorder phase transitions and the percolating properties of the adsorbed phase has been studied. For this purpose, four lattice-gas models in presence of repulsive interactions…