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A self-interacting polymer can undergo an orientational ordering transition, depending on the magnitude of the nematic interaction. The effect of embedding such a polymer into a flexible surface on this transition is studied on the…

Condensed Matter · Physics 2009-10-28 Rudolf Podgornik

We investigate the dynamics and the pathways of the collapse of a single, semiflexible polymer in a poor solvent via 3-D Brownian Dynamics simulations. Earlier work indicates that the condensation of semiflexible polymers generically…

Soft Condensed Matter · Physics 2009-11-10 Alberto Montesi , Matteo Pasquali , F. C. MacKintosh

A phase diagram for a surface interacting long flexible partially directed polymer chain in a two-dimensional poor solvent where the possibility of collapse in the bulk exists is determined using exact enumeration method. We used a model of…

Statistical Mechanics · Physics 2020-12-29 Pramod K Mishra , Yashwant Singh

Directed polymers on 1+1 dimensional lattices coupled to a heat bath at temperature $T$ are studied numerically for three ensembles of the site disorder. In particular correlations of the disorder as well as fractal patterning are…

Disordered Systems and Neural Networks · Physics 2022-09-01 Alexander K. Hartmann

We analyze equilibrium properties and adsorption desorption phase transition behaviour of a linear semiflexible copolymer chain under constrained geometrical situation on square lattice in a good solvent. One dimensional stair shaped line…

Statistical Mechanics · Physics 2010-06-04 Pramod Kumar Mishra

We have studied the structure and free energy landscape of a semi-flexible lattice-polymer in the presence of a surface. At low temperatures coexistence of two-dimensional integer-folded crystals is observed. As the temperature is increased…

Soft Condensed Matter · Physics 2007-05-23 Jonathan Doye , Daan Frenkel

Frontal polymerization is a promising energy-saving method for rapid fabrication of polymer components with good mechanical properties. In these systems, a small energy input is sufficient to convert monomers, from a liquid or soft solid…

Soft Condensed Matter · Physics 2023-10-04 Xuanhe Li , Tal Cohen

We have analyzed the equilibrium response of chain molecules to stretching. For a homogeneous sequence of monomers, the induced transition from compact globule to extended coil below the $\theta$-temperature is predicted to be sharp. For…

Soft Condensed Matter · Physics 2009-11-07 Phillip L. Geissler , Eugene I. Shakhnovich

We study the behavior of a flexible polymer chain in the presence of a low-molecular weight solvent in the vicinity of a liquid-gas critical point within the framework of a self-consistent field theory. The total free energy of the dilute…

Statistical Mechanics · Physics 2015-07-29 Yu. A. Budkov , A. L. Kolesnikov , N. Georgi , M. G. Kiselev

Limited-valency colloidal particles can self-assemble into polymeric structures analogous to molecules. While their structural equilibrium properties have attracted wide attention, insight into their dynamics has proven challenging. Here,…

Soft Condensed Matter · Physics 2021-09-08 Simon Stuij , Joep Rouwhorst , Hannah Jonas , Nicola Ruffino , Zhe Gong , Stefanno Sacanna , Peter Bolhuis , Peter Schall

We analyse the nature of the confinement of an infinitely long (and finite) linear semiflexible homo-polymer chain confined in between two geometrical constraints (A&B) under good solvent condition in two dimensions. The constraints are…

Soft Condensed Matter · Physics 2017-10-16 Pramod Kumar Mishra

A constitutive model is developed for the mechanical response of elastomers at finite strains. A polymer is treated as a network of linear chains linked by permanent (chemical crosslinks) and temporary (entanglements and van der Waals…

Materials Science · Physics 2007-05-23 Aleksey D. Drozdov , Al Dorfmann

Loops undergoing thermal fluctuations are prevalent in nature. Ring-like or cross-linked polymers, cyclic macromolecules, and protein-mediated DNA loops all belong to this category. Stability of these molecules are generally described in…

Computational Physics · Physics 2016-04-27 James T. Waters , Harold D. Kim

This paper reviews recent Monte Carlo simulation studies of the glassy behavior in thin polymer films. The simulations employ a version of the bond-fluctuation lattice model, in which the glass transition is driven by the competition…

Soft Condensed Matter · Physics 2007-05-23 C. Mischler , J. Baschnagel , K. Binder

We investigate the conformations of a semiflexible polymer confined to a square box. Results of Monte Carlo simulations show the existence of a shape transition when the persistence length of the polymer becomes comparable to the dimensions…

Soft Condensed Matter · Physics 2008-06-19 Y. Liu , B. Chakraborty

We explore the effect of an attractive interaction between parallel-aligned polymers, which are perpendicularly grafted on a substrate. Such an attractive interaction could be due to, e.g., reversible cross-links. The competition between…

Soft Condensed Matter · Physics 2013-10-08 Panayotis Benetatos , Eugene M. Terentjev , Annette Zippelius

We consider an inextensible, semiflexible polymer or worm-like chain which is confined in the transverse direction by a parabolic potential and subject to a longitudinal force at the ends, so that the polymer is stretched out and…

Soft Condensed Matter · Physics 2015-05-28 Theodore W. Burkhardt

The extension elasticity of rod-coil mutliblock copolymers is analyzed for two experimentally accessible situations. In the quenched case, when the architecture is fixed by the synthesis, the force law is distinguished by a sharp change in…

Soft Condensed Matter · Physics 2009-10-31 A. Buhot , A. Halperin

Semiflexible polymers are widely used as a paradigm for understanding structural phases in biomolecules including folding of proteins. Here, we compare bead-spring and bead-stick variants of coarse-grained semiflexible polymer models that…

Soft Condensed Matter · Physics 2024-02-16 Wolfhard Janke , Suman Majumder , Martin Marenz , Subhajit Paul

Inspired by recent experiments on chromosomal dynamics, we introduce an exactly solvable model for the interaction between a flexible polymer and a set of motor-like enzymes. The enzymes can bind and unbind to specific sites of the polymer…

Soft Condensed Matter · Physics 2019-04-03 Stefanie Put , Takahiro Sakaue , Carlo Vanderzande
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