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Heusler alloys that undergo martensitic transformation in ferromagnetic state are of increasing scientific and technological interest. These alloys show large magnetic field induced strains upon martensitic phase change thus making it a…

Materials Science · Physics 2009-11-13 P. A. Bhobe , K. R. Priolkar , P. R. Sarode

The local atomic structure of Ni$_{2+x}$Mn$_{1-x}$Ga with 0 $\le$ $x$ $\le$ 0.16 alloys was explored using Mn and Ga K-edge Extended X-ray Absorption Fine Structure (EXAFS) measurement. Inorder to study the atomic re-arrangements that occur…

Materials Science · Physics 2009-11-11 P. A. Bhobe , K. R. Priolkar , P. R. Sarode

We have carried out \textit{ab-initio} calculations of local structure of Mn and Ni in Mn$_{2}$Ni$_{1.5}$In$_{0.5}$ alloy with different site occupancies in order to understand the similarities in martensitic and magnetic properties of…

Materials Science · Physics 2017-01-31 D. N. Lobo , K. R. Priolkar , A. Koide , S. Emura

The local atomic structure of Ni-Mn-Ga alloys was explored using Mn and Ga K-edge extended X-ray fine structure (EXAFS) measurement. The changes occuring in the L1$_0$ sub-cell of the martensitic unit cell and the bond lengths obtained from…

Materials Science · Physics 2007-05-23 P. A. Bhobe , K. R. Priolkar , P. R. Sarode

Martensitic and magnetic properties of ferromagnetic shape memory alloys are known to depend up on structural modulations and associated changes in the Fermi surface. These modulations although periodic and spanning over multiple unit…

Materials Science · Physics 2008-04-24 K. R. Priolkar , P. A. Bhobe , P. R. Sarode

Extended x-ray absorption fine-structure (EXAFS) measurements have been carried out on Ni$_{50}$Mn$_{35}$Sn$_{15}$ in the austenitic and martensitic phase. The temperatures associated with structural and magnetic phase transformations are…

Materials Science · Physics 2009-11-13 P. A. Bhobe , K. R. Priolkar , P. R. Sarode

The magnetic properties of Mn$_{2}$Ni$_{(1+x)}$In$_{(1-x)}$ ($x$ = 0.5, 0.6, 0.7) and Mn$_{(2-y)}$Ni$_{(1.6+y)}$In$_{0.4}$ ($y$ = -0.08, -0.04, 0.04, 0.08) shape memory alloys have been studied. Magnetic interactions in the martensitic…

Materials Science · Physics 2015-06-17 D. N. Lobo , Sandhya Dwivedi , C. A. daSilva , N. O. Moreno , K. R. Priolkar , A. K. Nigam

Room temperature Mn K-edge extended x-ray absorption fine structure (EXAFS) studies were carried out on La$_{1-x}$Sr$_x$MnO$_{3+\delta}$ (x = 0.1 to 0.9) compounds. It is found from the detailed EXAFS analysis that the local structure…

Materials Science · Physics 2009-11-11 R. Bindu , S. K. Pandey , Ashwani Kumar , S. Khalid , A. V. Pimpale

At certain compositions Ni-Mn-$X$ Heusler alloys ($X$: group IIIA-VA elements) undergo martensitic transformations, and many of them exhibit inverse magnetocaloric effects. In alloys where $X$ is Sn, the isothermal entropy change is largest…

Materials Science · Physics 2009-11-13 Thorsten Krenke , Eyup Duman , Mehmet Acet , Xavier Moya , Lluis Manosa , Antoni Planes

The all-d-metal Mn2-based Heusler ferromagnetic shape memory alloys Mn50Ni40-xCoxTi10 (x = 8 and 9.5) are realized. With a generic comparison between d-metal Ti and main-group elements in lowering the transformation temperature, the…

Materials Science · Physics 2016-08-24 Z. Y. Wei , E. K. Liu , Y. Li , X. L. Han , Z. W. Du , H. Z. Luo , G. D. Liu , X. K. Xi , H. W. Zhang , W. H. Wang , G. H. Wu

The martensitic transformation in Ni$_{2}$Mn$_{1+x}$Sn$_{1-x}$ alloys has been investigated within ab-initio density functional theory. The experimental trend of a martensitic transition happening beyond $x$ = 0.36 is captured within these…

Materials Science · Physics 2016-10-12 Soumyadipta Pal , Sagar Sarkar , Shishir Kumar Pandey , Chhayabrita Maji , Priya Mahadevan

Extended X-ray Absorption Fine Structure (EXAFS) studies on Ni$_{50}$Mn$_{25+x}$In$_{25-x}$ have been carried out at Ni and Mn K edge as a function of temperature. Thermal evolution of nearest neighbor Ni-Mn and Mn-Mn bond distances in the…

Materials Science · Physics 2015-05-27 K. R. Priolkar , D. N. Lobo , P. A. Bhobe , S. Emura , A. K. Nigam

The structure, magnetic and martensitic properties of Fe doped Ni-Mn-In magnetic shape memory alloys have been studied by differential scanning calorimetry, magnetization, resistivity, X-ray diffraction (XRD) and EXAFS. While…

Materials Science · Physics 2015-06-23 D. N. Lobo , K. R. Priolkar , S. Emura , A. K. Nigam

Ni$_{50}$Mn$_{34}$In$_{16}$ undergoes a martensitic transformation around 250 K and exhibits a field induced reverse martensitic transformation and substantial magnetocaloric effects. We substitute small amounts Ga for In, which are…

Effect of the temperature and magnetic field induced martensitic transformation (MT) on the electronic structure and some physical properties of bulk Fe$_{45.2}$Mn$_{25.9}$Ga$_{28.9}$ Heusler alloy has been investigated. {According to the…

Materials Science · Physics 2019-02-21 Y. V. Kudryavtsev , N. V. Uvarov , A. E. Perekos , J. Dubowik , L. E. Kozlova

MnMX (M = Co or Ni, X = Si or Ge) alloys, experiencing structural transformation between Ni2In-type hexagonal and TiNiSi-type orthorhombic phases, attract considerable attention due to their potential applications as room-temperature solid…

Materials Science · Physics 2021-08-03 Tingting Zhang , Yuanyuan Gong , Bin Wang , Dongyu Cen , Feng Xu

A delicate balance between various factors such as site occupancy, composition and magnetic ordering seems to affect the stability of the martensitic phase in Mn$_{2}$Ni$_{1+x}$Sn$_{1-x}$. Using first-principles DFT calculations, we explore…

Materials Science · Physics 2018-01-17 Ashis Kundu , Subhradip Ghosh

A systematic study of magnetic properties of Ni2+xMn1-xGa (0 \le x \le 0.19) Heusler alloys undergoing structural martensite-austenite transformations while in ferromagnetic state has been performed. From measurements of spontaneous…

Materials Science · Physics 2009-11-10 V. V. Khovailo , V. Novosad , T. Takagi , D. A. Filippov , R. Z. Levitin , A. N. Vasilev

The structural, magnetic, transport, thermal and magnetothermal properties of quaternary Heusler alloys Ni50Mn38-xFexSb12 have been studied. Powder x-ray diffraction and temperature dependence of magnetization studies reveal that with…

Strongly Correlated Electrons · Physics 2015-05-27 Roshnee Sahoo , Ajaya K. Nayak , K. G. Suresh , A. K. Nigam

The thermoelectric power (TEP) measurements have been carried out to investigate the changes in the electronic structure associated with the intermartensitic and martensitic transitions in Ni$_{2+x}$Mn$_{1-x}$Ga (0 $\le$ x $\le$ 0.19). The…

Materials Science · Physics 2009-11-11 P. A. Bhobe , J. H. Monteiro , J. C. Cascalheira , S. K. Mendiratta , K. R. Priolkar , P. R. Sarode
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