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A large-scale molecular dynamics simulation is performed on a glass-forming Lennard-Jones mixture to determine the nature of dynamical heterogeneities which arise in this model fragile liquid. We observe that the most mobile particles…

Disordered Systems and Neural Networks · Physics 2009-10-30 Claudio Donati , Jack F. Douglas , Walter Kob , Steven J. Plimpton , Peter H. Poole , Sharon C. Glotzer

The interaction-site-density-fluctuation correlators, the dipole-relaxation functions, and the mean-squared displacements of a system of symmetric dumbbells of fused hard spheres are calculated for two representative elongations of the…

Soft Condensed Matter · Physics 2009-11-07 S. -H. Chong , W. Gotze

If a liquid is cooled rapidly to form a glass, its structural relaxation becomes retarded, producing a drastic increase in viscosity. In two dimensions, strong long-wavelength fluctuations persist, even at low temperature, making it…

Soft Condensed Matter · Physics 2019-12-25 Hayato Shiba , Takeshi Kawasaki , Kang Kim

As approaching the glass transition, particle motion in liquids becomes highly heterogeneous and regions with virtually no mobility coexist with liquid-like domains. This complex dynamics is believed to be responsible for different…

Soft Condensed Matter · Physics 2018-03-28 F. Puosi , N. Jakse , A. Pasturel

We study a kinetically constrained lattice glass model in which continuous local densities are randomly redistributed on neighbouring sites with a kinetic constraint that inhibits the process at high densities, and a random bias accounting…

Disordered Systems and Neural Networks · Physics 2007-05-23 Eric Bertin , Jean-Philippe Bouchaud , Francois Lequeux

Existence and growth of amorphous order in supercooled liquids approaching glass transition is a subject of intense research. Even after decades of work, there is still no clear consensus on the molecular mechanisms that lead to a rapid…

Statistical Mechanics · Physics 2023-03-14 Rajsekhar Das , Saurish Chakrabarty , Smarajit Karmakar

Probing dynamic and static correlation in glass-forming supercooled liquids has been a challenge for decades in spite of extensive research. Dynamic correlation which manifests itself as Dynamic Heterogeneity is ubiquitous in a vast variety…

Statistical Mechanics · Physics 2021-09-22 Anoop Mutneja , Smarajit Karmakar

Binary mixtures of hard-spheres with different diameters and square-well attraction between different particles are studied by theory and Monte Carlo simulations. In our mesoscopic theory, local fluctuations of the volume fraction of the…

Soft Condensed Matter · Physics 2021-10-04 O. Patsahan , A. Meyra , A. Ciach

The breakdown of the Stokes-Einstein (SE) relation between diffusivity and viscosity at low temperatures is considered to be one of the hallmarks of glassy dynamics in liquids. Theoretical analyses relate this breakdown with the presence of…

Statistical Mechanics · Physics 2015-06-12 Shiladitya Sengupta , Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

We use molecular dynamics to investigate the glass transition occurring at large volume fraction, phi, and low temperature, T, in assemblies of soft repulsive particles. We find that equilibrium dynamics in the (phi, T) plane obey a form of…

Statistical Mechanics · Physics 2009-04-10 Ludovic Berthier , Thomas A. Witten

Fragility, quantifying the rapidity of variation of relaxation times, is analysed for a series of model glass formers, which differ in the softness of their interparticle interactions. In an attempt to rationalize experimental observations…

Soft Condensed Matter · Physics 2017-05-30 Anshul D. S. Parmar , Pallabi Kundu , Srikanth Sastry

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

Disordered Systems and Neural Networks · Physics 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi

The growth of cooperatively rearranging regions was invoked long ago by Adam and Gibbs to explain the slowing down of glass-forming liquids. The lack of knowledge about the nature of the growing order, though, complicates the definition of…

Disordered Systems and Neural Networks · Physics 2012-07-19 Andrea Cavagna , Tomas S. Grigera , Paolo Verrocchio

One of the central problems of the liquid-glass transition is whether there is a structural signature that can qualitatively distinguish different dynamic behaviors at different degrees of supercooling. Here, we propose a novel structural…

Soft Condensed Matter · Physics 2015-09-24 Yan-Wei Li , You-Liang Zhu , Zhao-Yan Sun

We show numeric evidence that, at low enough temperatures, the potential energy density of a glass-forming liquid fluctuates over length scales much larger than the interaction range. We focus on the behavior of translationally invariant…

Soft Condensed Matter · Physics 2009-04-21 L. A. Fernandez , V. Martin-Mayor , P. Verrocchio

Understanding the influence of activity on dense amorphous assemblies is crucial for biological processes such as wound healing, embryogenesis, or cancer progression. Here, we study the effect of self-propulsion forces of amplitude $f_0$…

Soft Condensed Matter · Physics 2026-01-27 Puneet Pareek , Peter Sollich , Saroj Kumar Nandi , Ludovic Berthier

In a recent paper [S. Mandal et al., Phys. Rev. E 88, 022129 (2013)] the nature of spatial correlations of plasticity in hard sphere glasses was addressed both via computer simulations and in experiments. It was found that the…

The utility of a cooperative length scale for describing the dynamics of glass-forming liquids is shown using literature data on o-terphenyl. Molecular dynamics and Monte Carlo simulations reveal a distribution of cooperative fractal events…

Other Condensed Matter · Physics 2007-05-23 B. M. Erwin , S. Y. Kamath , R H. Colby

Many amorphous materials show spatially heterogenous dynamics, as different regions of the same system relax at different rates. Such a signature, known as Dynamic Heterogeneity, has been crucial to understand the jamming transition in…

Soft Condensed Matter · Physics 2017-04-24 Raffaele Pastore , Giuseppe Pesce , Marco Caggioni

A recently published analytical model, describing and predicting elasticity, viscosity, and fragility of metallic melts, is applied for the analysis of about 30 nonmetallic glassy systems, ranging from oxide network glasses to alcohols,…

Disordered Systems and Neural Networks · Physics 2020-09-25 Peter Lunkenheimer , Felix Humann , Alois Loidl , Konrad Samwer