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We report strong variations in the Raman spectra for different single-layer graphene samples obtained by micromechanical cleavage, which reveals the presence of excess charges, even in the absence of intentional doping. Doping…

Materials Science · Physics 2008-01-07 C. Casiraghi , S. Pisana , K. S. Novoselov , A. K. Geim , A. C. Ferrari

The Raman scattering spectra (RS) of two series of monolayer graphene samples irradiated with various doses of C$^{+}$ and Xe$^{+}$ ions were measured after annealing in high vacuum, and in forming gas (95\%Ar+5\%H$_{2}$). It was found that…

Mesoscale and Nanoscale Physics · Physics 2017-09-28 E. Zion , A. Butenko , Yu. Kaganovskii , V. Richter , L. Wolfson , A. Sharoni , E. Kogan , M. Kaveh , I. Shlimak

Electron-phonon coupling directly determines the stability of cooperative order in solids, including superconductivity, charge and spin density waves. Therefore, the ability to enhance or reduce electron-phonon coupling by optical driving…

The electron-phonon interaction in monolayer graphene is investigated by using density functional perturbation theory. The results indicate that the electron-phonon interaction strength is of comparable magnitude for all four in-plane…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 K. M. Borysenko , J. T. Mullen , E. A. Barry , S. Paul , Y. G. Semenov , J. M. Zavada , M. Buongiorno Nardelli , K. W. Kim

We report the first systematic measurements of the Raman scattering by electrons in elemental metals of Al, Mo, Nb, Os, Pb, Re, Ta, Ti, V, W and metallic compound La$B_6$. Experimental spectra are modelled on the base of the band…

Strongly Correlated Electrons · Physics 2012-08-09 Yu. S. Ponosov , S. V. Streltsov

We theoretically investigate the double-resonance Raman spectrum of monolayer graphene down to infrared laser excitation energies. By using first-principles density functional theory calculations, we improve upon previous theoretical…

Mesoscale and Nanoscale Physics · Physics 2025-05-21 Lorenzo Graziotto , Francesco Macheda , Thibault Sohier , Matteo Calandra , Francesco Mauri

The influence of GaN nanowires on the optical and electrical properties of graphene deposited on them was studied using Raman spectroscopy and microwave induced electron transport method. It was found that interaction with the nanowires…

As the synthesis of graphene on copper became one of the primary preparation methods for both fundamental research and industrial application, Raman spectra of graphene/Cu systems need to be quantitatively understood regarding how their…

Materials Science · Physics 2020-08-07 Jieun Choi , Seonghyun Koo , Myeongin Song , Daeyool Jung , Sungyool Choi , Sunmin Ryu

Polarization resolved, Raman scattering response due to E$_{2g}$ phonon in monolayer graphene has been investigated in magnetic fields up to 29 T. The hybridization of the E$_{2g}$ phonon with only the fundamental inter Landau level…

Mesoscale and Nanoscale Physics · Physics 2013-01-01 P. Kossacki , C. Faugeras , M. Kühne , M. Orlita , A. Mahmood , E. Dujardin , R. R. Nair , A. K. Geim , M. Potemski

Density functional perturbation theory is used to analyze electron-phonon interaction in bilayer graphene. The results show that phonon scattering in bilayer graphene bears more resemblance with bulk graphite than monolayer graphene. In…

Mesoscale and Nanoscale Physics · Physics 2010-11-29 K. M. Borysenko , J. T. Mullen , X. Li , Y. G. Semenov , J. M. Zavada , M. Buongiorno Nardelli , K. W. Kim

We compute, from first-principles, the frequency of the E2g, Gamma phonon (Raman G-band) of graphene, as a function of the charge doping. Calculations are done using i) the adiabatic Born-Oppenheimer approximation and ii) time-dependent…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michele Lazzeri , Francesco Mauri

We report the ultrafast dynamics of the 47.4 THz coherent phonons of graphite interacting with a photoinduced non-equilibrium electron-hole plasma. Unlike conventional materials, upon photoexcitation the phonon frequency of graphite…

Other Condensed Matter · Physics 2008-03-13 Kunie Ishioka , Muneaki Hase , Masahiro Kitajima , Ludger Wirtz , Angel Rubio , Hrvoje Petek

Room temperature Raman scattering measurements have been carried out on well characterized samples of MgB2-xCx. The Raman line corresponding to the E2g phonon mode shows progressive hardening from 620 cm-1 in pristine MgB2 to 775 cm-1 in…

Superconductivity · Physics 2009-11-11 T. Sakuntala , A. Bharathi , S. K. Deb , N. Gayathri , C. S. Sundar , Y. Hariharan

Recent theory has demonstrated that the value of the electron-phonon coupling strength $\lambda$ can be extracted directly from the thermal attenuation (Debye-Waller factor) of Helium atom scattering reflectivity. This theory is here…

Materials Science · Physics 2021-04-21 G. Benedek , J. R. Manson , S. Miret-Artés

Under homogeneous uniaxial strains, the Raman 2D band of graphene involving two-phonon double-resonance scattering processes splits into two peaks and they altogether redshift strongly depending on the direction and magnitude of the strain.…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Duhee Yoon , Young-Woo Son , Hyeonsik Cheong

We present a systematic study of the Raman spectra of optical phonons in graphene monolayers under tunable uniaxial tensile stress. Both the G and 2D bands exhibit significant red shifts. The G band splits into two distinct sub-bands (G+,…

Materials Science · Physics 2008-12-15 Mingyuan Huang , Hugen Yan , Changyao Chen , Daohua Song , Tony F. Heinz , James Hone

We show the evolution of Raman spectra with number of graphene layers on different substrates, SiO$_{2}$/Si and conducting indium tin oxide (ITO) plate. The G mode peak position and the intensity ratio of G and 2D bands depend on the…

Materials Science · Physics 2007-10-24 Anindya Das , Biswanath Chakraborty , A. K. Sood

In the bilayer ReS$ _{2} $ channel of a field-effect transistor (FET), we demonstrate using Raman spectroscopy that electron doping (n) results in softening of frequency and broadening of linewidth of the in-plane vibrational modes, leaving…

We analyze the effect of electron-phonon coupling on photoemission properties and ultrafast response of doped monolayer MoS2. The analysis is based on combined DFT and many-body (Eliashberg theory) approaches. In particular, we have…

Materials Science · Physics 2015-02-02 Neha Nayyar , Duy Le , Volodymyr Turkowski , Talat S. Rahman

Raman spectroscopy of graphene is reviewed from a theoretical perspective. After an introduction of the building blocks (electronic band structure, phonon dispersion, electron-phonon interaction, electron-light coupling), Raman intensities…

Mesoscale and Nanoscale Physics · Physics 2017-03-23 Sven Reichardt , Ludger Wirtz