Related papers: H2 reformation in post-shock regions
Many theoretical and laboratory studies predict H2 to be formed in highly excited ro-vibrational states. The consequent relaxation of excited levels via a cascade of infrared transitions might be observable in emission from suitable…
The recombination of hydrogen in the interstellar medium, taking place on surfaces of microscopic dust grains, is an essential process in the evolution of chemical complexity in interstellar clouds. The H_2 formation process has been…
(Abridged) H2 is the most abundant molecule in the Universe. Thanks to its widely spaced energy levels, it predominantly lights up in warm gas, T > 100 K, such as shocked regions, and it is one of the key targets of JWST observations. These…
We have obtained K-band spectra at R~5,000 and angular resolution 0.3" of a section of the Herbig-Haro 7 (HH7) bow shock, using the Near-Infrared Integral Field Spectrograph at Gemini North. Present in the portion of the data cube…
The study of the chemical evolution of glycine in the interstellar medium is one of challenging topics in astrochemistry. Here, we present the chemical modeling of glycine in hot cores using the state-of-the-art three-phase chemical model…
Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes.…
The modelling of emission spectra of molecules seen in interstellar clouds requires the knowledge of collisional rate coefficients. Among the commonly observed species, N$_2$H$^+$ is of particular interest since it was shown to be a good…
Context. Water together with O2 are important gas phase ingredients to cool dense gas in order to form stars. On dust grains, H2 O is an important constituent of the icy mantle in which a complex chemistry is taking place, as revealed by…
We have mapped the warm molecular gas traced by the H_2 S(0) - H_2 S(5) pure rotational mid-infrared emission lines over a radial strip across the nucleus and disk of M51 (NGC 5194) using the Infrared Spectrograph (IRS) on the Spitzer Space…
We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…
The interpretation of water line emission from existing observations and future HIFI/Herschel data requires a detailed knowledge of collisional rate coefficients. Among all relevant collisional mechanisms, the rotational (de)excitation of…
The energy transfer among the components in a gas determines its fate. Especially at low temperatures, inelastic collisions drive the cooling and the heating mechanisms. In the early Universe as well as in zero- or low- metallicity…
H2 formation remains a major issue for the understanding of interstellar physics. We investigate H2 formation in the interstellar medium at the light of the most recent experimental and theoretical data. We implemented detailed H2 formation…
Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…
Continuous-time, random-walk Monte Carlo simulations of H2 formation on grains have been performed for surfaces that are stochastically heated by photons. We have assumed diffuse cloud conditions and used a variety of grains of varying…
It is commonly believed that it is unfavourable for adsorbed H atoms on carbonaceous surfaces to form H$_2$ without the help of incident H atoms. Using ring-polymer instanton theory to describe multidimensional tunnelling effects, combined…
We map for the first time the two-dimensional H_2 excitation of warm intergalactic gas in Stephan's Quintet on group-wide (50 x 35 kpc^2) scales to quantify the temperature, mass and warm-H_2 mass fraction as a function of position using…
At low temperatures, the main coolant in primordial gas is molecular hydrogen, H2. Recent work has shown that primordial gas that is not collapsing gravitationally but is cooling from an initially ionized state forms hydrogen deuteride, HD,…
The ability of primordial gas to cool in proto-galactic haloes exposed to Lyman-Werner (LW) radiation is critically dependent on the self-shielding of H_2. We perform radiative transfer calculations of LW line photons, post-processing…
The radiative cooling of shocked gas with primordial chemical composition is an important process relevant to the formation of the first stars and structures, as well as taking place also in high velocity cloud collisions and supernovae…