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The classical ground state magnetic response of fullerene molecules that resemble capped carbon nanotubes is calculated within the framework of the antiferromagnetic Heisenberg model. It is found that the magnetic response depends subtly on…

Strongly Correlated Electrons · Physics 2017-04-28 N. P. Konstantinidis

Using a tight binding model, we theoretically study the electronic properties of zigzag boron-carbon-nitride (BCN) nanoribbons where the outermost C atoms of zigzag graphene nanoribbons are replaced with B and N atoms. We show that the flat…

Materials Science · Physics 2013-05-23 Tomoaki Kaneko , Kikuo Harigaya

Configuration Interaction (CI) calculations on the ground state of the C atom are carried out using a small basis set of Slater orbitals [7s6p5d4f3g]. The configurations are selected according to their contribution to the total energy. One…

Atomic Physics · Physics 2017-08-01 María Belén Ruiz , Robert Tröger

Atomic models of zigzag (n, 0)- and armchair (n,n)-like NiCl2 nanotubes (n = 4 - 29) formed by rolling (100) single layers of the bulk NiCl2 which crystallizes in the CdCl2-type structure, are constructed and their electronic properties and…

Materials Science · Physics 2007-05-23 V. V. Ivanovskaya , A. N. Enyashin , N. I. Medvedeva , A. L. Ivanovskii

We investigate the electronic and magnetic properties of hydrogenated carbon nanotubes using ab initio spin-polarized calculations within both the local density approximation (LDA) and the generalized gradient approximation (GGA). We find…

Materials Science · Physics 2010-02-05 Xiaoping Yang , Gang Wu

Gold clusters Aun of size n = 2 to 12 atoms were studied by the density-functional theory with an ab-initio pseudopotential and a generalized gradient approximation. Geometry optimizations starting from a number of initial candidate…

Other Condensed Matter · Physics 2007-05-23 Prashant K. Jain

We use first principles simulations to investigate the electronic properties of a set of carbon nanocages with a bipartite structure. These nanocages are exclusively formed by hexagonal and tetragonal rings and we show they feature frontier…

The binding of clusters of metal nanoparticles is partly electrostatic. We address difficulties in calculating the electrostatic energy when high charging energies limit the total charge to a single quantum, entailing unequal potentials on…

Soft Condensed Matter · Physics 2016-03-23 Jian Qin , Nathan W. Krapf , Thomas A. Witten

A comprehensive first-principles theoretical study of the electronic properties and half-metallic nature of finite zigzag carbon nanotubes is presented. Unlike previous reports, we find that all nanotubes studied present a spin-polarized…

Materials Science · Physics 2008-11-29 Oded Hod , Gustavo E. Scuseria

The nucleation of carbon caps on small nickel clusters is studied using a tight binding model coupled to grand canonical Monte Carlo simulations. It takes place in a well defined carbon chemical potential range, when a critical…

Materials Science · Physics 2009-11-13 Hakim Amara , Christophe Bichara , François Ducastelle

Possible crystalline modifications of chemical compounds at low temperatures correspond to local minima of the energy landscape. Determining these minima via simulated annealing is one method for the prediction of crystal structures, where…

Materials Science · Physics 2008-10-31 K. Doll , J. C. Schoen , M. Jansen

The Korringa-Kohn-Rostoker Green (KKR) function method for non-collinear magnetic structures was applied on Mn and Cr ad-clusters deposited on the Ni(111) surface. By considering various dimers, trimers and tetramers, a large amount of…

Materials Science · Physics 2015-06-25 Samir Lounis , Phivos Mavropoulos , Rudolf Zeller , Peter H. Dederichs , Stefan Blügel

We investigate the spectrum of finite-length carbon nanotubes in the presence of onsite and nearest-neighbor superconducting pairing terms. A one-dimensional ladder-type lattice model is developed to explore the low-energy spectrum and the…

Mesoscale and Nanoscale Physics · Physics 2017-09-20 W. Izumida , L. Milz , M. Marganska , M. Grifoni

The formation and evolution mechanism of fullerenes in the planetary nebula or in the interstellar medium are still not understood. Here we present the study on the cluster formation and the relative reactivity of fullerene cations (from…

Atomic and Molecular Clusters · Physics 2021-01-13 Deping Zhang , Yuanyuan Yang , Xiaoyi Hu , Junfeng Zhen

By means of quantum Monte Carlo (QMC) calculations from first principles, we study the ground-state properties of the narrowest zigzag graphene nanoribbon, with an infinite linear acene structure. We show that this quasi-one-dimensional…

Strongly Correlated Electrons · Physics 2022-03-14 Raghavendra Meena , Guanna Li , Michele Casula

Several experiments have recently found room-temperature ferromagnetism in graphite-like carbon based materials. This paper offers a model explaining such ferromagnetism by using an asymmetric nano-graphene. Our first typical model is…

Mesoscale and Nanoscale Physics · Physics 2011-01-28 Norio Ota , Narjes Gorjizadeh , Yoshiyuki Kawazoe

We show that carbon-doped hexagonal boron nitride (h-BN) has extraordinary properties with many possible applications. We demonstrate that the substitution-induced impurity states, associated with carbon atoms, and their interactions…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Hyoungki Park , Amita Wadehra , John W. Wilkins , Antonio H. Castro Neto

Composition, atomic structure, and electronic properties of TM$_x$Mg$_y$O$_z$ clusters (TM = Cr, Ni, Fe, Co, $x+y \leq 3$) at realistic temperature $T$ and partial oxygen pressure $p_{\textrm{O}_2}$ conditions are explored using the {\em ab…

Allotropes of carbon, including one-dimensional carbon nanotubes and two-dimensional graphene sheets, continue to draw attention as promising platforms for probing the physics of electrons in lower dimensions. Recent research has shown that…

Mesoscale and Nanoscale Physics · Physics 2020-05-20 Benedetta Flebus , Allan H. MacDonald

We present a novel comprehensive first-principles theoretical study of the electronic properties and relative stabilities of edge-oxidized zigzag graphene nanoribbons. The oxidation schemes considered include hydroxyl, carboxyl, ether, and…

Materials Science · Physics 2015-05-13 Oded Hod , Veronica Barone , Juan E. Peralta , Gustavo E. Scuseria