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The electron-phonon matrix elements relevant to the Raman intensity and Kohn anomaly of the G band are calculated by taking into account the effect of the edge of graphene. The analysis of the pseudospin reveals that the longitudinal…

Mesoscale and Nanoscale Physics · Physics 2010-04-13 K. Sasaki , R. Saito , K. Wakabayashi , T. Enoki

Graphene edges are of particular interest, since their chirality determines the electronic properties. Here we present a detailed Raman investigation of graphene flakes with well defined edges oriented at different crystallographic…

Materials Science · Physics 2009-04-10 C. Casiraghi , A. Hartschuh , H. Qian , S. Piscanec , C. Georgi , K. S. Novoselov , D. M. Basko , A. C. Ferrari

In this report, we present Raman spectroscopy investigation of the thermal stability and dynamics of graphene edges. It was found that graphene edges (both armchair and zigzag) are not stable and undergo modifications even at temperature as…

Materials Science · Physics 2010-12-15 Ya Nan Xu , Da Zhan , Lei Liu , Hui Suo , Zhen Hua Ni , Thuong Thuong Nguyen , Chun Zhao , Ze Xiang Shen

Edges naturally exist in a single-layer graphene sample. Similarly, individual graphene layers in a multilayer graphene sample contribute their own edges. We study the Raman spectrum at the edge of a graphene layer laid on n layer graphene…

Materials Science · Physics 2015-01-15 Q. -Q. Li , X. Zhang , W. -P. Han , Y. Lu , W. Shi , J. -B. Wu , P. -H. Tan

Polarization resolved micro-Raman spectroscopy was carried out at the edges of bilayer graphene. We find strong dependence of the intensity of the G band on the incident laser polarization, with its intensity dependence being 90 degrees out…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Milan Begliarbekov , Onejae Sul , Sokratis Kalliakos , Eui-Hyeok Yang , Stefan Strauf

Theory has predicted rich and very distinct physics for graphene devices with boundaries that follow either the armchair or zigzag crystallographic directions. A prerequisite to disclose this physics in experiment is to be able to produce…

Raman imaging on the edges of single layer micromechanical cleavage graphene (MCG) was carried out. The intensity of disorder-induced Raman feature (D band at ~1350 cm-1) was found to be correlated to the edge chirality: it is stronger at…

Materials Science · Physics 2009-11-13 YuMeng You , ZhenHua Ni , Ting Yu , ZeXiang Shen

We present a systematic study of the Raman spectra of optical phonons in graphene monolayers under tunable uniaxial tensile stress. Both the G and 2D bands exhibit significant red shifts. The G band splits into two distinct sub-bands (G+,…

Materials Science · Physics 2008-12-15 Mingyuan Huang , Hugen Yan , Changyao Chen , Daohua Song , Tony F. Heinz , James Hone

The polarization dependences of the G, D, and 2D (G$'$) bands in Raman spectra at graphene bulk and edge are examined theoretically. The 2D and D bands have different selection rules at bulk and edge. At bulk, the 2D band intensity is…

Mesoscale and Nanoscale Physics · Physics 2010-11-15 K. Sasaki , K. Wakabayashi , T. Enoki

The quantum corrections to the energies of the $\Gamma$ point optical phonon modes (Kohn anomalies) in graphene nanoribbons are investigated. We show theoretically that the longitudinal optical modes undergo a Kohn anomaly effect, while the…

Accurate and simple local strain assessment in graphene is one of the crucial tasks in device characterization. Raman spectroscopy is often used for that purpose through monitoring of the G and 2D modes. However, the shifts of those two…

Materials Science · Physics 2018-04-27 Elena del Corro , Ladislav Kavan , Martin Kalbac , Otakar Frank

The paper reports a theoretical study of scattering of electrons by edges in graphene and its effect on Raman scattering. First, effective models are discussed for translationally invariant and rough edges. Second, they are used in a…

Materials Science · Physics 2009-05-28 D. M. Basko

Spatially inhomogeneous strains in graphene can simulate the effects of valley-dependent magnetic fields. As demonstrated in recent experiments, the realizable magnetic fields are large enough to give rise to well-defined flat pseudo-Landau…

Mesoscale and Nanoscale Physics · Physics 2013-04-25 Pouyan Ghaemi , Sarang Gopalakrishnan , Shinsei Ryu

We investigate the quality of hydrogen plasma defined graphene edges by Raman spectroscopy, atomic resolution AFM and low temperature electronic transport measurements. The exposure of graphite samples to a remote hydrogen plasma leads to…

We have investigated antidot lattices, which were prepared on exfoliated graphene single layers via electron-beam lithography and ion etching, by means of scanning Raman spectroscopy. The peak positions, peak widths and intensities of the…

Mesoscale and Nanoscale Physics · Physics 2011-07-01 S. Heydrich , M. Hirmer , C. Preis , T. Korn , J. Eroms , D. Weiss , C. Schüller

Bernal- and non-Bernal-stacked graphene layers have been systematically studied by Raman imaging and spectroscopy. Two dominant Raman modes, G and G' (or 2D) of folded graphene layers exhibit three types of spectral features when interlayer…

Optics · Physics 2014-07-02 Chunxiao Cong , Ting Yu

It is known that zigzag graphene edge is able to support edge states: there is a non-dispersive single-electron band localized near the zigzag edge. However, it is generally believed that no edge states exist near the armchair edge. In this…

Mesoscale and Nanoscale Physics · Physics 2014-01-14 P. A. Maksimov , A. V. Rozhkov , A. O. Sboychakov

Vibrational properties of graphene nanoribbons are examined with density functional based tight-binding method and non-resonant bond polarization theory. We show that the recently discovered reconstructed zigzag edge can be identified from…

Materials Science · Physics 2009-11-13 S. Malola , H. Häkkinen , P. Koskinen

We investigate the topological phase transitions in graphene under the modulation of circularly polarized light, by analyzing the changes of edge states and its topological structures. A full phase diagram, with up to ten different…

Mesoscale and Nanoscale Physics · Physics 2016-04-20 Yi-Xiang Wang , Fuxiang Li

We investigate etched single-layer graphene nanoribbons with different widths ranging from 30 to 130 nm by confocal Raman spectroscopy. We show that the D-line intensity only depends on the edge-region of the nanoribbon and that…

Mesoscale and Nanoscale Physics · Physics 2011-05-06 Dominik Bischoff , Johannes Güttinger , Susanne Dröscher , Thomas Ihn , Klaus Ensslin , Christoph Stampfer
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