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Related papers: Projector self-consistent DFT+U using non-orthogon…

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Machine-learning models can be trained to predict the converged electron charge density of a density functional theory (DFT) calculation. In general, the value of the density at a given point in space is invariant under global translations…

Materials Science · Physics 2024-10-03 Bruno Focassio , Michelangelo Domina , Urvesh Patil , Adalberto Fazzio , Stefano Sanvito

A systematic comparative study has been performed to better understand DFT$+U$ (density functional theory + $U$) method. We examine the effect of choosing different double counting and exchange-correlation functionals. The calculated energy…

Strongly Correlated Electrons · Physics 2018-06-26 Siheon Ryee , Myung Joon Han

The Discrete Fourier Transform (DFT) is central to the analysis of uniformly sampled signals, yet many practical applications involve non-uniform sampling, requiring the Non-Uniform Discrete Fourier Transform (NUDFT). While quantum…

Quantum Physics · Physics 2026-03-18 Junaid Aftab , Yuehaw Khoo , Haizhao Yang

We present a derivation of the exact expression for Pulay forces in density-functional theory calculations augmented with extended Hubbard functionals, and arising from the use of orthogonalized atomic orbitals as projectors for the Hubbard…

Materials Science · Physics 2022-05-13 Iurii Timrov , Francesco Aquilante , Luca Binci , Matteo Cococcioni , Nicola Marzari

The Hubbard model is implemented in real-space Green's function calculations of x-ray spectra using an effective self-energy adapted from the LSDA+U method of Anisimov et al. This self-energy consists of an energy-dependent many-pole…

Strongly Correlated Electrons · Physics 2011-07-12 Towfiq Ahmed , J. J. Kas , J. J. Rehr

Double-hybrid density functional theory (DHDFT) offers a pathway to accuracies approaching composite wavefunction approaches like G4 theory. However, the GLPT2 (G{\"o}rling 2nd order perturbation theory) term causes them to partially…

Chemical Physics · Physics 2022-10-13 Nisha Mehta , Jan M. L. Martin

Numerical inspection of wide-angle (WA) or ultra-wide-angle (UWA) computer-generated holograms (CGH) is a computationally demanding task. To surpass this limitation, we propose a novel computational approach for fast and accurate WA-CGH…

We extend to strongly correlated molecular systems the recently introduced basis-set incompleteness correction based on density-functional theory (DFT) [E. Giner et al., J. Chem. Phys. 149, 194301 (2018)]. This basis-set correction relies…

Chemical Physics · Physics 2020-05-20 Emmanuel Giner , Anthony Scemama , Pierre-François Loos , Julien Toulouse

Imaginary-time time-dependent Density functional theory (it-TDDFT) has been proposed as an alternative method for obtaining the ground state within density functional theory (DFT) which avoids some of the difficulties with convergence…

Computational Physics · Physics 2021-11-09 John McFarland , Efstratios Manousakis

A solid-state quantum emitter is one of the indispensable components for optical quantum technologies. Ideally, an emitter should have a compatible wavelength for efficient coupling to other components in a quantum network. It is therefore…

Quantum Physics · Physics 2024-05-08 Chanaprom Cholsuk , Sujin Suwanna , Tobias Vogl

In effective single-electron theories, self-interaction manifests itself through the unphysical dependence of the energy of an electronic state as a function of its occupation, which results in important deviations from the ideal Koopmans…

Materials Science · Physics 2009-01-20 I. Dabo , M. Cococcioni , N. Marzari

We reexamine results obtained with the recently proposed density functional theory framework based on forces (force-DFT) [Tschopp et al., Phys. Rev. E 106, 014115 (2022)]. We compare inhomogeneous density profiles for hard sphere fluids to…

Soft Condensed Matter · Physics 2024-02-28 Florian Sammüller , Sophie Hermann , Matthias Schmidt

Empirical fitting of parameters in approximate density functionals is common. Such fits conflate errors in the self-consistent density with errors in the energy functional, but density-corrected DFT (DC-DFT) separates these two. We…

Chemical Physics · Physics 2020-12-02 Suhwan Song , Stefan Vuckovic , Eunji Sim , Kieron Burke

Dynamical correlations and non-local contributions beyond static mean-field theories are of fundamental importance for describing the electronic structure of correlated metals. Their effects are usually described with many-body approaches…

Strongly Correlated Electrons · Physics 2023-09-22 Marco Vanzini , Nicola Marzari

Semi-local DFT methods exhibit significant errors for the phase diagrams of transition-metal oxides that are caused by an incorrect description of molecular oxygen and the large self-interaction error in materials with strongly localized…

Materials Science · Physics 2022-03-29 Nongnuch Artrith , José Antonio Garrido Torres , Alexander Urban , Mark S. Hybertsen

The combination of density functional theory with dynamical mean-field theory (DFT+DMFT) has become a powerful first-principles approach to tackle strongly correlated materials in condensed matter physics. The wide use of this approach…

Strongly Correlated Electrons · Physics 2022-05-10 Xin Qu , Peng Xu , Rusong Li , Gang Li , Lixin He , Xinguo Ren

A non-iterative method is presented to calculate the closest Wannier functions (CWFs) to a given set of localized guiding functions, such as atomic orbitals, hybrid atomic orbitals, and molecular orbitals, based on minimization of a…

Materials Science · Physics 2023-07-03 Taisuke Ozaki

The 2D half-filled Hubbard model is studied by a nonperturbative analytic theory of correlator projection. The original dynamical mean-field approximation (DMFA) is reproduced at the first-order projection and then improved by systematic…

Strongly Correlated Electrons · Physics 2009-11-07 Shigeki Onoda , Masatoshi Imada

The Discrete Fourier Transform (DFT) is widely utilized for signal analysis but is plagued by spectral leakage, leading to inaccuracies in signal approximation. Window functions play a crucial role in mitigating spectral leakage by…

Signal Processing · Electrical Eng. & Systems 2023-12-27 Haichao Xu , Xingpao Suo

Density functional theory (DFT), one of the most widely utilized methods available to computational chemistry, fails to describe systems with statically correlated electrons. To address this shortcoming, in previous work we transformed DFT…

Chemical Physics · Physics 2023-01-02 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti