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The concept of entropy in nonequilibrium macroscopic systems is investigated in the light of an extended equation of motion for the density matrix obtained in a previous study. It is found that a time-dependent information entropy can be…

Statistical Mechanics · Physics 2009-11-10 W. T. Grandy

We consider a finite chain of non-linear oscillators coupled at its ends to two infinite heat baths which are at different temperatures. Using our earlier results about the existence of a stationary state, we show rigorously that for…

chao-dyn · Physics 2015-06-24 Jean-Pierre Eckmann , Claude-Alain Pillet , Luc Rey-Bellet

In this work we introduce a method for estimating entropy rate and entropy production rate from finite symbolic time series. From the point of view of statistics, estimating entropy from a finite series can be interpreted as a problem of…

Statistical Mechanics · Physics 2021-02-24 Raul Salgado-Garcia , Cesar Maldonado

Entropy production (EP) is a central measure in nonequilibrium thermodynamics, as it can quantify the irreversibility of a process as well as its energy dissipation in special cases. Using the time-reversal asymmetry in a system's path…

Statistical Mechanics · Physics 2022-04-26 Dong-Kyum Kim , Sangyun Lee , Hawoong Jeong

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

The entropy production is commonly interpreted as measuring the distance from equilibrium. However, this explanation lacks a rigorous description due to the absence of a natural equilibrium measure. The present analysis formalizes this…

Statistical Mechanics · Physics 2025-10-23 David Andrieux

We present an exact relationship between the entropy production and the distinguishability of a process from its time-reverse, quantified by the relative entropy between forward and backward states. The relationship is shown to remain valid…

Statistical Mechanics · Physics 2017-05-15 Juan M. R. Parrondo , Christian van den Broeck , Ryoichi Kawai

The thermodynamic uncertainty relation gives a lower bound on the amount of dissipation in a mesoscopic system. By considering the fluctuations in the hysteresis of the current -- the sum of the currents in the time-forward and…

Statistical Mechanics · Physics 2019-09-04 Karel Proesmans , Jordan M. Horowitz

We show that the scale dependence of the fluctuations of the natural time itself under time reversal provides a useful tool for the discrimination of seismic electric signals (critical dynamics) from noises emitted from man made sources as…

Statistical Mechanics · Physics 2009-11-13 P. A. Varotsos , N. V. Sarlis , E. S. Skordas , M. S. Lazaridou

Fluctuations of observables as functions of time, or "fluctuation patterns", are studied in a chaotic microscopically reversible system that has irreversibly reached a nonequilibrium stationary state. Supposing that during a certain, long…

chao-dyn · Physics 2008-10-08 G. Gallavotti

We consider conservative quantum evolutions possibly interrupted by macroscopic measurements. When started in a nonequilibrium state, the resulting path-space measure is not time-reversal invariant and the weight of time-reversal breaking…

Statistical Mechanics · Physics 2007-05-23 I. Callens , W. De Roeck , T. Jacobs , C. Maes , K. Netocny

We present a method of estimating the rate of entropy production in underdamped dynamics by decomposing it into contributions originating in different non-equilibrium effects. Specifically, a non-zero average velocity, a non-thermal width…

Statistical Mechanics · Physics 2025-12-01 Mario A. Ciampini , Jakob Rieser , Nikolai Kiesel , Andreas Dechant

Entropy serves as a central observable in equilibrium thermodynamics. However, many biological and ecological systems operate far from thermal equilibrium. Here we show that entropy production can characterize the behavior of such…

Statistical Mechanics · Physics 2015-03-17 Benjamin Andrae , Jonas Cremer , Tobias Reichenbach , Erwin Frey

If a system is at thermodynamic equilibrium, an observer cannot tell whether a film of it is being played forward or in reverse: any transition will occur with the same frequency in the forward as in the reverse direction. However, if…

Statistical Mechanics · Physics 2020-07-01 John W. Biddle , Jeremy Gunawardena

For a Markovian dynamics on discrete states, the logarithmic ratio of waiting-time distributions between two successive, instantaneous transitions in forward and backward direction is a measure of time-irreversibility. It thus serves as an…

Statistical Mechanics · Physics 2024-06-13 Ellen Meyberg , Julius Degünther , Udo Seifert

We show how to extract from a sufficiently long time series of stationary fluctuations of chemical reactions an estimate of the entropy production. This method, which is based on recent work on fluctuation theorems, is direct, non-invasive,…

Statistical Mechanics · Physics 2014-12-09 S. Muy , A. Kundu , D. Lacoste

The linear response to temperature changes is derived for systems with overdamped stochastic dynamics. Holding both in transient and steady state conditions, the results allow to compute nonequilibrium thermal susceptibilities from…

Statistical Mechanics · Physics 2016-04-11 Gianmaria Falasco , Marco Baiesi

The entropy production is one of the most essential features for systems operating out of equilibrium. The formulation for discrete-state systems goes back to the celebrated Schnakenberg's work and hitherto can be carried out when for each…

Statistical Mechanics · Physics 2020-04-15 D. M. Busiello , D. Gupta , A. Maritan

Thermodynamic inference from coarse observations remains a key challenge. Memory, in particular correlations between consecutively observed mesostates, blur signatures of irreversibility and must be accounted for in defining physical…

Statistical Mechanics · Physics 2025-12-24 Tassilo Schwarz , Anatoly B. Kolomeisky , Aljaž Godec

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

Statistical Mechanics · Physics 2007-05-23 Giovanni Gallavotti