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A ferroelectric is a material with a polar structure whose polarity can be reversed by applying an electric field. In metals, the itinerant electrons tend to screen electrostatic forces between ions, helping to explain why polar metals are…

The effective barrier height between an electrode and a ferroelectric (FE) depends on both macroscopic electrical properties and microscopic chemical and electronic structure. The behavior of a prototypical electrode/FE/electrode structure,…

When insulator LaAlO3 is grown by epitaxy onto a TiO2-terminated {100} surface of insulator SrTiO3, the resulting system has a metallic character. This phenomenon has been associated with an electrostatic frustration at the interface, as…

Materials Science · Physics 2016-08-16 J. -L. Maurice , C. Carretero , M. -J. Casanove , K. Bouzehouane , S. Guyard , É. Larquet , J. -P. Contour

We consider theoretically the influence of the flexoelectric coupling on the spatial distribution and temperature behavior of spontaneous polarization for several types of stable domain structure in thin ferroelectric films, such as stripe…

Materials Science · Physics 2021-08-25 Anna N. Morozovska , Eugene A. Eliseev , Sergei V. Kalinin , Riccardo Hertel

Artificial tuning of dielectric parameters can result from interface conductivity in polycrystalline materials. In ferroelectric single crystals, it was already shown that ferroelectric domain walls can be the source of such artificial…

Materials Science · Physics 2015-06-05 R. Anand Theerthan , Alla Artemenko , Mario Maglione

Complex oxide heterointerfaces and van der Waals heterostructures present two versatile but intrinsically different platforms for exploring emergent quantum phenomena and designing new functionalities. The rich opportunity offered by the…

Mesoscale and Nanoscale Physics · Physics 2020-03-19 Dawei Li , Xi Huang , Zhiyong Xiao , Hanying Chen , Le Zhang , Yifei Hao , Jingfeng Song , Ding-Fu Shao , Evgeny Y. Tsymbal , Yongfeng Lu , Xia Hong

Charged polar interfaces such as charged ferroelectric domain walls or heterostructured interfaces of ZnO/(Zn,Mg)O and LaAlO3/SrTiO3, across which the normal component of electric polarization changes suddenly, can host large…

Materials Science · Physics 2016-06-06 F. -T. Huang , F. Xue , B. Gao , L. H. Wang , X. Luo , W. Cai , X. Lu , J. M. Rondinelli , L. Q. Chen , S. -W. Cheong

First-principles calculations were performed to investigate the ferroelectric properties of barium titanate and bismuth ferrite, as well as phonon dispersion of BaTiO3, using density functional theory and density functional perturbation…

Materials Science · Physics 2014-12-08 Hong-Jian Feng

An emerging area in condensed matter physics is the use of multilayered heterostructures to enhance ferroelectricity in complex oxides. Here, we demonstrate that optically pumping carriers across the interface between thin films of a…

Materials Science · Physics 2013-07-12 Y. M. Sheu , S. A. Trugman , L. Yan , C. -P. Chuu , Z. Bi , Q. X. Jia , A. J. Taylor , R. P. Prasankumar

Physical effects caused by the presence of interfaces between the domains of coexisting ferroelectric and antiferroelectric phases in solid solutions with small difference in free energies of the ferroelectric and antiferroelectric states…

Materials Science · Physics 2015-06-08 V. M. Ishchuk , V. L. Sobolev

Interface physics in oxide heterostructures is pivotal in material's science. Domain walls (DWs) in ferroic systems are examples of naturally occurring interfaces, where order parameter of neighboring domains is modified and emerging…

Materials Science · Physics 2015-10-08 Josep Fontcuberta , Vassil Skumryev , Vladimir Laukhin , Xavier Granados , Ekhard K. H. Salje

We use density functional theory plus dynamical mean-field theory to demonstrate the emergence of a metallic layer at the interface between the two Mott insulators LaTiO$_3$ and LaVO$_3$. The metallic layer is due to charge transfer across…

Strongly Correlated Electrons · Physics 2019-09-11 Sophie Beck , Claude Ederer

Composite materials comprised of ferroelectric nanoparticles in a dielectric matrix are being actively investigated for a variety of functional properties attractive for a wide range of novel electronic and energy harvesting devices.…

Mesoscale and Nanoscale Physics · Physics 2017-01-11 John Mangeri , Yomery Espinal , Andrea Jokisaari , S. Pamir Alpay , Serge Nakhmanson , Olle Heinonen

First-principles modeling of ferroelectric capacitors presents several technical challenges, due to the coexistence of metallic electrodes, long-range electrostatic forces and short-range interface chemistry. Here we show how these aspects…

Materials Science · Physics 2011-03-03 Massimiliano Stengel , David Vanderbilt , Nicola A. Spaldin

We investigate the structural, electronic, transport, and thermoelectric properties of LaNiO$_3$/SrTiO$_3(001)$ superlattices containing either exclusively $n$- or $p$-type interfaces or coupled interfaces of opposite polarity by using…

Materials Science · Physics 2017-03-03 Benjamin Geisler , Ariadna Blanca-Romero , Rossitza Pentcheva

As a room-temperature multiferroic, BiFeO3 has been intensively investigated for both magnetoelectric devices and non-volatile ferroelectric memory applications. Both magnetoelectric and ferroelectric memory devices have the same control…

Ferroelectric switching governs the functional properties of ferroelectric perovskites. It is widely accepted that this switching depends on domain nucleation and pinning and that these processes can be controlled by the defect structure.…

Materials Science · Physics 2026-04-16 Himal Wijekoon , Pierre Hirel , Anna Grünebohm

We review the concept of surface charge, first in the context of the polarization in ferroelectric materials, and second in the context of layers of charged ions in ionic insulators. While the former is traditionally discussed in the…

Materials Science · Physics 2025-07-22 Nicola A Spaldin , Ipek Efe , Marta D Rossell , Chiara Gattinoni

Pressure-induced polarization switching in ferroelectric thin films has emerged as a powerful method for domain patterning, allowing to create predefined domain patterns on free surfaces and under thin conductive top electrodes. However,…

Materials Science · Physics 2017-12-06 Ye Cao , Anna Morozovska , Sergei V. Kalinin

We use density functional theory calculations to show that the LaAlO3|SrTiO3 interface between insulating perovskite oxides is borderline in satisfying the Stoner criterion for itinerant ferromagnetism and explore other oxide combinations…

Materials Science · Physics 2014-09-17 Nirmal Ganguli , Paul J. Kelly