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By performing first-principles calculations on four capacitor structures based on BaTiO3 and PbTiO3, we determine the intrinsic interfacial effects that are responsible for the destabilization of the polar state in thin-film ferroelectric…

Materials Science · Physics 2011-03-03 Massimiliano Stengel , David Vanderbilt , Nicola A. Spaldin

In polar oxide interfaces phenomena such as conductivity, superconductivity, magnetism, one-dimensional conductivity and Quantum Hall states can emerge at the polar discontinuity. Combining controllable ferroelectricity at such interfaces…

Strongly Correlated Electrons · Physics 2020-07-06 Gal Tuvia , Yiftach Frenkel , Prasanna K. Rout , Itai Silber , Beena Kalisky , Yoram Dagan

LaNiO$_{3}$-BaTiO$_{3}$ superlattices with different types of interfaces are studied from first-principles density-functional theory. It is revealed that the ferroelectricity in the superlattice with (NiO$_2$)$^-$/(BaO)$^0$ interfaces is…

Materials Science · Physics 2014-09-30 Yin-Zhong Wu , Hai-Shuang Lu , Tian-Yi Cai , Sheng Ju

Integrating multiple properties in a single system is crucial for the continuous developments in electronic devices. However, some physical properties are mutually exclusive in nature. Here, we report the coexistence of two seemingly…

Interface effects on the ferroelectric behavior of PbTiO$_3$ ultrathin films deposited on SrTiO$_3$ substrate are investigated using an interatomic potential approach with parameters fitted to first-principles calculations. We find that the…

Materials Science · Physics 2009-11-11 M Sepliarsky , M. G. Stachiotti , R. L. Migoni

The emerging interest in two-dimensional electron gases (2DEGs), formed at interfaces between two insulating oxide perovskites poses crucial fundamental question in view of future electronic devices. In the framework of density-functional…

Materials Science · Physics 2022-03-09 Le Fang , Wahib Aggoune , Wei Ren , Claudia Draxl

The predictions of the polar catastrophe scenario to explain the occurrence of a metallic interface in heterostructures of the solid solution(LaAlO$_3$)$_{x}$(SrTiO$_3$)$_{1-x}$ (LASTO:x) grown on (001) SrTiO$_3$ were investigated as a…

In the framework of Landau--Ginzburg--Devonshire (LGD) phenomenological theory, the influence of misfit strains, surface energy, and finite-size effects on phase diagrams, polar properties, and hysteresis loops has been calculated for…

Materials Science · Physics 2014-07-01 E. A. Eliseev , M. D. Glinchuk , A. N. Morozovska , Ya. V. Yakovenko

Novel phenomena appear when two different oxide materials are combined together to form an interface. For example, at the interface of LaAlO3/SrTiO3, two dimensional conductive states form to avoid the polar discontinuity and magnetic…

Materials Science · Physics 2017-02-23 Fang Wang , Zhaohui Ren , He Tian , Shengyuan A. Yang , Yanwu Xie , Yunhao Lu , Jianzhong Jiang , Gaorong Han , Kesong Yang

Ferroelectric polar displacements have recently been observed in conducting electron-doped BaTiO3. The co-existence of a ferroelectric phase and conductivity opens the door to new functionalities which may provide a unique route for novel…

Materials Science · Physics 2014-06-06 Xiaohui Liu , Yong Wang , J. D. Burton , Evgeny Y. Tsymbal

An unexplored physical mechanism which produces a magnetoelectric effect in ferroelectric/ferromagnetic multilayers is studied based on first-principles calculations. Its origin is a change in bonding at the ferroelectric/ferromagnet…

Materials Science · Physics 2015-06-25 Chun-Gang Duan , Sitaram S. Jaswal , Evgeny Y. Tsymbal

Recent experimental results demonstrate that in thin films ferroelectricity persists down to film thickness of a few unit cells. This finding opens an avenue for novel electronic devices based on ultathin ferroelectrics, but also raises…

Materials Science · Physics 2015-06-25 Chun-Gang Duan , Renat F. Sabirianov , Wai-Ning Mei , Sitaram S. Jaswal , Evgeny Y. Tsymbal

With the example of LaInO$_{3}$/BaSnO$_3$, we demonstrate how both density and distribution of a two-dimensional electron gas (2DEG) formed at the interface between these perovskite oxides, can be efficiently controlled by a ferroelectric…

Materials Science · Physics 2022-01-17 Le Fang , Wahib Aggoune , Wei Ren , Claudia Draxl

Using interlayer interaction to control functional heterostructures with atomic-scale designs has become one of the most effective interface-engineering strategies nowadays. Here, we demonstrate the effect of a crystalline LaFeO3 buffer…

Ionic crystals terminated at oppositely charged polar surfaces are inherently unstable and expected to undergo surface reconstructions to maintain electrostatic stability. Essentially, an electric field that arises between oppositely…

We investigated a switchable ferroelectric diode effect and its physical mechanism in Pt/BiFeO3/SrRuO3 thin-film capacitors. Our results of electrical measurements support that, near the Pt/BiFeO3 interface of as-grown samples, a defective…

Materials Science · Physics 2011-09-12 Daesu Lee , S. H. Baek , T. H. Kim , J. -G. Yoon , C. M. Folkman , C. B. Eom , T. W. Noh

With the recent experimental verification that ferroelectric lattice distortions survive in the metallic phase of some materials, there is a desire to create devices that are both switchable and take advantage of the novel functionalities…

Mesoscale and Nanoscale Physics · Physics 2022-02-10 Kelsey S. Chapman , W. A. Atkinson

Transition metal oxide hetero-structure has great potential for multifunctional devices. However, the degraded physical properties at interface, known as dead-layer behavior, present a main obstacle for device applications. Here we present…

Materials Science · Physics 2015-06-12 R. Peng , H. C. Xu , M. Xia , J. F. Zhao , X. Xie , D. F. Xu , B. P. Xie , D. L. Feng

The formation of a two-dimensional electron gas at oxide interfaces as a consequence of polar discontinuities has generated an enormous amount of activity due to the variety of interesting effects it gives rise to. Here we study under what…

The (001) surfaces of polar perovskites BaTiO$_3$ and PbTiO$_3$ have been studied from first principles at T=0 K. For both cases of polarization, the most stable TiO-terminated interfaces show intrinsic ferroelectricity. In the topmost…

Materials Science · Physics 2008-03-12 M. Fechner , S. Ostanin , I. Mertig
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