Related papers: Modeling molecular hyperfine line emission
The redshifted spectral line radiation emitted from both atomic fine-structure and molecular rotational transitions in the interstellar medium (ISM) of high-redshift galaxies can be detected in the centimetre, millimetre and submillimetre…
We present a new code for solving the molecular and atomic excitation and radiation transfer problem in a molecular gas and predicting emergent spectra. This code works in arbitrary three dimensional geometry using unstructured Delaunay…
Accurate line lists are important for the description of the spectroscopic nature of small molecules. While a line list for CN (an important molecule for chemistry and astrophysics) exists, no underlying energy spectroscopic model has been…
Inelastic low-energy (0--1 eV) collisions of electrons with HeH$^+$ cations are treated theoretically, with a focus on the rovibrational excitation and dissociative recombination (DR) channels. In an application of {\it ab initio}…
Spectroscopy of hydrogen can be used for a search into physics beyond the Standard Model. Differences between the absorption spectra of H$_2$ as observed at high redshift and those measured in the laboratory can be interpreted in terms of…
The intensities of the three widely observed radio-wavelength hyperfine structure (HFS) lines between the {\Lambda}-doublet components of the rotational ground state of CH are inconsistent with LTE and indicate ubiquitous population…
(Abridged) Organic molecules are important constituents of protoplanetary disks. Their ro-vibrational lines observed in the near- and mid-infrared are commonly detected toward T Tauri disks. These lines are the only way to probe the…
We demonstrate coherent control of both the rotational and hyperfine state of ultracold, chemically stable $^{87}$Rb$^{133}$Cs molecules with external microwave fields. We create a sample of ~2000 molecules in the lowest hyperfine level of…
A non-LTE radiative transfer treatment of cis-methyl formate (HCOOCH3) rotational lines is presented for the first time using a set of theoretical collisional rate coefficients. These coefficients have been computed in the temperature range…
A comprehensive, hyperfine-resolved rotation-vibration line list for the ammonia molecule ($^{14}$NH$_3$) is presented. The line list, which considers hyperfine nuclear quadrupole coupling effects, has been computed using robust, first…
The OH molecule, found abundantly in the Milky Way, has four transitions at the ground state rotational level(J = 3/2) at cm wavelengths. These are E1 transitions between the F+ and F- hyperfine levels of the Lambda doublet of the J=3/2…
Calculations of transition intensities for small molecules like H$_2$O, CO, CO$_2$ based on s high-quality potential energy surface (PES) and dipole moment surface (DMS) can nowadays reach sub-percent accuracy. An extension of this…
Using cosmological simulations to make useful, scientifically relevant emission line predictions is a relatively new and rapidly evolving field. However, nebular emission lines have been particularly challenging to model because they are…
Theoretical investigations of the hyperfine structure of the hydrogen molecular ion (one electron and two protons) are discussed. The nuclear spin-rotation interaction has been found to be of the same sign as in the hydrogen molecule and…
We present a high order perturbation approach to quantitatively calculate spectral densities in three distinct steps starting from the model Hamiltonian and the observables of interest. The approach is based on the perturbative continuous…
In the first paper of this series (Rhea et al. 2020), we demonstrated that neural networks can robustly and efficiently estimate kinematic parameters for optical emission-line spectra taken by SITELLE at the Canada-France-Hawaii Telescope.…
Spectroscopy methods often require calculating the central frequency of a resonance line, that is usually implemented by finding a best fit to the spectrum by a line-shape function. Such an iterative procedure is slow and requires an…
To address the challenges of low detection accuracy and high false positive rates of transmission lines in UAV (Unmanned Aerial Vehicle) images, we explore the linear features and spatial distribution. We introduce an enhanced stochastic…
The study of multiple molecular spectral lines in gas infalling sources can provide the physical and chemical properties of these sources and help us estimate their evolutionary stages. We report line detections within the 3 mm band using…
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The…